Microwave shielding of transparent and conducting single-walled carbon nanotube films

The authors measured the transport properties of single-walled carbon nanotube (SWCNT) films in the microwave frequency range from 10 MHz to 30 GHz by using the Corbino reflection technique from temperatures of 20-400 K. Based on the real and imaginary parts of the microwave conductivity, they calculated the shielding effectiveness for various film thicknesses. Shielding effectiveness of 43 dB at 10 MHz and 28 dB at 10 GHz are found for films with 90% optical transmittance, which suggests that SWCNT films are promising as a type of transparent microwave shielding material. By combining their data with those from the literature, the conductivity of SWCNT films was established in a broad frequency range from dc to visible.Comment: 4 pages, 4 figure

Frequency- and electric-field-dependent conductivity of single-walled carbon nanotube networks of varying density

We present measurements of the frequency and electric field dependent conductivity of single walled carbon nanotube(SWCNT) networks of various densities. The ac conductivity as a function of frequency is consistent with the extended pair approximation model and increases with frequency above an onset frequency $\omega_0$ which varies over seven decades with a range of film thickness from sub-monolayer to 200 nm. The nonlinear electric field-dependent DC conductivity shows strong dependence on film thickness as well. Measurement of the electric field dependence of the resistance R(E) allows for the determination of a length scale $L_{E}$ possibly characterizing the distance between tube contacts, which is found to systematically decrease with increasing film thickness. The onset frequency $\omega_0$ of ac conductivity and the length scale $L_{E}$ of SWCNT networks are found to be correlated, and a physically reasonable empirical formula relating them has been proposed. Such studies will help the understanding of transport properties and benefit the applications of this material system.Comment: 7 pages and 6 figure

New Environmental-Thermal Barrier Coatings for Ultrahigh Temperature Alloys

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Ultrafast Microwave Nano-manufacturing of Fullerene-Like Metal Chalcogenides

Metal Chalcogenides (MCs) have emerged as an extremely important class of nanomaterials with applications ranging from lubrication to energy storage devices. Here we report our discovery of a universal, ultrafast (60 seconds), energy-efficient, and facile technique of synthesizing MC nanoparticles and nanostructures, using microwave-assisted heating. A suitable combination of chemicals was selected for reactions on Polypyrrole nanofibers (PPy-NF) in presence of microwave irradiation. The PPy-NF serves as the conducting medium to absorb microwave energy to heat the chemicals that provide the metal and the chalcogenide constituents separately. The MCs are formed as nanoparticles that eventually undergo a size-dependent, multi-stage aggregation process to yield different kinds of MC nanostructures. Most importantly, this is a single-step metal chalcogenide formation process that is much faster and much more energy-efficient than all the other existing methods and can be universally employed to produce different kinds of MCs (e.g., MoS2, and WS2).NASA LEARN II [NNX14AF49A]We gratefully acknowledge financial support from NASA LEARN II NNX14AF49A. We thank Dr. Runzhe Tao for technical assistance for this experiment

Ultra-fast self-assembly and stabilization of reactive nanoparticles in reduced graphene oxide films.

Nanoparticles hosted in conductive matrices are ubiquitous in electrochemical energy storage, catalysis and energetic devices. However, agglomeration and surface oxidation remain as two major challenges towards their ultimate utility, especially for highly reactive materials. Here we report uniformly distributed nanoparticles with diameters around 10 nm can be self-assembled within a reduced graphene oxide matrix in 10 ms. Microsized particles in reduced graphene oxide are Joule heated to high temperature (∼1,700 K) and rapidly quenched to preserve the resultant nano-architecture. A possible formation mechanism is that microsized particles melt under high temperature, are separated by defects in reduced graphene oxide and self-assemble into nanoparticles on cooling. The ultra-fast manufacturing approach can be applied to a wide range of materials, including aluminium, silicon, tin and so on. One unique application of this technique is the stabilization of aluminium nanoparticles in reduced graphene oxide film, which we demonstrate to have excellent performance as a switchable energetic material

Holey Carbon Nanotubes from Controlled Air Oxidation

Defects in various nanomaterials are often desirable to enable enhanced functional group attachments and attain properties that are not available with their intact counterparts. A new paradigm in the defective low-dimensional carbon nanomaterials is to create holes on the graphitic surfaces via partial etching. For example, holey graphene, graphene sheets with through-thickness holes, was synthesized using several different partial etching approaches and found useful for various applications such as field-effect transistors, sensors, energy storage devices, and separation membranes. In these applications, the presence of holes led to unique advantages, such as bandgap widening, chemical functionalization of hole edges, improved through-the-thickness ion transport with lowered tortuosity, and improved accessible surface area. Here, we present a facile method to prepare holey carbon nanotubes via controlled air oxidation. Although no additional catalyst was added, the residual iron nanoparticles from nanotube growth encapsulated in the nanotube cavity significantly contributed to the hole generation through the nanotube walls. The holey carbon nanotube products exhibited enhanced surface area, pore volume, and oxygen-containing functional groups, which led to their much enhanced electrochemical capacitive properties. Synthesis and characterization details of this novel class of holey carbon nanomaterials are presented, and their potential applications are discussed

A radiative cooling structural material.

Reducing human reliance on energy-inefficient cooling methods such as air conditioning would have a large impact on the global energy landscape. By a process of complete delignification and densification of wood, we developed a structural material with a mechanical strength of 404.3 megapascals, more than eight times that of natural wood. The cellulose nanofibers in our engineered material backscatter solar radiation and emit strongly in mid-infrared wavelengths, resulting in continuous subambient cooling during both day and night. We model the potential impact of our cooling wood and find energy savings between 20 and 60%, which is most pronounced in hot and dry climates

High-throughput, combinatorial synthesis of multimetallic nanoclusters

Multimetallic nanoclusters (MMNCs) offer unique and tailorable surface chemistries that hold great potential for numerous catalytic applications. The efficient exploration of this vast chemical space necessitates an accelerated discovery pipeline that supersedes traditional “trial-and-error” experimentation while guaranteeing uniform microstructures despite compositional complexity. Herein, we report the high-throughput synthesis of an extensive series of ultrafine and homogeneous alloy MMNCs, achieved by 1) a flexible compositional design by formulation in the precursor solution phase and 2) the ultrafast synthesis of alloy MMNCs using thermal shock heating (i.e., ∼1,650 K, ∼500 ms). This approach is remarkably facile and easily accessible compared to conventional vapor-phase deposition, and the particle size and structural uniformity enable comparative studies across compositionally different MMNCs. Rapid electrochemical screening is demonstrated by using a scanning droplet cell, enabling us to discover two promising electrocatalysts, which we subsequently validated using a rotating disk setup. This demonstrated high-throughput material discovery pipeline presents a paradigm for facile and accelerated exploration of MMNCs for a broad range of applications

Single-digit-micrometer thickness wood speaker

Partial funding for Open Access provided by the UMD Libraries' Open Access Publishing Fund.Thin films of several microns in thickness are ubiquitously used in packaging, electronics, and acoustic sensors. Here we demonstrate that natural wood can be directly converted into an ultrathin film with a record-small thickness of less than 10 μm through partial delignification followed by densification. Benefiting from this aligned and laminated structure, the ultrathin wood film exhibits excellent mechanical properties with a high tensile strength of 342 MPa and a Young’s modulus of 43.6 GPa, respectively. The material’s ultrathin thickness and exceptional mechanical strength enable excellent acoustic properties with a 1.83-times higher resonance frequency and a 1.25-times greater displacement amplitude than a commercial polypropylene diaphragm found in an audio speaker. As a proof-of-concept, we directly use the ultrathin wood film as a diaphragm in a real speaker that can output music. The ultrathin wood film with excellent mechanical property and acoustic performance is a promising candidate for next-generation acoustic speakers