Free-sustaining three-dimensional S235 steel-based porous electrocatalyst for highly efficient and durable oxygen evolution

A novel oxygen evolution reaction (OER) catalyst (3D S235-P steel) based on steel S235 substrate has been successfully prepared via a facile one-step surface modification. The standard Carbon Manganese steel was phosphorizated superficially leading to the formation of a unique 3D interconnected nanoporous surface with high specific area which facilitates the electrocatalytically initiated oxygen evolution reaction. The prepared 3D S235-P steel exhibits enhanced electrocatalytic OER activities in alkaline regime confirmed by a low overpotential (η=326 mV at j=10 mA cm-2) and a small Tafel slope of 68.7 mV dec-1. Moreover, the catalyst was found to be stable under long-term usage conditions functioning as oxygen evolving electrode at pH 13 as evidenced by the sufficient charge to oxygen conversion rate (Faradaic efficiency: 82.11% and 88.34% at 10 mA cm-2 and 5 mA cm-2, respectively). In addition, it turned out that the chosen surface modification renders steel S235 into an OER electrocatalyst sufficiently and stable to work in neutral pH condition. Our investigation revealed that the high catalytic activities are likely to stem from the generated Fe/(Mn) hydroxide/oxo-hydroxides generated during the OER process. The phosphorization treatment is therefore not only an efficient way to optimize the electrocatalytic performance of standard Carbon-Manganese steel, but also enables for the development of low cost and abundant steels in the field of energy conversion

Scanner‐Based Capillary Stamping

Classical microcontact printing and polymer pen lithography (PPL) involve ink transfer to substrates using solid elastomeric stamps. Ink depletion thus limits the number of successive stamping steps without reinking. Porous stamps developed to overcome this limitation are used only for manual proof‐of‐principle experiments. Here, porous composite stamps for scanner‐based capillary stamping (SCS) that can be mounted on automated printing devices designed for PPL are developed. Porous SCS composite stamps consist of a rigid controlled porous silica glass (CPG) layer and a porous polymeric stamping layer. The latter can be topographically structured with contact elements by replication molding. The mechanical stabilization by the CPG layer ensures that the contact elements are coplanar. SCS allows automated, continuous, high‐throughput patterning enabled by ink supply through the porous SCS composite stamps. Even after more than 800 consecutive stamp–substrate contacts without reinking (the porous SCS composite stamps themselves are used as ink reservoirs), ink microdroplets are deposited without deterioration of the pattern quality. However, SCS also allows supply of additional ink during ongoing stamping operations through the pore systems of the porous SCS composite stamps. SCS can easily be adapted for multi‐ink patterning and may pave the way for further upscaling of contact lithography

1.28 and 5.12 Gbps multi-channel twinax cable receiver ASICs for the ATLAS Inner Tracker Pixel Detector Upgrade

We present two prototypes of a gigabit transceiver ASIC, GBCR1 and GBCR2, both designed in a 65-nm CMOS technology for the ATLAS Inner Tracker Pixel Detector readout upgrade. The first prototype, GBCR1, has four upstream receiver channels and one downstream transmitter channel with pre-emphasis. Each upstream channel receives the data at 5.12 Gbps through a 5 meter AWG34 Twinax cable from an ASIC driver located on the pixel module and restores the signal from the high frequency loss due to the low mass cable. The signal is retimed by a recovered clock before it is sent to the optical transmitter VTRx+. The downstream driver is designed to transmit the 2.56 Gbps signal from lpGBT to the electronics on the pixel module over the same cable. The peak-peak jitter (throughout the paper jitter is always peak-peak unless specified) of the restored signal is 35.4 ps at the output of GBCR1, and 138 ps for the downstream channel at the cable ends. GBCR1 consumes 318 mW and is tested. The second prototype, GBCR2, has seven upstream channels and two downstream channels. Each upstream channel works at 1.28 Gbps to recover the data directly from the RD53B ASIC through a 1 meter custom FLEX cable followed by a 6 meter AWG34 Twinax cable. The equalized signal of each upstream channel is retimed by an input 1.28 GHz phase programmable clock. Compared with the signal at the FLEX input, the additional jitter of the equalized signal is about 80 ps when the retiming logic is o . When the retiming logic is on, the jitter is 50 ps at GBCR2 output, assuming the 1.28 GHz retiming clock is from lpGBT. The downstream is designed to transmit the 160 Mbps signal from lpGBT through the same cable connection to RD53B and the jitter is about 157 ps at the cable ends. GBCR2 consumes about 150 mW when the retiming logic is on. This design was submitted in November 2019.Comment: 7 pages, 15 figure

Nanoporous block copolymer stamps: design and applications

This thesis focuses on the surface patterning by using nanoporous block copolymer (BCP) stamps. Polystyrene‐block‐poly(2‐vinylpyridine) (PS‐b‐P2VP) was used as model BCP. Nanoporous BCP stamps were fabricated by replication of lithographically patterned silicon molds. Nanopores inside of BCP stamps were generated by swelling‐induced pore formation. A method for scanner-based capillary stamping (SCS) with spongy nanoporous BCP stamps was developed. First, in the course of stamps design using replication molding of PS-b-P2VP against surface-modified macroporous silicon molds, PS-b-P2VP fiber rings remaining on the macroporous silicon molds were obtained that allow immobilization of water drops on the hydrophobically modified surfaces of the macroporous silicon molds. Water drops immobilized by these rings can be prevented from dewetting within the PS‐b‐P2VP fiber rings. Second, after spongy nanoporous PS-b-P2VP stamps had been obtained, preliminary experiments with non-inked PS-b-P2VP stamps revealed that parts of the stamps’ contact elements can be lithographically transferred onto counterpart surfaces. As a result, arrays of nanostructured submicron PS‐b‐P2VP dots with heights of ∼100 nm onto silicon wafers and glass slides were produced. Lastly, the SCS technique was developed, which overcomes the limitation of time-consuming re-inking procedures associated with classical soft lithography including microcontact printing (µCP) and polymer pen lithography (PPL) with solid stamps, as well as the limitations regarding throughput of scanning probe‐based serial writing approaches such as nanoscale dispensing (NADIS) and other micropipetting techniques. In addition, sizes of stamped droplets can be controlled by adjusting surface wettability and dwell time

Spiral and Mesoporous Block Polymer Nanofibers Generated in Confined Nanochannels

Spiral-like or various porous polymer nanofibers have great applications in biosensor, bioengineering, and template-fabrication of functional inorganic materials. However, the fabrication of polymer nanostructures with controllable porous or spiral morphology in one process is a big challenge. Here we first demonstrated a general and easy method to generate spiral or porous block copolymer (BCP) nanofibers by using geometric confinement of nanochannels to disturb the self-assembly of BCP while nonsolvent is induced into BCP solution. Continuous spiral polymer nanofibers and polymer nanofibers with hierarchical porous nanostructures can be easily generated within channels of anodic aluminum oxide (AAO) membranes by tuning the composition and concentration of BCP. This study first reports the influence of cylinder confinement to the arrangement of BCP micelles. These spiral and porous BCP nanostructures are not only good templates to generate functional inorganic nanostructures, but also promising candidates to create biosensors or to load catalyst because their enlarged surface area enables high guest concentrations

Nanostructured Submicron Block Copolymer Dots by Sacrificial Stamping: A Potential Preconcentration Platform for Locally Resolved Sensing, Chemistry, and Cellular Interactions

Classical contact lithography involves patterning of surfaces by embossing or by transfer of ink. We report direct lithographic transfer of parts of sacrificial stamps onto counterpart surfaces. Using sacrificial stamps consisting of the block copolymer polystyrene-<i>block</i>-poly­(2-pyridine) (PS-<i>b</i>-P2VP), we deposited arrays of nanostructured submicron PS-<i>b</i>-P2VP dots with heights of ∼100 nm onto silicon wafers and glass slides. The sacrificial PS-<i>b</i>-P2VP stamps were topographically patterned with truncated-pyramidal contact elements and penetrated by spongy-continuous nanopore systems. The spongy nature of the sacrificial PS-<i>b</i>-P2VP stamps supported formation of adhesive contact to the counterpart surfaces and the rupture of the contact elements during stamp retraction. The submicron PS-<i>b</i>-P2VP dots generated by sacrificial stamping can be further functionalized; examples include loading submicron PS-<i>b</i>-P2VP dots with dyes and attachment of gold nanoparticles to their outer surfaces. The arrays of submicron PS-<i>b</i>-P2VP dots can be integrated into setups for advanced optical microscopy, total internal reflection fluorescence microscopy, or Raman microscopy. Arrays of nanostructured submicron block copolymer dots may represent a preconcentration platform for locally resolved sensing and locally resolved monitoring of cellular interactions or might be used as microreactor arrays in lab-on-chip configurations