Modification of amino acids at shock pressures of 3 to 30 GPA: Initial results

Since the discovery of amino acids in the Murchison meteorite, much speculation has focused on their origin and subsequent alteration, including the possible role of secondary processes, both terrestrial and extraterrestrial. As collisional processes and associated shock waves seem to have affected the silicate portions of many primitive meteorites, a mixture of powdered Allende (125-150 m grain size) and nine synthetic amino acids (six protein and three nonprotein) were subjected to controlled shock pressures from 3 to 30 GPa to determine the effect of shocks on amino acid survivability. Preliminary characterizations of the recovered shock products are presented

Experimental Impacts into Chondritic Targets

A fragment of an L6 chondrite (ALH 85017,13) with an initial mass (M(sub 0)) of 464.1 g was the target in a series of experimental impacts in which the largest remaining fragment (M(sub R)) after each shot was impacted by a 3.18-mm ceramic sphere at a nominal speed of 2 km/s. This continued until the mass of the largest remaining piece was less than half the mass of the target presented to that shot (M(sub S)). Two chunks of Bushveldt gabbro with similar initial masses were also impacted under the same conditions until M(sub R) was less than half M(sub 0). The two gabbro targets required a total of 1.51x10(exp 7) and 1.75x10(exp 7) erg/g to attain 0.27 and 0.33 M(sub R)/M(sub 0), respectively; the chondrite, however, was considerably tougher, reaching 0.40 and 0.21 M(sub R)/M(sub 0) only after receiving 2.37x10(exp 7) and 3.10x10(exp 7) erg g-1, respectively. The combined ejecta and spallation products from the gabbro impacts were coarser than those from the chondrite and in sufficient quantities that the new surface areas exceeded those from the meteorite until the fifth shot in the chondrite series, which was the number of impacts required to disrupt each gabbro target (i.e., MR/M0 = 0.5). Unlike the behavior shown in previous regolith-evolution series, neither gabbro target produced an enhancement in the size fraction reflecting the mean size of the crystals composing the rock (about 3 mm), an effect possibly related to the width of the shock pulse. The original chondrite was so fine-grained and fractured, and the variance in its grain-size distribution so large, that effects related to grain-size were relegated to the <63- m fraction. Impacts into ALH 85017 produced abundant, fine-grained debris, but otherwise the slopes of its size distributions were comparable to those from other experiments involving natural and fabricated terrestrial targets. The characteristic slopes of the chondrite's size distributions, however, were notably more constant over the entire nine-impact series than those from any of the terrestrial targets, a testament to the control over comminution apparently exerted by pre-existing fractures and other, microscopic damage in the meteorite. The enhancement in the finer fraction of debris from ALH 85017 indicates that ordinary chondrites in solar orbit would be very efficient contributors to the cosmic-dust complex. At the same time, the greater resistance to disruption displayed by ordinary chondrites relative to that exhibited by igneous rocks indicates that a selection effect could be operative between the annealed, ordinary-chondritic breccias and relatively weaker, differentiated meteorites. Preferential survival from their time in the regoliths of their parent bodies through their transit to Earth and passage through the atmosphere suggests that meteorite collections could be biased in favor of the ordinary chondrites

Compositional analysis and classification of projectile residues in LDEF impact craters

This catalog contains preliminary analyses of residues of hypervelocity projectiles that encountered gold substrates exposed by instrument A0187-1 on the Long Duration Exposure Facility (LDEF). This instrument was on LDEF's trailing edge where relative encounter speeds should be lowest for any non-spinning platform in low Earth orbit (LEO). Approximately 0.6 m(exp 2) of Au substrates yielded 198 impact craters greater than 20 micrometers in diameter. Some 30 percent of the craters were made by natural cosmic dust particles and some 15 percent by man-made objects. Some 50 percent of all features, however, have residues, if any, that are beyond the detection threshold of the SEM-EDXA method used. The purpose of this catalog is to provide detailed evidence and criteria that may be used to arrive at specific particle types on a case-by-case basis and to group such particles into compositional classes. Clearly this is a somewhat interpretative undertaking. For that reason, we encourage and solicit critique and comments from those interested in the systematic analysis of all impact features on LDEF

Low Density Sabot Catcher for Hypervelocity Impact Tests

The monolithic steel plate traditionally used to intercept sabot pieces during light-gas gun operations was replaced by low density material. The idea was to decrease the shock stress in these plastic sabot pieces to values below the vaporization threshold, thereby reducing the prominent soot-deposits that characterize typical target surfaces. The project was a collaboration between Orbital Debris and Planetary Science interests at JSC/ARES

The composition of meteoroids impacting LDEF

So far we have completed an initial scanning electron microscopy (SEM) survey of craters on the exterior of the Long Duration Exposure Facility (LDEF) in the 100 micron to 1mm size range and done some quantitative analysis. In typical craters, the residue appears to be a mixture of glass and FeNi and sulfide beads with an overall chondritic elemental composition. In less than 10 percent of the craters, there is a substantial amount of meteoroid debris that also contains unmelted mineral grains. The relatively high abundance of forsterite and enststite among these irregular grains suggests that a high melting point probably plays a role in surviving impact without melting

Microstructural Study of Micron-Sized Craters Simulating Stardust Impacts in Aluminum 1100 Targets

Various microscopic techniques were used to characterize experimental micro- craters in aluminium foils to prepare for the comprehensive analysis of the cometary and interstellar particle impacts in aluminium foils to be returned by the Stardust mission. First, SEM (Scanning Electron Microscopy) and EDS (Energy Dispersive X-ray Spectroscopy) were used to study the morphology of the impact craters and the bulk composition of the residues left by soda-lime glass impactors. A more detailed structural and compositional study of impactor remnants was then performed using TEM (Transmission Electron Microscopy), EDS, and electron diffraction methods. The TEM samples were prepared by Focused Ion Beam (FIB) methods. This technique proved to be especially valuable in studying impact crater residues and impact crater morphology. Finally, we also showed that InfraRed microscopy (IR) can be a quick and reliable tool for such investigations. The combination of all of these tools enables a complete microscopic characterization of the craters

Lunar Surface Operations with Dual Rovers

Lunar Electric Rovers (LER) are currently being developed that are substantially more capable than the Apollo vehicle (LRN ,"). Unlike the LRV, the new LERs provide a pressurized cabin that serves as short-sleeve environment for the crew of two, including sleeping accommodations and other provisions that allow for long tern stays, possibly up to 60 days, on the hear surface, without the need to replenish consumables from some outside source, such as a lander or outpost. As a consequence, significantly larger regions may be explored in the future and traverse distances may be measured in a few hundred kilometers (1, 2). However, crew safety remains an overriding concern, and methods other than "walk back", the major operational constraint of all Apollo traverses, must be implemented to assure -at any time- the safe return of the crew to the lander or outpost. This then causes current Constellation plans to envision long-tern traverses to be conducted with 2 LERs exclusively, each carrying a crew of two: in case one rover fails, the other will rescue the stranded crew and return all 4 astronauts in a single LER to base camp. Recent Desert Research and Technology Studies (DRATS) analog field tests simulated a continuous 14 day traverse (3), covering some 135 km, and included a rescue operation that transferred the crew and diverse consumables from one LER to another these successful tests add substantial realism to the development of long-term, dual rover operations. The simultaneous utilization of 2 LERs is of course totally unlike Apollo and raises interesting issues regarding science productivity and mission operations, the thrust of this note

Comet 81p/Wild 2: The Updated Stardust Coma Dust Fluence Measurement for Smaller (Sub 10-Micrometre) Particles

Micrometre and smaller scale dust within cometary comae can be observed by telescopic remote sensing spectroscopy [1] and the particle size and abundance can be measured by in situ spacecraft impact detectors [2]. Initial interpretation of the samples returned from comet 81P/Wild 2 by the Stardust spacecraft [3] appears to show that very fine dust contributes not only a small fraction of the solid mass, but is also relatively sparse [4], with a low negative power function describing grain size distribution, contrasting with an apparent abundance indicated by the on-board Dust Flux Monitor Instrument (DFMI) [5] operational during the encounter. For particles above 10 m diameter there is good correspondence between results from the DFMI and the particle size inferred from experimental calibration [6] of measured aerogel track and aluminium foil crater dimensions (as seen in Figure 4 of [4]). However, divergence between data-sets becomes apparent at smaller sizes, especially submicrometre, where the returned sample data are based upon location and measurement of tiny craters found by electron microscopy of Al foils. Here effects of detection efficiency tail-off at each search magnification can be seen in the down-scale flattening of each scale component, but are reliably compensated by sensible extrapolation between segments. There is also no evidence of malfunction in the operation of DFMI during passage through the coma (S. Green, personal comm.), so can the two data sets be reconciled

TOF-SIMS Analysis of Crater Residues from Wild 2 Cometary on Stardust Aluminum Foil

Impact residues of cometary particles on aluminum foils from the Stardust mission were investigated with TOF-SIMS for their elemental and organic composition. The residual matter from comet 81P/Wild 2 shows a wide compositional range, from nearly monomineralic grains to polymict aggregates. Despite the comparably small analyzed sample volume, the average element composition of the investigated residues is similar to bulk CI chondritic values. Analysis of organic components in impact residues is complicated, due to fragmentation and alteration of the compounds during the impact process and by the presence of contaminants on the aluminum foils. Nevertheless, polycyclic aromatic hydrocarbons (PAHs) that are unambiguously associated with the impact residues were observed, and thus are most likely of cometary origin

SIMS Studies of Allende Projectiles Fired into Stardust-type Aluminum Foils at 6 km/s

We have explored the feasibility of C-, N-, and O-isotopic measurements by NanoSIMS and of elemental abundance determinations by TOF-SIMS on residues of Allende projectiles that impacted Stardust-type aluminum foils in the laboratory at 6 km/s. These investigations are part of a consortium study aimed at providing the foundation for the characterization of matter associated with micro-craters that were produced during the encounter of the Stardust space probe with comet 81P/Wild 2. Eleven experimental impact craters were studied by NanoSIMS and eighteen by TOF-SIMS. Crater sizes were between 3 and 190 microns. The NanoSIMS measurements have shown that the crater morphology has only a minor effect on spatial resolution and on instrumental mass fractionation. The achievable spatial resolution is always better than 200 nm, and C- and O-isotopic ratios can be measured with a precision of several percent at a scale of several 100 nm, the typical size of presolar grains. This clearly demonstrates that presolar matter, provided it survives the impact into the aluminum foil partly intact, is recognizable even if embedded in material of Solar System origin. TOF-SIMS studies are restricted to materials from the crater rim. The element ratios of the major rockforming elements in the Allende projectiles are well characterized by the TOF-SIMS measurements, indicating that fractionation of those elements during impact can be expected to be negligible. This permits information on the type of impactor material to be obtained. For any more detailed assignments to specific chondrite groups, however, information on the abundances of the light elements, especially C, is crucial