7 research outputs found
Near-field Electrical Detection of Optical Plasmons and Single Plasmon Sources
Photonic circuits can be much faster than their electronic counterparts, but
they are difficult to miniaturize below the optical wavelength scale. Nanoscale
photonic circuits based on surface plasmon polaritons (SPs) are a promising
solution to this problem because they can localize light below the diffraction
limit. However, there is a general tradeoff between the localization of an SP
and the efficiency with which it can be detected with conventional far-field
optics. Here we describe a new all-electrical SP detection technique based on
the near-field coupling between guided plasmons and a nanowire field-effect
transistor. We use the technique to electrically detect the plasmon emission
from an individual colloidal quantum dot coupled to an SP waveguide. Our
detectors are both nanoscale and highly efficient (0.1 electrons/plasmon), and
a plasmonic gating effect can be used to amplify the signal even higher (up to
50 electrons/plasmon). These results enable new on-chip optical sensing
applications and are a key step towards "dark" optoplasmonic nanocircuits in
which SPs can be generated, manipulated, and detected without involving
far-field radiation.Comment: manuscript followed by supplementary informatio
Ion Mobility-Derived Collision Cross-Sections Add Extra Capability in Distinguishing Isomers and Compounds with Similar Retention Times: The Case of Aphidicolanes
The hyphenation of ion mobility spectrometry with high-resolution mass spectrometry has been widely used in the characterization of various metabolites. Nevertheless, such a powerful tool remains largely unexplored in natural products research, possibly mainly due to the lack of available compounds. To evaluate the ability of collision cross-sections (CCSs) in characterizing compounds, especially isomeric natural products, here we measured and compared the traveling-wave IMS-derived nitrogen CCS values for 75 marine-derived aphidicolanes. We established a CCS database for these compounds which contained 227 CCS values of different adducts. When comparing the CCS differences, 36 of 57 pairs (over 60%) of chromatographically neighboring compounds showed a ΔCCS over 2%. What is more, 64 of 104 isomeric pairs (over 60%) of aphidicolanes can be distinguished by their CCS values, and 13 of 18 pairs (over 70%) of chromatographically indistinguishable isomers can be differentiated from the mobility dimension. Our results strongly supported CCS as an important parameter with good orthogonality and complementarity with retention time. CCS is expected to play an important role in distinguishing complex and diverse marine natural products