A lattice model for the line tension of a sessile drop

Within a semi--infinite thre--dimensional lattice gas model describing the coexistence of two phases on a substrate, we study, by cluster expansion techniques, the free energy (line tension) associated with the contact line between the two phases and the substrate. We show that this line tension, is given at low temperature by a convergent series whose leading term is negative, and equals 0 at zero temperature

A compact null set containing a differentiability point of every Lipschitz function

We prove that in a Euclidean space of dimension at least two, there exists a compact set of Lebesgue measure zero such that any real-valued Lipschitz function defined on the space is differentiable at some point in the set. Such a set is constructed explicitly.Comment: 28 pages; minor modifications throughout; Lemma 4.2 is proved for general Banach space rather than for Hilbert spac

SURFACE INDUCED FINITE-SIZE EFFECTS FOR FIRST ORDER PHASE TRANSITIONS

We consider classical lattice models describing first-order phase transitions, and study the finite-size scaling of the magnetization and susceptibility. In order to model the effects of an actual surface in systems like small magnetic clusters, we consider models with free boundary conditions. For a field driven transition with two coexisting phases at the infinite volume transition point $h=h_t$, we prove that the low temperature finite volume magnetization m_{\free}(L,h) per site in a cubic volume of size $L^d$ behaves like m_\free(L,h)=\frac{m_++m_-}2 + \frac{m_+-m_-}2 \tanh \bigl(\frac{m_+-m_-}2\,L^d\, (h-h_\chi(L))\bigr)+O(1/L), where $h_\chi(L)$ is the position of the maximum of the (finite volume) susceptibility and $m_\pm$ are the infinite volume magnetizations at $h=h_t+0$ and $h=h_t-0$, respectively. We show that $h_\chi(L)$ is shifted by an amount proportional to $1/L$ with respect to the infinite volume transitions point $h_t$ provided the surface free energies of the two phases at the transition point are different. This should be compared with the shift for periodic boun\- dary conditons, which for an asymmetric transition with two coexisting phases is proportional only to $1/L^{2d}$. One also consider the position $h_U(L)$ of the maximum of the so called Binder cummulant U_\free(L,h). While it is again shifted by an amount proportional to $1/L$ with respect to the infinite volume transition point $h_t$, its shift with respect to $h_\chi(L)$ is of the much smaller order $1/L^{2d}$. We give explicit formulas for the proportionality factors, and show that, in the leading $1/L^{2d}$ term, the relative shift is the same as that for periodic boundary conditions.Comment: 65 pages, amstex, 1 PostScript figur