27,201 research outputs found

    Doubled Full Shot Noise in Quantum Coherent Superconductor - Semiconductor Junctions

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    We performed low temperature shot noise measurements in Superconductor (TiN) - strongly disordered normal metal (heavily doped Si) weakly transparent junctions. We show that the conductance has a maximum due to coherent multiple reflections at low energy and that shot noise is then twice the Poisson noise (S=4eI). The shot noise changes to the normal value (S=2eI) due to a large quasiparticle contribution.Comment: published in Physical Review Letter

    Enhancement of perfluorooctanoate and perfluorooctanesulfonate activity at acoustic cavitation bubble interfaces

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    Acoustic cavitation driven by ultrasonic irradiation decomposes and mineralizes the recalcitrant perfluorinated surfactants perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA). Pyrolytic cleavage of the ionic headgroup is the rate-determining step. In this study, we examine the sonochemical adsorption of PFOX, where X = S for PFOS and A for PFOA, by determining kinetic order and absolute rates over an initial PFOX concentration range of 20 nM to 200 μM. Sonochemical PFOX kinetics transition from pseudo-first-order at low initial concentrations, [PFOX]_i 40 μM, as the bubble interface sites are saturated. At PFOX concentrations below 100 μM, concentration-dependent rates were modeled with Langmuir−Hinshelwood (LH) kinetics. Empirically determined rate maximums, V_(Max)^(−PFOA) = 2230 ± 560 nM min^−1 and V_(Max)^(−PFOS) = 230 ± 60 nM min^−1, were used in the LH model, and sonochemical surface activities were estimated to be K_(Sono)^(PFOS) = 120000 M^−1 and K_(Sono)^(PFOA) = 28500 M^−1, 60 and 80 times greater than equilibrium surface activities, K_(Eq)^(PFOS) and K_(Eq)^(PFOA). These results suggest enhanced sonochemical degradation rates for PFOX when the bubble interface is undersaturated. The present results are compared to previously reported sonochemical kinetics of nonvolatile surfactants

    Combination ecotoxicity and testing of common chemical discharges to sewer using the Vibrio fischeri luminescence bioassay

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    In order to investigate possible synergistic or antagonistic (more or less than additive) toxicity effects, mixtures of chemicals were tested in water using a microbial bioassay. Ten toxicants (3,4-dichloroaniline, 3,5- dichlorophenol, cadmium, chromium, copper, Lindane, linear alkylbenzene sulphonate, pentachlorophenol, toluene, zinc) were chosen on the basis of their common occurrence in industrial effluents within local waste water treatment plants. These toxicants also cover a wide range of modes of toxic action, namely, polar and non-polar narcosis, membrane disruption, respiratory disruption, uncouplers of oxidative phosphorylation, biochemical disruption and enzyme inhibition. Efficient screening for possible combination toxicity between toxicants involved testing the chemicals both singly and in triplet combinations. The triplets were based on four replicates of a balanced incomplete block design (BIB). A standardised Vibrio fischeri rapid toxicity bioluminescence assay was used. The combinations tested showed that only one mixture was found to be significantly more toxic than expected from the pure singletoxicant results. Two triplets were significantly less toxic. Further tests on the more toxic triplet showed that the effect was due to only one of the 45 pairs originally screened. It is concluded that synergistic effects in combinations of toxicants are rather rare in bioluminescence systems utilising common effluents discharged to sewer

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    Hybrid phase-space simulation method for interacting Bose fields

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    We introduce an approximate phase-space technique to simulate the quantum dynamics of interacting bosons. With the future goal of treating Bose-Einstein condensate systems, the method is designed for systems with a natural separation into highly occupied (condensed) modes and lightly occupied modes. The method self-consistently uses the Wigner representation to treat highly occupied modes and the positive-P representation for lightly occupied modes. In this method, truncation of higher-derivative terms from the Fokker-Planck equation is usually necessary. However, at least in the cases investigated here, the resulting systematic error, over a finite time, vanishes in the limit of large Wigner occupation numbers. We tested the method on a system of two interacting anharmonic oscillators, with high and low occupations, respectively. The Hybrid method successfully predicted atomic quadratures to a useful simulation time 60 times longer than that of the positive-P method. The truncated Wigner method also performed well in this test. For the prediction of the correlation in a quantum nondemolition measurement scheme, for this same system, the Hybrid method gave excellent agreement with the exact result, while the truncated Wigner method showed a large systematic error.Comment: 13 pages; 6 figures; references added; figures correcte

    Incompatible Magnetic Order in Multiferroic Hexagonal DyMnO3

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    Magnetic order of the manganese and rare-earth lattices according to different symmetry representations is observed in multiferroic hexagonal (h-) DyMnO3_3 by optical second harmonic generation and neutron diffraction. The incompatibility reveals that the 3d-4f coupling in the h-RRMnO3_3 system (RR = Sc, Y, In, Dy - Lu) is substantially less developed than commonly expected. As a consequence, magnetoelectric coupling effects in this type of split-order parameter multiferroic that were previously assigned to a pronounced 3d-4f coupling have now to be scrutinized with respect to their origin

    In-situ measurement of the permittivity of helium using microwave NbN resonators

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    By measuring the electrical transport properties of superconducting NbN quarter-wave resonators in direct contact with a helium bath, we have demonstrated a high-speed and spatially sensitive sensor for the permittivity of helium. In our implementation a ∼10−3\sim10^{-3} mm3^3 sensing volume is measured with a bandwidth of 300 kHz in the temperature range 1.8 to 8.8 K. The minimum detectable change of the permittivity of helium is calculated to be ∼6×\sim6\times10−1110^{-11} ϵ0\epsilon_0/Hz1/2^{1/2} with a sensitivity of order 10−1310^{-13} ϵ0\epsilon_0/Hz1/2^{1/2} easily achievable. Potential applications include operation as a fast, localized helium thermometer and as a transducer in superfluid hydrodynamic experiments.Comment: 4 pages, 3 figure
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