6,976 research outputs found
Proton endor study of the photoexcited triplet state PT in Rps. sphaeroides R-26 photosynthetic reaction centres
The photoexcited triplet state PT of Rhodopseudomonas sphaeroides R-26 has been investigated by ENDOR measurements performed on frozen photosynthetic reaction centre solutions. For the first time hyperfine data could be obtained for PT. These data indicate a delocalisation of the triplet state over two bacteriochlorophyll a molecules
Calculation of the Voronoi boundary for lens-shaped particles and spherocylinders
We have recently developed a mean-field theory to estimate the packing
fraction of non-spherical particles [A. Baule et al., Nature Commun. (2013)].
The central quantity in this framework is the Voronoi excluded volume, which
generalizes the standard hard-core excluded volume appearing in Onsager's
theory. The Voronoi excluded volume is defined from an exclusion condition for
the Voronoi boundary between two particles, which is usually not tractable
analytically. Here, we show how the technical difficulties in calculating the
Voronoi boundary can be overcome for lens-shaped particles and spherocylinders,
two standard prolate and oblate shapes with rotational symmetry. By decomposing
these shapes into unions and intersections of spheres analytical expressions
can be obtained.Comment: 19 pages, 8 figure
Hand bone loss as an outcome measure in established rheumatoid arthritis: 2-year observational study comparing cortical and total bone loss
The aim of this 2-year longitudinal observational study was to explore hand bone loss as a disease outcome measure in established rheumatoid arthritis (RA)
The radical cation of bacteriochlorophyll b. A liquid-phase endor and triple resonance study
The previous termradical cationnext term of bacterioehlorophyll b (BChl b) is investigated by ENDOR and TRIPLE resonance in liquid solution. The experimental hyperfine coupling constants, ten proton and three nitrogen couplings, are compared with the predictions from advanced molecular-orbital calculations (RHF INDO/SP). The detailed picture obtained of the spin density distribution is a prerequisite for the investigation of the primary electron donor previous termradical cationnext term in BChl b containing photosynthetic bacteria
Black string corrections in variable tension braneworld scenarios
Braneworld models with variable tension are investigated, and the corrections
on the black string horizon along the extra dimension are provided. Such
corrections are encrypted in additional terms involving the covariant
derivatives of the variable tension on the brane, providing profound
consequences concerning the black string horizon variation along the extra
dimension, near the brane. The black string horizon behavior is shown to be
drastically modified by the terms corrected by the brane variable tension. In
particular, a model motivated by the phenomenological interesting case
regarding Eotvos branes is investigated. It forthwith provides further physical
features regarding variable tension braneworld scenarios, heretofore concealed
in all previous analysis in the literature. All precedent analysis considered
uniquely the expansion of the metric up to the second order along the extra
dimension, what is able to evince solely the brane variable tension absolute
value. Notwithstanding, the expansion terms aftermath, further accomplished in
this paper from the third order on, elicits the successive covariant
derivatives of the brane variable tension, and their respective coupling with
the extrinsic curvature, the Weyl tensor, and the Riemann and Ricci tensors, as
well as the scalar curvature. Such additional terms are shown to provide sudden
modifications in the black string horizon in a variable tension braneworld
scenarioComment: 12 pages, 5 figures, accepted in PR
Kinetics of UV254 inactivation of selected viral pathogens in a static system
Aims:  The objective of this study was to estimate UV254 inactivation constants for four viral pathogens: influenza virus type A, porcine respiratory and reproductive syndrome virus (PRRSV), bovine viral diarrhoea virus (BVDV) and reovirus.
Methods and Results:  Viruses in culture medium were exposed to one of nine doses of UV254 and then titrated for infectious virus. Analysis showed that viral inactivation by UV254 was more accurately described by a two-stage inactivation model vs a standard one-stage inactivation model.
Conclusions:  The results provided evidence for the existence of two heterogeneous viral subpopulations among the viruses tested, one highly susceptible to UV254 inactivation and the other more resistant. Importantly, inactivation constants based on the one-stage inactivation model would have underestimated the UV254 dose required for the inactivation of these viruses under the conditions of the experiment.
Significance and Impact of the Study:  To improve the accuracy of estimates, it is recommended that research involving the inactivation of micro-organisms evaluates inactivation kinetics using both one-stage and two-stage models. These results will be of interest to persons responsible for microbial agents under laboratory or field conditions
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