1,305 research outputs found

    Continuous symmetry of C60 fullerene and its derivatives

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    Conventionally, the Ih symmetry of fullerene C60 is accepted which is supported by numerous calculations. However, this conclusion results from the consideration of the molecule electron system, of its odd electrons in particular, in a close-shell approximation without taking the electron spin into account. Passing to the open-shell approximation has lead to both the energy and the symmetry lowering up to Ci. Seemingly contradicting to a high-symmetry pattern of experimental recording, particularly concerning the molecule electronic spectra, the finding is considered in the current paper from the continuous symmetry viewpoint. Exploiting both continuous symmetry measure and continuous symmetry content, was shown that formal Ci symmetry of the molecule is by 99.99% Ih. A similar continuous symmetry analysis of the fullerene monoderivatives gives a reasonable explanation of a large variety of their optical spectra patterns within the framework of the same C1 formal symmetry exhibiting a strong stability of the C60 skeleton.Comment: 11 pages. 5 figures. 6 table

    Dental management considerations for the patient with an acquired coagulopathy. Part 1: Coagulopathies from systemic disease

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    Current teaching suggests that many patients are at risk for prolonged bleeding during and following invasive dental procedures, due to an acquired coagulopathy from systemic disease and/or from medications. However, treatment standards for these patients often are the result of long-standing dogma with little or no scientific basis. The medical history is critical for the identification of patients potentially at risk for prolonged bleeding from dental treatment. Some time-honoured laboratory tests have little or no use in community dental practice. Loss of functioning hepatic, renal, or bone marrow tissue predisposes to acquired coagulopathies through different mechanisms, but the relationship to oral haemostasis is poorly understood. Given the lack of established, science-based standards, proper dental management requires an understanding of certain principles of pathophysiology for these medical conditions and a few standard laboratory tests. Making changes in anticoagulant drug regimens are often unwarranted and/or expensive, and can put patients at far greater risk for morbidity and mortality than the unlikely outcome of postoperative bleeding. It should be recognised that prolonged bleeding is a rare event following invasive dental procedures, and therefore the vast majority of patients with suspected acquired coagulopathies are best managed in the community practice setting

    Kinetic Energy, Condensation Energy, Optical Sum Rule and Pairing Mechanism in High-Tc Cuprates

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    The mechanism of high-Tc superconductivity is investigated with interests on the microscopic aspects of the condensation energy. The theoretical analysis is performed on the basis of the FLEX approximation which is a microscopic description of the spin-fluctuation-induced-superconductivity. Most of phase transitions in strongly correlated electron system arise from the correlation energy which is copmetitive to the kinetic energy. However, we show that the kinetic energy cooperatively induces the superconductivity in the underdoped region. This unusual decrease of kinetic energy below T_c is induced by the feedback effect. The feedback effect induces the magnetic resonance mode as well as the kink in the electronic dispersion, and alters the properties of quasi-particles, such as mass renormalization and lifetime. The crossover from BCS behavior to this unusual behavior occurs for hole dopings. On the other hand, the decrease of kinetic energy below T_c does not occur in the electron-doped region. We discuss the relation to the recent obserbation of the violation of optical sum rule

    Renormalization Group Induced Neutrino Mass in Supersymmetry without R-parity

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    We study supersymmetric models without R parity and with universal soft supersymmetry breaking terms. We show that as a result of the renormalization group flow of the parameters, a misalignment between the directions in field space of the down-type Higgs vacuum expectation value vdv_d and of the μ\mu term is always generated. This misalignment induces a mixing between the neutrinos and the neutralinos, resulting in one massive neutrino. By means of a simple approximate analytical expression, we study the dependence on the different parameters that contribute to the misalignment and to mνm_\nu. In large part of the parameter space this effect dominates over the standard one-loop contributions to mνm_\nu; we estimate 1 MeV \lsim m_\nu \lsim 1 GeV. Laboratory, cosmological and astrophysical constraints imply m_\nu \lsim 100 eV. To be phenomenologically viable, these models must be supplemented with some additional mechanism to ensure approximate alignment and to suppress mνm_\nu.Comment: 21 pages, LaTex. Few points clarified, results unchanged. Final version to appear on Physical Review

    Charge pairing, superconducting transition and supersymmetry in high-temperature cuprate superconductors

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    We propose a model for high-Tc_{c} superconductors, valid for 0δδSC0\leq\delta\leq\delta_{SC}, that includes both the spin fluctuations of the Cu++^{++} magnetic ions and of the O^{--} doped holes. Spin-charge separation is taken into account with the charge of the doped holes being associated to quantum skyrmion excitations (holons) of the Cu++^{++} spin background. The holon effective interaction potential is evaluated as a function of doping, indicating that Cooper pair formation is determined by the competition between the spin fluctuations of the Cu++^{++} background and of spins of the O^{--} doped holes (spinons). The superconducting transition occurs when the spinon fluctuations dominate, thereby reversing the sign of the interaction. At this point (δ=δSC\delta = \delta_{SC}), the theory is supersymmetric at short distances and, as a consequence, the leading order results are not modified by radiative corrections. The critical doping parameter for the onset of superconductivity at T=0 is obtained and found to be a universal constant determined by the shape of the Fermi surface. Our theoretical values for δSC\delta_{SC} are in good agreement with the experiment for both LSCO and YBCO.Comment: RevTex, 4 pages, no figure

    Reconfiguration, contestation, and decline: conceptualizing mature large technical systems

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    Large technical systems (LTS) are integral to modern lifestyles but arduous to analyze. In this paper, we advance a conceptualization of LTS using the notion of mature “phases,” drawing from insights into innovation studies, science and technology studies, political science, the sociology of infra- structure, history of technology, and governance. We begin by defining LTS as a unit of analysis and explaining its conceptual utility and novelty, situating it among other prominent sociotechnical theories. Next, we argue that after LTS have moved through the (overlapping) phases proposed by Thomas Hughes of invention, expansion, growth, momentum, and style,mature LTS undergo the additional (overlapping) phases of reconfiguration, contestation (subject to pressures such as drift and crisis), and eventually stagnation and decline. We illustrate these analytical phases with historical case studies and the conceptual literature, and close by suggesting future research to refine and develop the LTS framework, particularly related to more refined typologies, temporal dimensions, and a broadening of system users. We aim to contribute to theoretical debates about the coevolution of LTS as well as empirical discussions about system-related use, socio- technical change, and policy-making

    A quantum Monte Carlo study of the one-dimensional ionic Hubbard model

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    Quantum Monte Carlo methods are used to study a quantum phase transition in a 1D Hubbard model with a staggered ionic potential (D). Using recently formulated methods, the electronic polarization and localization are determined directly from the correlated ground state wavefunction and compared to results of previous work using exact diagonalization and Hartree-Fock. We find that the model undergoes a thermodynamic transition from a band insulator (BI) to a broken-symmetry bond ordered (BO) phase as the ratio of U/D is increased. Since it is known that at D = 0 the usual Hubbard model is a Mott insulator (MI) with no long-range order, we have searched for a second transition to this state by (i) increasing U at fixed ionic potential (D) and (ii) decreasing D at fixed U. We find no transition from the BO to MI state, and we propose that the MI state in 1D is unstable to bond ordering under the addition of any finite ionic potential. In real 1D systems the symmetric MI phase is never stable and the transition is from a symmetric BI phase to a dimerized BO phase, with a metallic point at the transition

    Reversible magnetization of MgB2 single crystals with a two-gap nature

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    We present reversible magnetization measurements on MgB2 single crystals in magnetic fields up to 2.5 T applied parallel to the crystal's c-axis. This magnetization is analyzed in terms of the Hao-Clem model, and various superconducting parameters, such as the critical fields [Hc(0) and Hc2(0)], the characteristic lengths [xi(0) and lambda(0)], and the Ginzburg-Landau parameter, kappa, are derived. The temperature dependence of the magnetic penetration depth, lambda(T), obtained from the Hao-Clem analysis could not be explained by theories assuming a single gap. Our data are well described by using a two-gap model.Comment: 20 pages, 1 table, 4 figures, will be published in Phys. Rev.
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