Intrinsic effects of substitution and intercalation on thermal transport in two-dimensional TiS2_2 single crystals

The promising thermoelectric material TiS$_2$ can be easily chemically doped and intercalated. We present here studies of single crystals that are intercalated with excess Ti or Co, or substituted with Ta. We demonstrate the intrinsic impact of these dopants on the thermal transport in the absence of grain boundary scattering. We show that Ta doping has the greatest impact on the thermal scattering rate per ion added, leading to a five-fold reduction in the lattice thermal conductivity as compared to stoichiometric single crystals.Comment: 5 pages, 2 figure

Strong photo-absorption by a single quantum wire in waveguide-transmission spectroscopy

We measured the absorption spectrum of a single T-shaped, 14x6 nm lateral-sized quantum wire embedded in an optical waveguide using waveguide-transmission spectroscopy at 5 K. In spite of its small volume, the one-dimensional-exciton ground state shows a large absorption coefficient of 80 /cm, or a 98 % absorption probability for a single pass of the 500-um-long waveguide.Comment: 4 pages, 3 figure

Room-temperature excitonic absorption in quantum wires

We measured absorption spectra of T-shaped quantum wires at room temperature using waveguide-transmission spectroscopy. Strong and narrow room-temperature one-dimensional-exciton absorption peak was observed, which shows peak modal absorption coefficient of 160 cm$^{-1}$ per 20 wires with $\Gamma$-factor of $4.3\times10^{-3}$, width of 7.2 meV, and strong polarization anisotropy.Comment: 3pages, 3figure, 1tabl

Entropy production in a longitudinally expanding Yang–Mills field with use of the Husimi function: semiclassical approximation

We investigate the possible thermalization process of the highly occupied and weakly coupled Yang–Mills fields expanding along the beam axis through an evaluation of the entropy, particle number, and pressure anisotropy. The time evolution of the system is calculated by solving the equation of motion for the Wigner function in the semiclassical approximation with initial conditions mimicking the glasma. For the evaluation of the entropy, we adopt Husimi–Wehrl (HW) entropy, which is obtained by using the Husimi function, a positive semidefinite quantum distribution function given by smearing the Wigner function. By numerical calculations at g = 0.1 and 0.2, the entropy production is found to occur together with the particle creation in two distinct stages: In the first stage, the particle number and entropy at low longitudinal momenta grow rapidly. In the second stage, the particle number and entropy of higher longitudinal momentum modes show a slower increase. The pressure anisotropy remains in our simulation and implies that the system is still out of equilibrium

Imaging of emission patterns in a T-shaped quantum wire laser

Spatially and spectrally resolved microscopic images of spontaneous and stimulated emissions are imaged at the mirror facets of a GaAs T-shaped quantum wire laser with high uniformity. Laser emission from the one-dimensional ground state reveals a circular image located at the core of a T-shaped optical waveguide but significantly smaller in area than the low power spontaneous emission from the same waveguide. These images unambiguously allow assignment of all spontaneous and laser emissions to the wire ground state and respective intersecting wells in the structure.Comment: 4 pages, 3 figure

Giant enhancement of cryogenic thermopower by polar structural instability in the pressurized semimetal MoTe2

We found that a high mobility semimetal 1T'-MoTe2 shows a significant pressure-dependent change in the cryogenic thermopower in the vicinity of the critical pressure, where the polar structural transition disappears. With the application of a high pressure of 0.75 GPa, while the resistivity becomes as low as 10 {\mu}{\Omega}cm, thermopower reached the maximum value of 60 {\mu}VK-1 at 25 K, leading to a giant thermoelectric power factor of 300 {\mu}WK-2cm-1. Based on semiquantitative analyses, the origin of this behavior is discussed in terms of inelastic electron-phonon scattering enhanced by the softening of zone center phonon modes associated with the polar structural instability.Comment: 13 pages, 4 figures Physical review B (accepted

Superconductivity in a ferroelectric-like topological semimetal SrAuBi

Given the rarity of metallic systems that exhibit ferroelectric-like transitions, it is apparently challenging to find a system that simultaneously possesses superconductivity and ferroelectric-like structural instability. Here, we report the observation of superconductivity at 2.4 K in a layered semimetal SrAuBi characterized by strong spin-orbit coupling (SOC) and ferroelectric-like lattice distortion. Single crystals of SrAuBi have been successfully synthesized and found to show a polar-nonpolar structure transition at 214 K, which is associated with the buckling of Au-Bi honeycomb lattice. On the basis of the band calculations considering SOC, we found significant Rashba-type spin splitting and symmetry-protected multiple Dirac points near the Fermi level. We believe that this discovery opens up new possibilities of pursuing exotic superconducting states associated with the semimetallic band structure without space inversion symmetry and the topological surface state with the strong SOC.Comment: 17 pages, 6 figures (npj Quantum Materials in press

Unveiling the orbital-selective electronic band reconstruction through the structural phase transition in TaTe2_2

Tantalum ditelluride TaTe$_2$ belongs to the family of layered transition metal dichalcogenides but exhibits a unique structural phase transition at around 170 K that accompanies the rearrangement of the Ta atomic network from a "ribbon chain" to a "butterfly-like" pattern. While multiple mechanisms including Fermi surface nesting and chemical bonding instabilities have been intensively discussed, the origin of this transition remains elusive. Here we investigate the electronic structure of single-crystalline TaTe$_2$ with a particular focus on its modifications through the phase transition, by employing core-level and angle-resolved photoemission spectroscopy combined with first-principles calculations. Temperature-dependent core-level spectroscopy demonstrates a splitting of the Ta $4f$ core-level spectra through the phase transition indicative of the Ta-dominated electronic state reconstruction. Low-energy electronic state measurements further reveal an unusual kink-like band reconstruction occurring at the Brillouin zone boundary, which cannot be explained by Fermi surface nesting or band folding effects. On the basis of the orbital-projected band calculations, this band reconstruction is mainly attributed to the modifications of specific Ta $5d$ states, namely the $d_{XY}$ orbitals (the ones elongating along the ribbon chains) at the center Ta sites of the ribbon chains. The present results highlight the strong orbital-dependent electronic state reconstruction through the phase transition in this system and provide fundamental insights towards understanding complex electron-lattice-bond coupled phenomena.Comment: 21 pages, 5 figure