Air pollution at transport interchanges

Air pollution from DEEEs is becoming an increased international concern, and whilst attention has been primarily focused on the automotive industry, concerns have also been raised about emissions from diesel rail vehicles. The research is designed to assess the hypothesis that diesel rolling stock severely impacts air quality at Birmingham New Street station due to the station’s enclosed nature. To assess this hypothesis, an extensive series of long term measurements were made at Birmingham New Street station. The monitoring campaign consisted of diffusion tube measurements, to measure NO2 at locations in and around the station, followed by measurements of NOx, PM, CO2 and BC at stationary and mobile sites at the platform level. The results illustrated that diesel trains serving the station elevated pollutant concentrations, particularly oxides of nitrogen. During the sampling campaign the average NO2 concentration in the centre of platform 10/11 was 407 μg/m3, approximately 10 times greater than the EU ambient air quality limit. NO exceed its WEL 35% of the time during the monitoring campaign for the same site. Furthermore, this research concludes that CO2 is not suitable as a surrogate for assessing DEEEs exposure. NO2 concentrations exceeded their relevant exposure limits, whilst CO2 did not exceed the ventilation system’s 50% speed threshold, as a result it is unlikely that harmful pollutants were being successfully exhausted from the station. The environmental analysis identified a potential trapped vortex in the West end of the station, which could have an impact on the ventilation system in place at Birmingham New Street station. It is clear that this research has been pivotal in driving a focus towards air quality with the railway industry and has prompted further research at other enclosed railway stations

Evaluation of air quality at the Birmingham New Street Railway Station

Air pollution from diesel emissions is becoming an increased international concern, and whilst attention has been primarily focused on the automotive industry, concerns have also been raised about emissions from diesel rail vehicles. This paper reports an extensive series of measurements made at the Birmingham New Street station, a major rail interchange in the Midlands of England, with a mix of diesel and electric train movements, which is of particular concern because of the enclosed nature of the platforms. This study was undertaken in collaboration with Network Rail to better understand the environment in and around the station over a longer period to provide a more detailed analysis of the complex environment at the station. The station environment has been considered in terms of the European Union (EU) and Department of Environment, Food and Rural Affairs (DEFRA) limits as part of the monitoring methodology, but it should be noted that these limits do not apply in this environment as the Management of Health and Safety at Work Regulation 1999 and the Control of Substances Hazardous to Health Regulations 2002 are applicable. The monitoring campaign consisted of diffusion tube measurements to measure nitrogen dioxide at a large number of different locations throughout and around the station. These were followed by detailed measurements of oxides of nitrogen, particulate matter, carbon dioxide and black carbon (a diesel tracer) at a smaller number of sites at the platform level. The results are analysed to give concentrations over a wide variety of time scales, and long- and short-term averages. The effects of ambient wind conditions and individual train movements are also considered. Recommendations are made for possible remedial measures and for future work to more fully understand the physical mechanisms involved. </jats:p

Air quality in enclosed railway stations

In 2012, the World Health Organization's International Agency for Research on Cancer (IARC) reclassified diesel engine exhaust and related ambient air pollution to be carcinogenic and associated with increased mortality from lung cancer. This could have critical consequences for both public and occupational health in enclosed railway stations where ventilation is often inadequate. Recent policies encouraging a shift to public transport, along with increasing passenger and train numbers, have led to a variety of co-benefits, including improved health and well-being from increased walking and cycling. This paper considers the unintended consequences of a reduction of air quality in crowded enclosed railway stations and concludes with a number of possible interventions to ensure that public health is not affected, especially by air pollution from stationary diesel trains. Pollution from electric trains can also lead to poor air quality due to the production of metal-rich ultrafine particles from brake linings, friction between wheel and rail, and from overhead pantographs. Current occupational health standards are not suitable for enclosed railway stations and need to be reconsidered in the light of the IARC findings. More measurements of the levels of particulates and nitrogen dioxide in enclosed railway stations need to be undertaken and published. </jats:p

Time periods of altered risk for severe injection drug use-associated skin and soft-tissue infections: protocol for a self-controlled case series in New South Wales, Australia, 2001-2018

Injection drug use-associated bacterial and fungal infections (e.g., skin and soft-tissue infections, endocarditis, osteomyelitis, etc.) are common health problems among people who inject drugs, associated with pain, disability, and death. The incidence of these infections is rising, and better understanding of the social and environmental factors that shape individual injecting practices and risk for injecting-related infections is urgently needed. Using a self-controlled study design, the aim of this proposed study is to quantify the risks of injecting-related skin and soft-tissue infections associated with initiation of, exposure to, and discontinuation of incarceration and OAT among a sample of people with opioid use disorder

Neighbourhood, Route and Workplace-Related Environmental Characteristics Predict Adults' Mode of Travel to Work

Commuting provides opportunities for regular physical activity which can reduce the risk of chronic disease. Commuters' mode of travel may be shaped by their environment, but understanding of which specific environmental characteristics are most important and might form targets for intervention is limited. This study investigated associations between mode choice and a range of objectively assessed environmental characteristics.Participants in the Commuting and Health in Cambridge study reported where they lived and worked, their usual mode of travel to work and a variety of socio-demographic characteristics. Using geographic information system (GIS) software, 30 exposure variables were produced capturing characteristics of areas around participants' homes and workplaces and their shortest modelled routes to work. Associations between usual mode of travel to work and personal and environmental characteristics were investigated using multinomial logistic regression.Of the 1124 respondents, 50% reported cycling or walking as their usual mode of travel to work. In adjusted analyses, home-work distance was strongly associated with mode choice, particularly for walking. Lower odds of walking or cycling rather than driving were associated with a less frequent bus service (highest versus lowest tertile: walking OR 0.61 [95% CI 0.20–1.85]; cycling OR 0.43 [95% CI 0.23–0.83]), low street connectivity (OR 0.22, [0.07–0.67]; OR 0.48 [0.26–0.90]) and free car parking at work (OR 0.24 [0.10–0.59]; OR 0.55 [0.32–0.95]). Participants were less likely to cycle if they had access to fewer destinations (leisure facilities, shops and schools) close to work (OR 0.36 [0.21–0.62]) and a railway station further from home (OR 0.53 [0.30–0.93]). Covariates strongly predicted travel mode (pseudo r-squared 0.74).Potentially modifiable environmental characteristics, including workplace car parking, street connectivity and access to public transport, are associated with travel mode choice, and could be addressed as part of transport policy and infrastructural interventions to promote active commuting

Towards the synthesis of alkoxy-substituted [2.2] para-cyclophenes and [2.2]para-cyclophane-1-enes; tailored monomers for the preparation of well-defined, functionalised ppv

This thesis describes a route towards the synthesis of alkoxy-functionalised [2.2] para-cyclophenes and [2.2]-para-cyclophane-1-enes as possible monomers for the preparation of functionalised PPVs via ROMP, using their corresponding alkoxy-functionalised stilbenes as precursors to furnish the desired cyclophenes through a ring-closing reaction. Chapter 1 is divided into three sections, A, B and C. Section A introduces the concept of conducting and electroluminescent polymers, with particular emphasis upon polyacetylene and PPV. Section B discusses stilbenes in detail, while section C examines the structure, preparation and reactivity of cyclophanes and cyclophenes, specifically [2.2] para-cyclophane and [2.2] para-cyclophene. Chapter 2 explains the synthesis of a series of alkoxy-substituted benzaldehydes, designed as easily accessible, readily functionalised precursors to alkoxy-substituted stilbenes, while Chapter 3 shows how these alkoxy-substituted benzaldehydes can be transformed into stilbenes, through the application of either the McMurry, Wittig, or Horner-Wittig reactions. Chapter 4 describes further transformations of alkoxy-substituted stilbenes, with emphasis placed upon achieving ring-closing to furnish the desired [2.2] para-cyclophenes and [2.2] para-cyclophene-1-enes. Preparation of an oligomeric form of PPV from the same stilbene precursors is also discussed, and the photophysics of both this oligomer and its related stilbenes is investigated. Chapter 5 outlines an alternative route towards alkoxy-functionalised [2.2] para-cyclophenes, via a Ramberg-Backlund rearrangement of functionalised cyclic dithioethers, and Chapter 6 gives overall conclusions for this thesis, briefly introducing possible further studies to be undertaken on this topic. Chapter 7 contains experimental details and characterisation data for all compounds prepared during the course of this work