Oxidative Stress and Antioxidant Defenses Induced by Physical Exercise

This chapter intends to present the physiological and biochemical mechanisms by which exercise induces the appearance of oxidative stress, as well as the characteristics of the physical exercise that involve the appearance of oxidative stress in the human organism

What Does It Mean to Be Responsive to a Partner’s Sexual Needs? Toward a Definition of Sexual Need Responsiveness

Being responsive to a partner’s sexual needs in relationships (i.e., sexual need responsiveness) is associated with higher sexual and relationship satisfaction. Previous research has focused on researcher-led definitions of sexual need responsiveness. The purpose of the present study was to develop a participant-informed definition of sexual need responsiveness. A total of 305 individuals responded to five open-ended questions concerning the definition and behaviors pertaining to sexual need responsiveness. The content analysis results showed that the most common elements in participants’ definition included listening to and accommodating each other's sexual needs and wishes whenever possible, while respecting both partners’ safety and boundaries. Both verbal and non-verbal communication in various forms was used to express and share needs with partners and participants often evaluated responsiveness in terms of their sexual satisfaction. The results provide a participant-informed definition of sexual need responsiveness and can be used to inform research and clinical practice.University of Lausann

Synthesis, structure and reactivity of Pd and Ir complexes based on new lutidine-derived NHC/phosphine mixed pincer ligands

Coordination studies of new lutidine-derived hybrid NHC/phosphine ligands (CNP) to Pd and Ir have been performed. Treatment of the square-planar [Pd(CNP)Cl](AgCl2) complex 2a with KHMDS produces the selective deprotonation at the CH2P arm of the pincer to yield the pyridine-dearomatised complex 3a. A series of cationic [Ir(CNP)(cod)]+ complexes 4 has been prepared by reaction of the imidazolium salts 1 with Ir(acac)(cod). These derivatives exhibit in the solid state, and in solution, a distorted trigonal bipyramidal structure in which the CNP ligands adopt an unusual C(axial)–N(equatorial)–P(equatorial) coordination mode. Reactions of complexes 4 with CO and H2 yield the carbonyl species 5a(Cl) and 6a(Cl), and the dihydrido derivatives 7, respectively. Furthermore, upon reaction of complex 4b(Br) with base, selective deprotonation at the methylene CH2P arms is observed. The, thus formed, deprotonated Ir complex 8b reacts with H2 in a ligand-assisted process leading to the trihydrido complex 9b, which can also be obtained by reaction of 7b(Cl) with H2 in the presence of KOtBu. Finally, the catalytic activity of Ir–CNP complexes in the hydrogenation of ketones has been briefly assessed.CTQ2013-45011-P, CTQ2016-80814-R and CTQ2014 -51912-RE

EM Parametric Study of Length Matching Elements Exploiting an ANSYS HFSS Matlab-Python Driver

This work presents a Python-based driver for ANSYS HFSS for length matching elements (LME) implemented in Matlab. The driver allows full-wave EM parametric simulation of length matching elements, whose S-parameters are inserted in other circuit simulators, such as ADS, for a complete interconnect validation. Three different LME (i.e., trapezoidal, triangular, and rectangular) are analyzed using the driver in a common high-speed routing scenario. The driver proposed in this work allows verifying that the three LME considered have a similar performance up to 5 GHz, indicating that these LME can be used as mismatch (phase skew) compensation structures in some interfaces within this frequency band, such as USB 3.0, PCIe Gen3 or 1 GBASE Ethernet. On the other hand, the trapezoidal LME shows the best performance for frequencies higher than 5 GHz, with a low impact in the electromagnetic interference (EMI), making it the most recommended for high-speed interfaces with operating frequencies higher than 5 GHz

Caracterización de materiales antiguos de construcción (tapial y adobe) en las iglesias de Cisneros, Villada y Boada de Campos (Palencia)

The aim of this work is to characterize the ancient building materials (mud wall and adobe) of three churches in the province of Palencia. This is the first part of a study which seeks to evaluate how the mud walls of the tower of the church of Cisneros reacted to restoration treatment which consisted of a structural reinforcement made by injecting a highly fluid grout of cement/lime/sand mortar. This treatment implies the introduction of large quantities of water into the fabric. The mud walls of the tower of Cisneros are compositionally and texturally very similar to each other, which indicates that despite their large dimensions, care was taken in the homogeneity of the materials. These mud walls are also very similar to those of the church of Villada. The original raw material is mud with some additives (rubble, ashes, bones, etc.) and some remains of lime used as a stabiliser. Although there is a very high proportion of clay, no effervescing clay has been detected. Hence it is deduced that once the mud wall was built, there were no important changes in volume due to variation in the humidity of the fabric. The characteristics of the adobe of the tower of Boada are logically different form those of the mud walls, being made of less sandy, more clayey mud with a high proportion of straw that the mud walls do not have, and without the addition of bricks, bones, etc.El objetivo de este trabajo es caracterizar los materiales antiguos de construcción (tapial y adobe) de tres iglesias en la provincia de Falencia. El trabajo es la primera parte de un estudio en el que se pretende evaluar el comportamiento de los tapiales de la torre de la iglesia de Cisneros frente al tratamiento de restauración, consistente en un cosido estructural mediante la realización de perforaciones en las que se introduce una barra de acero y donde, posteriormente, se inyecta una lechada muy fluidificada de mortero de cemento/cal/arena. Este tratamiento implica la introducción en las fábricas de grandes cantidades de agua. Los tapiales de la torre de Cisneros son, composicional y texturalmente, muy similares entre sí, lo que indica que, a pesar de sus grandes dimensiones, se cuidó la homogeneidad de los materiales. Estos tapiales guardan una notable similitud con los de la iglesia de Villada. La materia prima original es barro con algunos aditivos (escombro, cenizas, huesos, etc.) y algunos restos de cal empleada como estabilizante. Aunque la proporción de arcilla es muy elevada no se han detectado arcillas hinchables, de lo que se deduce que una vez construido el tapial no se habrían producido importantes cambios de volumen por variaciones de humedad de las fábricas. Las características del adobe de la torre de Boada son lógicamente diferentes de las de los tapiales estando constituido por un barro menos arenoso, más arcilloso, con una elevada proporción de paja que no tienen los tapiales y sin adiciones de ladrillos, huesos, etc