Development of the adjoint of GEOS-Chem

We present the adjoint of the global chemical transport model GEOS-Chem, focusing on the chemical and thermodynamic relationships between sulfate – ammonium – nitrate aerosols and their gas-phase precursors. The adjoint model is constructed from a combination of manually and automatically derived discrete adjoint algorithms and numerical solutions to continuous adjoint equations. Explicit inclusion of the processes that govern secondary formation of inorganic aerosol is shown to afford efficient calculation of model sensitivities such as the dependence of sulfate and nitrate aerosol concentrations on emissions of SOx, NOx, and NH3. The adjoint model is extensively validated by comparing adjoint to finite difference sensitivities, which are shown to agree within acceptable tolerances; most sets of comparisons have a nearly 1:1 correlation and R2>0.9. We explore the robustness of these results, noting how insufficient observations or nonlinearities in the advection routine can degrade the adjoint model performance. The potential for inverse modeling using the adjoint of GEOS-Chem is assessed in a data assimilation framework through a series of tests using simulated observations, demonstrating the feasibility of exploiting gas- and aerosol-phase measurements for optimizing emission inventories of aerosol precursors

Impact of the isoprene photochemical cascade on tropical ozone

Tropical tropospheric ozone affects Earth's radiative forcing and the oxidative capacity of the atmosphere. Considerable work has been devoted to the study of the processes controlling its budget. Yet, large discrepancies between simulated and observed tropical tropospheric ozone remain. Here, we characterize some of the mechanisms by which the photochemistry of isoprene impacts the budget of tropical ozone. At the regional scale, we use forward sensitivity simulation to explore the sensitivity to the representation of isoprene nitrates. We find that isoprene nitrates can account for up to 70% of the local NO_x = NO+NO_2 sink. The resulting modulation of ozone can be well characterized by their net modulation of NO_x. We use adjoint sensitivity simulations to demonstrate that the oxidation of isoprene can affect ozone outside of continental regions through the transport of NO_x over near-shore regions (e.g., South Atlantic) and the oxidation of isoprene outside of the boundary layer far from its emissions regions. The latter mechanism is promoted by the simulated low boundary-layer oxidative conditions. In our simulation, ~20% of the isoprene is oxidized above the boundary layer in the tropics. Changes in the interplay between regional and global effect are discussed in light of the forecasted increase in anthropogenic emissions in tropical regions

Inverse modeling and mapping US air quality influences of inorganic PM_(2.5) precursor emissions using the adjoint of GEOS-Chem

Influences of specific sources of inorganic PM_(2.5) on peak and ambient aerosol concentrations in the US are evaluated using a combination of inverse modeling and sensitivity analysis. First, sulfate and nitrate aerosol measurements from the IMPROVE network are assimilated using the four-dimensional variational (4D-Var) method into the GEOS-Chem chemical transport model in order to constrain emissions estimates in four separate month-long inversions (one per season). Of the precursor emissions, these observations primarily constrain ammonia (NH_3). While the net result is a decrease in estimated US~NH_3 emissions relative to the original inventory, there is considerable variability in adjustments made to NH_3 emissions in different locations, seasons and source sectors, such as focused decreases in the midwest during July, broad decreases throughout the US~in January, increases in eastern coastal areas in April, and an effective redistribution of emissions from natural to anthropogenic sources. Implementing these constrained emissions, the adjoint model is applied to quantify the influences of emissions on representative PM_(2.5) air quality metrics within the US. The resulting sensitivity maps display a wide range of spatial, sectoral and seasonal variability in the susceptibility of the air quality metrics to absolute emissions changes and the effectiveness of incremental emissions controls of specific source sectors. NH_3 emissions near sources of sulfur oxides (SO_x) are estimated to most influence peak inorganic PM_(2.5) levels in the East; thus, the most effective controls of NH_3 emissions are often disjoint from locations of peak NH_3 emissions. Controls of emissions from industrial sectors of SO_x and NO_x are estimated to be more effective than surface emissions, and changes to NH_3 emissions in regions dominated by natural sources are disproportionately more effective than regions dominated by anthropogenic sources. NOx controls are most effective in northern states in October; in January, SO_x controls may be counterproductive. When considering ambient inorganic PM_(2.5) concentrations, intercontinental influences are small, though transboundary influences within North America are significant, with SO_x emissions from surface sources in Mexico contributing almost a fourth of the total influence from this sector

A remarkable recurrent nova in M 31: The 2010 eruption recovered and evidence of a six-month period

The Andromeda Galaxy recurrent nova M31N 2008-12a has been caught in eruption nine times. Six observed eruptions in the seven years from 2008 to 2014 suggested a duty cycle of ~1 year, which makes this the most rapidly recurring system known and the leading single-degenerate Type Ia Supernova progenitor candidate; but no 2010 eruption has been found so far. Here we present evidence supporting the recovery of the 2010 eruption, based on archival images taken at and around the time. We detect the 2010 eruption in a pair of images at 2010 Nov 20.52 UT, with a magnitude of m_R = 17.84 +/- 0.19. The sequence of seven eruptions shows significant indications of a duty cycle slightly shorter than one year, which makes successive eruptions occur progressively earlier in the year. We compared three archival X-ray detections with the well observed multi-wavelength light curve of the 2014 eruption to accurately constrain the time of their optical peaks. The results imply that M31N 2008-12a might have in fact a recurrence period of ~6 months (175 +/- 11 days), making it even more exceptional. If this is the case, then we predict that soon two eruptions per year will be observable. Furthermore, we predict the next eruption will occur around late Sep 2015. We encourage additional observations.Comment: 4 pages, 3 figures, 2 tables; submitted to A&A Letter

Thyroxine-binding globulin: investigation of microheterogeneity

Preparations of T4-binding globulin (TBG) from human serum was performed using only two affinity chromatography steps. Purity of the protein was demonstrated by a single band in overloaded disc and sodium dodecyl sulfate electrophoresis, equimolar binding to T4, and linearity in sedimentation velocity run. The molecular weight was calculated to be 60,000 +/- 3,000 daltons (n = 3), the sedimentation coefficient was 3.95S, and the Stokes' radius was 37 A. The amino acid composition was found to be in good agreement with the calculations of other authors. By isoelectric focussing (IEF), pure TBG showed four main bands at pH 4.25, 4.35, 4.45, and 4.55 together with several fainter bands. The N- acetylneuraminic acid (NANA) content of the four TBG bands isolated by preparative IEF was found to decrease from 10.2 mol NANA/mol TBG in the band at pH 4.25 to 4.8 mol NANA/mol TBG in the band at pH 4.55. No significant difference in the affinity constants of the TBG bands to T4 was found. The affinity constants for TBG ranged from 3.1 x 10(9) to 7.2 x 10(9) M-1. Sequential kinetic desialylation of pure TBG resulted in a progressive tendency toward one major band at pH 6.0. In native sera, microheterogeneity of TBG was detected after IEF on polyacrylamide gel plates by immunofixation. The typical TBG patterns shown by pure TBG were also found in normal subjects. Characteristic deviations from this pattern were found in the sera of females during estrogen therapy or pregnancy, where there was a gradual increase in density of the band at pH 4.25 and the appearance of an additional band at pH 4.15. In sera from patients with liver disease and elevated TBG levels, there was a fading of the acidic bands, whereas the more alkaline band at pH 4.55 was intensified. It is therefore proposed that microheterogeneity of TBG is caused by differences in NANA content and that variations of TBG patterns in native sera may reflect altered TBG synthesis or degradation. A genetically related microheterogeneity of TBG could not be demonstrated after examination of 800 sera, including 2 families with quantitative TBG deficiency

Breaking the Habit: The Peculiar 2016 Eruption of the Unique Recurrent Nova M31N 2008-12a

Since its discovery in 2008, the Andromeda galaxy nova M31N 2008-12a has been observed in eruption every single year. This unprecedented frequency indicates an extreme object, with a massive white dwarf and a high accretion rate, which is the most promising candidate for the single-degenerate progenitor of a Type Ia supernova known to date. The previous three eruptions of M31N 2008-12a have displayed remarkably homogeneous multiwavelength properties: (i) from a faint peak, the optical light curve declined rapidly by two magnitudes in less than two days, (ii) early spectra showed initial high velocities that slowed down significantly within days and displayed clear He/N lines throughout, and (iii) the supersoft X-ray source (SSS) phase of the nova began extremely early, six days after eruption, and only lasted for about two weeks. In contrast, the peculiar 2016 eruption was clearly different. Here we report (i) the considerable delay in the 2016 eruption date, (ii) the significantly shorter SSS phase, and (iii) the brighter optical peak magnitude (with a hitherto unobserved cusp shape). Early theoretical models suggest that these three different effects can be consistently understood as caused by a lower quiescence mass accretion rate. The corresponding higher ignition mass caused a brighter peak in the free–free emission model. The less massive accretion disk experienced greater disruption, consequently delaying the re-establishment of effective accretion. Without the early refueling, the SSS phase was shortened. Observing the next few eruptions will determine whether the properties of the 2016 outburst make it a genuine outlier in the evolution of M31N 2008-12a

Development of the adjoint of GEOS-Chem

International audienceWe present the adjoint of the global chemical transport model GEOS-Chem, focusing on the chemical and thermodynamic relationships between sulfate ? ammonium ? nitrate aerosols and their gas-phase precursors. The adjoint model is constructed from a combination of manually and automatically derived discrete adjoint algorithms and numerical solutions to continuous adjoint equations. Explicit inclusion of the processes that govern secondary formation of inorganic aerosol is shown to afford efficient calculation of model sensitivities such as the dependence of sulfate and nitrate aerosol concentrations on emissions of SOx, NOx, and NH3. The accuracy of the adjoint model is extensively verified by comparing adjoint to finite difference sensitivities, which are shown to agree within acceptable tolerances. We explore the robustness of these results, noting how discontinuities in the advection routine hinder, but do not entirely preclude, the use of such comparisons for validation of the adjoint model. The potential for inverse modeling using the adjoint of GEOS-Chem is assessed in a data assimilation framework using simulated observations, demonstrating the feasibility of exploiting gas- and aerosol-phase measurements for optimizing emission inventories of aerosol precursors

Erhebung der Grundlagen für die bessere Vermarktung von nach besonderen Richtlinien erzeugten landwirtschaftlichen Produkten aus dem Oberrheingebiet

Die vorliegende Untersuchung basiert auf einer Situationsanalyse der Produktions- und Marktstrukturen der regionalen Landwirtschaft. Neben dem Nachfrageverhalten sowie den Erwartungen und Wünschen der Verbraucher und regionalen Marktpartner der Landwirtschaft (Mikroumfeld) werden zudem übergeordnete physische, gesellschaftliche, politische und ökonomische Faktoren (Makroumfeld), die die Ausrichtung der regionalen Landwirtschaft beeinflussen, betrachtet. Die Analyse des Mikro- und Makroumfeldes setzt sich aus folgenden Projektteilen zusammen: - Analyse der landwirtschaftlichen Produktion und ihres Umfeldes, - Analyse der landwirtschaftlichen Vermarktungsstruktur und des Grades der Vernetzung der Landwirtschaft mit ihren regionalen Marktpartnern, - Analyse des Kaufverhaltens und der Präferenzen bei Verbrauchern bezüglich regional und umweltgerecht erzeugter Produkte in verschiedenen Markttypen (Biomarkt/ Naturkostgeschäft, Supermarkt sowie Verbrauchermarkt/Einkaufszentrum), - Analyse des Grossverbrauchermarktes (Einrichtungen der Gemeinschaftsverpflegung) hinsichtlich des Einsatzes von regionalen und umweltgerecht erzeugten Agrarprodukten, - Untersuchung der grenzüberschreitenden Aktivitäten der Landwirtschaft und ihrer Marktpartner in der REGIO, - Systematisierung und Bewertung der handelsrechtlichen Hemmnisse im grenzüberschreitenden Warenaustausch. Da die Bedeutung einzelner Produktgruppen, wie auch einzelner Vermarktungswege im Untersuchungsgebiet variieren, konzentriert sich die Untersuchung auf die für die drei Regionen jeweils wichtigsten Nahrungsmittelmärkte Brotgetreide, Milch, Fleisch sowie Obst und Gemüse. Zusätzlich werden produktübergreifend die Märkte für integriert sowie für ökologisch erzeugte Nahrungsmittel analysiert. Aufbauend auf die im Rahmen dieser Arbeit erstellten Umfeldanalyse sowie die Schätzung der weiteren Entwicklung der wichtigsten Einflussfaktoren der landwirtschaftlichen Erzeugung und Vermarktung, werden, mit Hilfe einer produktbezogenen Betrachtung der fördernden und hemmenden Faktoren, die Möglichkeiten für eine stärkere regionale Marktausrichtung der Landwirtschaft unter besonderer Berücksichtigung der ökologischen und integrierten Produktion beurteilt

Cutting simulation with consideration of the material hardening in the Shear Zone of AISI1045

By the use of high energy synchrotron X-ray diffraction it was possible to determine the stress state in the chip formation zone during orthogonal cutting of AISI1045. The analysis of the diffractograms showed a hardening of the material during the movement through the shear zone. For this reason nano indentation experiments on prepared chips have been carried out. With these experiments, the material hardening has been confirmed. The nano indentation experiments were reproduced by FEM simulations and it was possible to determine flow curves of the hardened material above the shear zone based on existing flow curves of AISI1045. Thus, cutting simulations have been carried out, which considered the material hardening in the shear zone. The simulation results were then compared with the results of the in-situ strain measurements