Controls on amorphous organic matter type and sulphurization in a Mississippian black shale

Paleoredox proxies (Fe speciation, trace element and δ34Spy) integrated with sedimentological and palynological observations link the distribution and type of particulate organic matter (OM) preserved to hydrocarbon source rock potential. In the Mississippian Bowland Shale Formation (Lancashire, UK), particulate OM is dominated by “heterogeneous” amorphous OM (AOM), primarily “sharp-edged, pellet-like” (AOMpel) and “heterogeneous, granular” (AOMgr) types. AOMpel is abundant in muds deposited under anoxic and moderately to highly sulphidic conditions and most likely represents the fecal minipellets of zooplankton and/or pellets of macro-zooplankters. We recognize two intervals, “A” and “B,” which exhibit Sorg/TOC > 0.04, suggesting a bulk Type II-S kerogen composition. The Interval A palynofacies is typified by pyritized AOMpel (AOMpyr) particles that contain high-relief organic spheres surrounding individual pyrite framboids, within each AOMpyr particle. These textures are interpreted as sulphurized OM local to pyrite framboids (Sorg-PF). Sorg-PF is rarely observed in Interval B, and absent in all other samples. Redox oscillation between ferruginous and euxinic conditions during early diagenesis of Interval A likely promoted S cycling in microenvironments surrounding pyrite framboids, which generated reactive S species and reactive OM required for sulphurization. Early diagenetic redox oscillation processes were apparently triggered by relative sea level fall, associated with an increased supply of FeHR from adjacent shelves into the basin. Interval B represents deposition during the late stages of basin infill and transition from anoxic to (sub)oxic bottom waters, where AOMpel is replaced by AOMgr as the dominant type of AOM. A large particle diameter at the limit of the mesh size (500 μm), sheet-like, fragmented character, and presence of candidate organic sheaths suggests AOMgr at least partially represent fragments of benthic microbial mats, probably as sulphide-oxidizers. A ternary plot of AOMpel + AOMpyr versus AOMgr versus spores + phytoclasts links the observed palynofacies to bottom and pore water redox conditions, water column productivity and proximity to fluvial (deltaic) supply of spores and phytoclasts. These variables were moderated by changing basin accommodation, driven primarily by eustatic sea level fluctuation. A sequence-stratigraphic control on AOM type and sulphurization is important for understanding the link between source rock heterogeneity and the timing of hydrocarbon generation and expulsion from this source rock

Relationship Among a Supernova, a Transition of Polarity of the Geomagnetic Field and the Pliocene-Pleistocene Boundary

After the Middle Miocene, two important climatic changes took place, consisting mainly of cooling in both hemispheres. One occurred between 7.0 and 5.4 Ma and another at the end of the Pliocene, which marked the beginning of the Pleistocene in approximately 2.58 Ma. The proposal of thispresentation is to analyze diverse forcings of these climatic changes, such as the influence of the joint occurrence of reversions of the geomagnetic field andexplosions of a supernova. These events occurred coincidentally with thecooling of Earth. Also, biological changes in those time intervals are analyzed,especially the evolution of the Hominins since the oldest hominin fossils. Thecharacteristics of the Galactic Cosmic Rays, its influence on the climate and its potential mutogenetic effect were taken into account.Briefly, according to our analysis, it seems to be evident that together withother factors, the joint occurrence of the explosion of a supernova at less than100 pc from the Earth and the weakening and/or reversion of the GeomagneticField was an important factor that promoted these two climatic and ecosystemchanges.Fil: Compagnucci, Rosa Hilda. Universidad de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Orgeira, Maria Julia. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires; ArgentinaFil: Sinito, Ana Maria. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Cappellotto, Luiggina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geociencias Básicas, Aplicadas y Ambientales de Buenos Aires; ArgentinaFil: Plastani, María Sofía. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; Argentin