S-wave and p-wave scattering in a cold gas of Na and Rb atoms

Using improved experimentally based $X{}^1\Sigma^+$ and $a{}^3\Sigma^+$ molecular potentials of NaRb, we apply the variable phase method to compute new data for low energy scattering of $^{23}$Na atoms by $^{85}$Rb atoms and $^{87}$Rb atoms. These are the scattering lengths and volumes, numbers of bound states and effective ranges, which we use to obtain the low energy spin-change cross section as functions of the system temperature and the isotope masses. From an analysis of the contributions of s-wave and p-wave scatterings to the elastic cross section we estimate temperatures below which only s-wave scattering is dominant. We compare our quantal results to data obtained from the semiclassical approximation. We supply evidence for the existence of a near zero energy p-wave bound state supported by the singlet molecular potential.Comment: The article contains additional material and data (see abstract

Continuity and boundary conditions in thermodynamics: From Carnot's efficiency to efficiencies at maximum power

[...] By the beginning of the 20th century, the principles of thermodynamics were summarized into the so-called four laws, which were, as it turns out, definitive negative answers to the doomed quests for perpetual motion machines. As a matter of fact, one result of Sadi Carnot's work was precisely that the heat-to-work conversion process is fundamentally limited; as such, it is considered as a first version of the second law of thermodynamics. Although it was derived from Carnot's unrealistic model, the upper bound on the thermodynamic conversion efficiency, known as the Carnot efficiency, became a paradigm as the next target after the failure of the perpetual motion ideal. In the 1950's, Jacques Yvon published a conference paper containing the necessary ingredients for a new class of models, and even a formula, not so different from that of Carnot's efficiency, which later would become the new efficiency reference. Yvon's first analysis [...] went fairly unnoticed for twenty years, until Frank Curzon and Boye Ahlborn published their pedagogical paper about the effect of finite heat transfer on output power limitation and their derivation of the efficiency at maximum power, now known as the Curzon-Ahlborn (CA) efficiency. The notion of finite rate explicitly introduced time in thermodynamics, and its significance cannot be overlooked as shown by the wealth of works devoted to what is now known as finite-time thermodynamics since the end of the 1970's. [...] The object of the article is thus to cover some of the milestones of thermodynamics, and show through the illustrative case of thermoelectric generators, our model heat engine, that the shift from Carnot's efficiency to efficiencies at maximum power explains itself naturally as one considers continuity and boundary conditions carefully [...]

On the efficiency at maximum cooling power

The efficiency at maximum power (EMP) of heat engines operating as generators is one corner stone of finite-time thermodynamics, the Curzon-Ahlborn efficiency $\eta_{\rm CA}$ being considered as a universal upper bound. Yet, no valid counterpart to $\eta_{\rm CA}$ has been derived for the efficiency at maximum cooling power (EMCP) for heat engines operating as refrigerators. In this Letter we analyse the reasons of the failure to obtain such a bound and we demonstrate that, despite the introduction of several optimisation criteria, the maximum cooling power condition should be considered as the genuine equivalent of maximum power condition in the finite-time thermodynamics frame. We then propose and discuss an analytic expression for the EMCP in the specific case of exoreversible refrigerators

Barnes slave boson approach to the two-site single impurity Anderson model with non-local interaction

The Barnes slave boson approach to the $U=\infty$ single impurity Anderson model extended by a non-local Coulomb interaction is revisited. We demonstrate first that the radial gauge representation facilitates the treatment of such a non-local interaction by performing the \emph{exact} evaluation of the path integrals representing the partition function, the impurity hole density and the impurity hole density autocorrelation function for a two-site cluster. The free energy is also obtained on the same footing. Next, the exact results are compared to their approximations at saddle-point level, and it is shown that the saddle point evaluation recovers the exact answer in the limit of strong non-local Coulomb interaction, while the agreement between both schemes remains satisfactory in a large parameter range.Comment: 6 pages, 2 figures, published versio

Voltage-amplified heat rectification in SIS junctions

The control of thermal fluxes -- magnitude and direction, in mesoscale and nanoscale electronic circuits can be achieved by means of heat rectification using thermal diodes in two-terminal systems. The rectification coefficient $\mathcal{R}$, given by the ratio of forward and backward heat fluxes, varies with the design of the diode and the working conditions under which the system operates. A value of $\mathcal{R}\ll 1$ or $\mathcal{R}\gg 1$ is a signature of high heat rectification performance but current solutions allowing such ranges, necessitate rather complex designs. Here, we propose a simple solution: the use of a superconductor-insulator-superconductor (SIS) junction under an applied fast oscillating (THz range) voltage as the control of the heat flow direction and magnitude can be done by tuning the initial value of the superconducting phase. Our theoretical model based on the Green functions formalism and coherent transport theory, shows a possible sharp rise of the heat rectification coefficient with values up to $\mathcal{R} \approx 500$ beyond the adiabatic regime. The influence of quantum coherent effects on heat rectification in the SIS junction is highlighted

Super-relaxation of space-time-quantized ensemble of energy loads to curtail their synchronization after demand response perturbation

Ensembles of thermostatically controlled loads (TCL) provide a significant demand response reserve for the system operator to balance power grids. However, this also results in the parasitic synchronization of individual devices within the ensemble leading to long post-demand-response oscillations in the integrated energy consumption of the ensemble. The synchronization is eventually destructed by fluctuations, thus leading to the (pre-demand response) steady state; however, this natural desynchronization, or relaxation to a statistically steady state, is too long. A resolution of this problem consists in measuring the ensemble's instantaneous consumption and using it as a feedback to stochastic switching of the ensemble's devices between on- and off- states. A simplified continuous-time model showed that carefully tuned nonlinear feedback results in a fast (super-) relaxation of the ensemble energy consumption. Since both state information and control signals are discrete, the actual TCL devices operation is space-time quantized, and this must be considered for realistic TCL ensemble modelling. Here, assuming that states are characterized by indoor temperature (quantifying comfort) and air conditioner regime (on, off), we construct a discrete model based on the probabilistic description of state transitions. We demonstrate that super-relaxation holds in such a more realistic setting, and that while it is stable against randomness in the stochastic matrix of the quantized model, it remains sensitive to the time discretization scheme. Aiming to achieve a balance between super-relaxation and customer's comfort, we analyze the dependence of super-relaxation on details of the space-time quantization, and provide a simple analytical criterion to avoid undesirable oscillations in consumption

Performance Analysis of Composite Thermoelectric Generators

Composite thermoelectric generators (CTEGs) are thermoelectric systems composed of different modules arranged under various thermal and electrical configurations (series and/or parallel). The interest for CTEGs stems from the possibility to improve device performance by optimization of configuration and working conditions. Actual modeling of CTEGs rests on a detailed understanding of the nonequilibrium thermodynamic processes at the heart of coupled transport and thermoelectric conversion. In this chapter, we provide an overview of the linear out-of-equilibrium thermodynamics of the electron gas, which serves as the working fluid in CTEGs. The force‐flux formalism yields phenomenological linear, coupled equations at the macroscopic level, which describe the behavior of CTEGs under different configurations. The relevant equivalent quantities—figure of merit, efficiency, and output power—are formulated and calculated for two different configurations. Our results show, that system performance in each of these configurations is influenced by combination of different materials and their ordering, that is, position in the arrangement structure. The primary objective of our study is to contribute new design guidelines for development of composite thermoelectric devices that combine different materials, taking advantage of the performance of each in proper temperature range and type of configuration