4,553 research outputs found

    What Matters Most? A Survey of Accomplished Middle-Level Educators\u27 Beliefs and Values about Literacy

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    Ninety teachers working in award-winning middle schools responded to a survey that explored, quantitatively and qualitatively, how they (1) defined themselves as teachers of literacy, (2) viewed multiliteracies in adolescents\u27 lives, and (3) valued these literacies in the classroom. Mean scores indicated that Basic Literacies (e.g., comprehension, word identification, fluency, writing) were rated more favorably than New Literacies (e.g., media, Internet, critical, out of school). Strong qualitative support existed for literacy instruction in all disciplines, but interpretations varied. The most positive agreement centered on every teacher being a teacher of literacy. Little support existed for developing students\u27 out-of-school literacies in schools. Such findings have strong implications for altering curricular emphases and merging teacher practice with adolescents\u27 needs and interests

    Position and Orientation Estimation through Millimeter Wave MIMO in 5G Systems

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    Millimeter wave signals and large antenna arrays are considered enabling technologies for future 5G networks. While their benefits for achieving high-data rate communications are well-known, their potential advantages for accurate positioning are largely undiscovered. We derive the Cram\'{e}r-Rao bound (CRB) on position and rotation angle estimation uncertainty from millimeter wave signals from a single transmitter, in the presence of scatterers. We also present a novel two-stage algorithm for position and rotation angle estimation that attains the CRB for average to high signal-to-noise ratio. The algorithm is based on multiple measurement vectors matching pursuit for coarse estimation, followed by a refinement stage based on the space-alternating generalized expectation maximization algorithm. We find that accurate position and rotation angle estimation is possible using signals from a single transmitter, in either line-of- sight, non-line-of-sight, or obstructed-line-of-sight conditions.Comment: The manuscript has been revised, and increased from 27 to 31 pages. Also, Fig.2, Fig. 10 and Table I are adde

    Multi-criteria assessment of ethical aspects in fresh tomato systems: Plant genomics technology innovation and food policy uses

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    Product assessment for imperceptible characteristics like environmental impact, healthfulness, naturalness, and fairness is a helpful tool in product innovation and for enhancing socially responsible conduct. In this study we apply multiple criteria analysis for the assessment of fresh tomatoes in terms of consumer perceptions regarding the above characteristics. The generated indices provide an explicit and comprehensive representation of consumer perceptions. Existing tomato products from the Dutch market are ranked alongside (reasonable conjectures of) potential products to be developed with the use of plant genomics technology. The results are interpreted to provide insights into the socially optimal use of (plant genomics) technology for fresh tomato production. Policy uses are highlighted.Ethical assessment, corporate societal responsibility, multiple criteria., Demand and Price Analysis, Research and Development/Tech Change/Emerging Technologies,

    Radiation-induced radical formation in solid state sugars: a review of recent EMR and DFT results

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    Carbohydrates are important constituents of several biological systems, including DNA, and elucidating their radiation chemistry is therefore of general importance. In particular, sugar radicals play a crucial role in radiation-induced single and double strand breaks in DNA, which can lead to mutations and, finally, cancer. Certain sugars such as sucrose (table sugar) are also promising dosimetric materials. An advanced knowledge of the radiation-induced processes in carbohydrates may therefore provide better insight into the DNA radiation chemistry and aid in establishing reliable sugar dosimetry protocols. The first step in acquiring such knowledge is identification of the radical structures. Electron Magnetic Resonance (EMR) experiments on irradiated sugar single crystals allow a very detailed characterisation of the radicals via the g-tensor and the hyperfine interactions between the unpaired electron spin and the nuclear spins in the lattice. Single crystals also offer the advantage of mimicking to some extent the compact structure of chromosomal DNA. Numerous EMR studies on single crystals of sugars and sugar derivatives have been performed the last decades, but radical identification by EMR experiments alone is often ambiguous and sometimes not feasible. The last few years, highly accurate Density Functional Theory (DFT) calculations on extended organic solid state systems have become possible. These provide a powerful tool to help clarify and interpret experimental results and enable unambiguous structural identifications that were not possible before. In this talk, an overview will be given of recently identified radiation-induced radicals in single crystals of sugars (e.g. sucrose,1,2,3 fructose4) and sugar derivatives (e.g. glucose 1-phosphate5,6). The results pertain to primary as well as intermediate and stable species and the identifications are mainly based on the agreement, both in principal values and directions, between experimentally determined and DFT calculated proton hyperfine tensors. Common structural features are highlighted and possible commonly operative formation mechanisms are discussed

    Modeling Radiation-Damage Processes in Organic Solids via DFT Calculations of EMR Parameters

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    High-energy radiation induces radicals in organic materials. When created in biological macromolecules such as DNA, these can cause harm to living organisms. This detrimental effect is also exploited for the sterilisation of e.g. foodstuffs, and radiation-induced radicals are used for dosimetry purposes. Knowledge of the structure of the radicals and their formation mechanisms is therefore of fundamental importance. In particular, radiation-induced radicals in solid sugars are studied (i) as model systems to gain insight into the precise role of the deoxyribose unit in the radiation chemistry of DNA and (ii) because of their potential as (emergency) dosimeters. X-irradiation typically gives rise to a variety of primary radicals in these systems, which then transform into stable radicals or diamagnetic species via one or more radical reactions. A prerequisite for unraveling the formation mechanisms is the identification of the different intermediate (semistable) radicals. Experimentally, solid-state sugar radicals can be characterised in detail by electron magnetic resonance (EMR) experiments. These allow determination of EMR parameters which describe the interaction of the unpaired-electron spin with its lattice environment, e.g. with (nearby) nuclear spins. Theoretical calculations of EMR parameters with DFT codes are increasingly being used to help clarify, interpret and explain experimental results. Recently we have managed, in a combined experimental and theoretical approach, to identify the structure of the major radiation-induced stable radicals in solid sucrose [1,2,3] (see Figure). We currently are investigating their formation mechanism, also via both EMR experiments and DFT modeling. A summary of the results obtained so far are presented

    Carbon-related defects in Si:C/silicon heterostructures assessed by deep-level transient spectroscopy

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    This paper reports on a Deep-Level Transient Spectroscopy (DLTS) study of the electrically active defects in similar to 100 nm Si: C stressors, formed by chemical vapor deposition on p-type Czochralski silicon substrates. In addition, the impact of a post-deposition Rapid Thermal Annealing (RTA) at 850 degrees C on the DLT-spectra is investigated. It is shown that close to the surface at least two types of hole traps are present: one kind exhibiting slow hole capture, which may have a partial extended defect nature and a second type of hole trap behaving like a point defect. RTA increases the concentration of both hole traps and, in addition, introduces a point defect at EV + 0.35 eV in the depletion region of the silicon substrate at some distance from the Si: C epi layer. This level most likely corresponds with CiOi-related centers. Finally, a negative feature is found systematically for larger reverse bias pulses, which could point to a response of trap states at the Si: C/silicon hetero-interface

    A Dark Core in Abell 520

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    The rich cluster Abell 520 (z=0.201) exhibits truly extreme and puzzling multi-wavelength characteristics. It may best be described as a "cosmic train wreck." It is a major merger showing abundant evidence for ram pressure stripping, with a clear offset in the gas distribution compared to the galaxies (as in the bullet cluster 1E 0657-558). However, the most striking feature is a massive dark core (721 h_70 M_sun/L_sun) in our weak lensing mass reconstruction. The core coincides with the central X-ray emission peak, but is largely devoid of galaxies. An unusually low mass to light ratio region lies 500 kpc to the east, and coincides with a shock feature visible in radio observations of the cluster. Although a displacement between the X-ray gas and the galaxy/dark matter distributions may be expected in a merger, a mass peak without galaxies cannot be easily explained within the current collisionless dark matter paradigm. Interestingly, the integrated gas mass fraction (~0.15), mass-to-light ratio (220 h_70 M_sun/L_sun), and position on the X-ray luminosity-temperature and mass-temperature relations are unremarkable. Thus gross properties and scaling relations are not always useful indicators of the dynamical state of clusters.Comment: 10 pages, 5 figures, accepted for publication in the Astrophysical Journal, higher resolution version at http://visav.phys.uvic.ca/~amahdav

    Spin polarization of the L-gap surface states on Au(111)

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    The electron spin polarization (ESP) of the L-gap surface states on Au(111) is investigated theoretically by means of first-principles electronic-structure and photoemission calculations. The surface states show a large spin-orbit induced in-plane ESP which is perpendicular to the in-plane wavevector, in close analogy to a two-dimensional electron gas with Rashba spin-orbit interaction. The surface corrugation leads to a small ESP component normal to the surface, being not reported so far. The surface-states ESP can be probed qualitatively and quantitatively by spin- and angle-resolved photoelectron spectroscopy, provided that the initial-state ESP is retained in the photoemission process and not obscured by spin-orbit induced polarization effects. Relativistic photoemission calculations provide detailed information on what photoemission set-ups allow to conclude from the photoelectron ESP on that of the surface states.Comment: 22 pages with 8 figure

    Direct-effect radiation chemistry of solid-state carbohydrates using EMR and DFT

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    To contribute to a mechanistic understanding of radical reaction pathways in the sugar-phosphate backbone of DNA, we are investigating primary radicals induced by X-rays, as well as their transformation into stable radicals or diamagnetic products, in crystalline sugar and sugar derivatives. Radicals are identified and characterized mainly via the hyperfine interactions of the electron spin with protons in the molecular environment. These interactions are determined experimentally with electron magnetic resonance (EMR) techniques and compared to theoretical ab initio calculations based on density functional theory in a periodic approach. Different stages of the radiation-induced processes are investigated by irradiating in situ at various temperatures and controlled annealing experiments. Here, results obtained in single crystals of the dipotassium salt of glucose 1-phosphate (K2G1P) and the disaccharides sucrose and trehalose are presented. The dominant radical in K2G1P after irradiation at 77 K exhibits a broken phospho-ester bond and is chemically identical to one of the major stable sucrose radicals, the latter all being characterized by a broken glycosidic bond. This suggests that the ester bond is radiation sensitive and that the phosphate group is not essential for the reaction pathway leading to this scission. Surprisingly, however, no evidence for glycosidic bond scission has so far been observed in trehalose. Rather, a simple H-abstraction alkyl radical is remarkably stable in this system. In all three compounds, dominant radicals are formed with one or several concerted carbonyl group formations. Extended studies are necessary to establish how and to which extent structural or geometrical factors determine the radiation chemistry, but certain general principles are starting to emerge

    Adaptive Importance Sampling for Performance Evaluation and Parameter Optimization of Communication Systems

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    We present new adaptive importance sampling techniques based on stochastic Newton recursions. Their applicability to the performance evaluation of communication systems is studied. Besides bit-error rate (BER) estimation, the techniques are used for system parameter optimization. Two system models that are analytically tractable are employed to demonstrate the validity of the techniques. As an application to situations that are analytically intractable and numerically intensive, the influence of crosstalk in a wavelength-division multiplexing (WDM) crossconnect is assessed. In order to consider a realistic system model, optimal setting of thresholds in the detector is carried out while estimating error rate performances. Resulting BER estimates indicate that the tolerable crosstalk levels are significantly higher than predicted in the literature. This finding has a strong impact on the design of WDM networks. Power penalties induced by the addition of channels can also be accurately predicted in short run-time
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