Convening a Constitutional Convention in Washington Through the Use of the Popular Initative

Using Washington as a model for discussion this comment explores the doctrines which have limited the application of the flexible principles of popular sovereignty to the problems presented in the calling of a Constitutional Convention. The author concludes: that the people of the state of Washington can call such a convention by the use of the popular initiative; that earlier notions that changes in state governmental structure could only be accomplished by strict conformity to the procedures in the existing constitution have been supplanted by the resurgence of the doctrines of popular sovereignty; and that the broad theoretical underpinnings for popular sovereignty decry the soundness of the application of any maxims of interpretation which would deny the people, acting through the initiative, the power to call a Constitutional Convention

Novel Phosphonium-Based Ionic Liquid Electrolytes for Battery Applications

In this study, we address the fundamental question of the physicochemical and electrochemical properties of phosphonium-based ionic liquids containing the counter-ions bis(trifluoromethanesul fonyl)imide ([TFSI]−) and bis(fluorosulfonyl)imide ([FSI]−). To clarify these structure–property as well as structure–activity relationships, trimethyl-based alkyl- and ether-containing phosphonium ILs were systematically synthesized, and their properties, namely density, flow characteristics, alkali metal compatibility, oxidative stability, aluminum corrosivity as well as their use in Li-ion cells were examined comprehensively. The variable moiety on the phosphonium cation exhibited a chain length of four and five, respectively. The properties were discussed as a function of the side chain, counter-ion and salt addition ([Li][TFSI] or [Li][FSI]). High stability coupled with good flow characteristics were found for the phosphonium IL [P1114][TFSI] and the mixture [P1114][TFSI] + [Li][TFSI], respectively

Novel Phosphonium-Based Ionic Liquid Electrolytes for Battery Applications

In this study, we address the fundamental question of the physicochemical and electrochemical properties of phosphonium-based ionic liquids containing the counter-ions bis(trifluoromethanesul fonyl)imide ([TFSI]) and bis(fluorosulfonyl)imide ([FSI]). To clarify these structure–property as well as structure–activity relationships, trimethyl-based alkyl- and ether-containing phosphonium ILs were systematically synthesized, and their properties, namely density, flow characteristics, alkali metal compatibility, oxidative stability, aluminum corrosivity as well as their use in Li-ion cells were examined comprehensively. The variable moiety on the phosphonium cation exhibited a chain length of four and five, respectively. The properties were discussed as a function of the side chain, counter-ion and salt addition ([Li][TFSI] or [Li][FSI]). High stability coupled with good flow characteristics were found for the phosphonium IL [P1114][TFSI] and the mixture [P1114][TFSI] + [Li][TFSI], respectively

Crossing the Brown Dwarf Desert Using Adaptive Optics: A Very Close L-Dwarf Companion to the Nearby Solar Analog HR 7672

We have found a very faint companion to the active solar analog HR 7672 (HD 190406; GJ 779; 15 Sge). Three epochs of high resolution imaging using adaptive optics (AO) at the Gemini-North and Keck II Telescopes demonstrate that HR 7672B is a common proper motion companion, with a separation of 0.79" (14 AU) and a 2.16 um flux ratio of 8.6 mags. Using follow-up K-band spectroscopy from Keck AO+NIRSPEC, we measure a spectral type of L4.5+/-1.5. This is the closest ultracool companion around a main sequence star found to date by direct imaging. We estimate the primary has an age of 1-3 Gyr. Assuming coevality, the companion is most likely substellar, with a mass of 55-78 Mjup based on theoretical models. The primary star shows a long-term radial velocity trend, and we combine the radial velocity data and AO imaging to set a firm (model-independent) lower limit of 48 Mjup. In contrast to the paucity of brown dwarf companions at <~4 AU around FGK dwarfs, HR 7672B implies that brown dwarf companions do exist at separations comparable to those of the giant planets in our own solar system. Its presence is at variance with scenarios where brown dwarfs form as ejected stellar embryos. Moreover, since HR 7672B is likely too massive to have formed in a circumstellar disk as planets are believed to, its discovery suggests that a diversity of physical processes act to populate the outer regions of exoplanetary systems.Comment: Astrophysical Journal, in pres

Structure-Property Relation of Trimethyl Ammonium Ionic Liquids for Battery Applications

Ionic liquids are attractive and safe electrolytes for diverse electrochemical applications such as advanced rechargeable batteries with high energy densities. Their properties that are beneficial for energy storage and conversion include negligible vapor-pressure, intrinsic conductivity as well as high stability. To explore the suitability of a series of ionic liquids with small ammonium cations for potential battery applications, we investigated their thermal and transport properties. We studied the influence of the symmetrical imide-type anions bis(trifluoromethanesulfonyl)imide ([TFSI]−) and bis(fluorosulfonyl)imide ([FSI]−), side chain length and functionalization, as well as lithium salt content on the properties of the electrolytes. Many of the samples are liquid at ambient temperature, but their solidification temperatures show disparate behavior. The transport properties showed clear trends: the dynamics are accelerated for samples with the [FSI]− anion, shorter side chains, ether functionalization and lower amounts of lithium salts. Detailed insight was obtained from the diffusion coefficients of the different ions in the electrolytes, which revealed the formation of aggregates of lithium cations coordinated by anions. The ionic liquid electrolytes exhibit sufficient stability in NMC/Li half-cells at elevated temperatures with small current rates without the need of additional liquid electrolytes, although Li-plating was observed. Electrolytes containing [TFSI]− anions showed superior stability compared to those with [FSI]− anions in battery tests

Ages for illustrative field stars using gyrochronology: viability, limitations and errors

We here develop an improved way of using a rotating star as a clock, set it using the Sun, and demonstrate that it keeps time well. This technique, called gyrochronology, permits the derivation of ages for solar- and late-type main sequence stars using only their rotation periods and colors. The technique is clarified and developed here, and used to derive ages for illustrative groups of nearby, late-type field stars with measured rotation periods. We first demonstrate the reality of the interface sequence, the unifying feature of the rotational observations of cluster and field stars that makes the technique possible, and extends it beyond the proposal of Skumanich by specifying the mass dependence of rotation for these stars. We delineate which stars it cannot currently be used on. We then calibrate the age dependence using the Sun. The errors are propagated to understand their dependence on color and period. Representative age errors associated with the technique are estimated at ~15% (plus possible systematic errors) for late-F, G, K, & early-M stars. Ages derived via gyrochronology for the Mt. Wilson stars are shown to be in good agreement with chromospheric ages for all but the bluest stars, and probably superior. Gyro ages are then calculated for each of the active main sequence field stars studied by Strassmeier and collaborators where other ages are not available. These are shown to be mostly younger than 1Gyr, with a median age of 365Myr. The sample of single, late-type main sequence field stars assembled by Pizzolato and collaborators is then assessed, and shown to have gyro ages ranging from under 100Myr to several Gyr, and a median age of 1.2Gyr. Finally, we demonstrate that the individual components of the three wide binaries XiBooAB, 61CygAB, & AlphaCenAB yield substantially the same gyro ages.Comment: 58 pages, 18 color figures, accepted for publication in The Astrophysical Journal; Age uncertainties slightly modified upon correcting an algebraic error in Section

On the Relation between Solar Activity and Clear-Sky Terrestrial Irradiance

The Mauna Loa Observatory record of direct-beam solar irradiance measurements for the years 1958-2010 is analysed to investigate the variation of clear-sky terrestrial insolation with solar activity over more than four solar cycles. The raw irradiance data exhibit a marked seasonal cycle, extended periods of lower irradiance due to emissions of volcanic aerosols, and a long-term decrease in atmospheric transmission independent of solar activity. After correcting for these effects, it is found that clear-sky terrestrial irradiance typically varies by about 0.2 +/- 0.1% over the course of the solar cycle, a change of the same order of magnitude as the variations of the total solar irradiance above the atmosphere. An investigation of changes in the clear-sky atmospheric transmission fails to find a significant trend with sunspot number. Hence there is no evidence for a yet unknown effect amplifying variations of clear-sky irradiance with solar activity.Comment: 16 pages, 7 figures, in press at Solar Physics; minor changes to the text to match final published versio