Tuning the Interactions in Multiresponsive Complex Coacervate-Based Underwater Adhesives

In this work, we report the systematic investigation of a multiresponsive complex coacervate-based underwater adhesive, obtained by combining polyelectrolyte domains and thermoresponsive poly(N-isopropylacrylamide) (PNIPAM) units. This material exhibits a transition from liquid to solid but, differently from most reactive glues, is completely held together by non-covalent interactions, i.e., electrostatic and hydrophobic. Because the solidification results in a kinetically trapped morphology, the final mechanical properties strongly depend on the preparation conditions and on the surrounding environment. A systematic study is performed to assess the effect of ionic strength and of PNIPAM content on the thermal, rheological and adhesive properties. This study enables the optimization of polymer composition and environmental conditions for this underwater adhesive system. The best performance with a work of adhesion of 6.5 J/m2 was found for the complex coacervates prepared at high ionic strength (0.75 M NaCl) and at an optimal PNIPAM content around 30% mol/mol. The high ionic strength enables injectability, while the hydrated PNIPAM domains provide additional dissipation, without softening the material so much that it becomes too weak to resist detaching stress. © 2019 by the authors. Licensee MDPI, Basel, Switzerland

Thermoresponsive Complex Coacervate-Based Underwater Adhesive

Sandcastle worms have developed protein-based adhesives, which they use to construct protective tubes from sand grains and shell bits. A key element in the adhesive delivery is the formation of a fluidic complex coacervate phase. After delivery, the adhesive transforms into a solid upon an external trigger. In this work, a fully synthetic in situ setting adhesive based on complex coacervation is reported by mimicking the main features of the sandcastle worm's glue. The adhesive consists of oppositely charged polyelectrolytes grafted with thermoresponsive poly(N-isopropylacrylamide) (PNIPAM) chains and starts out as a fluid complex coacervate that can be injected at room temperature. Upon increasing the temperature above the lower critical solution temperature of PNIPAM, the complex coacervate transitions into a nonflowing hydrogel while preserving its volume—the water content in the material stays constant. The adhesive functions in the presence of water and bonds to different surfaces regardless of their charge. This type of adhesive avoids many of the problems of current underwater adhesives and may be useful to bond biological tissues.</p

Creating protein-rich snack foods using binder jet 3D printing

Rising consumer demand for healthy snacks drives a rapid market growth of protein-rich foods. While numerous studies used extrusion-based 3D food printing, only few investigated binder jet 3D printing to structure food materials. In this study, we investigated the feasibility of binder jet 3D printing to create protein-rich foods using Calcium Caseinate (CaCas) powder. We successfully printed foods using powder mixtures of CaCas, starch, and medium-chain triglyceride (MCT) powder. Addition of native starch to CaCas reduced swelling upon binder addition and enhanced the printability of powder mixtures. High protein model foods with different texture properties were obtained by changing ingredient, binder composition and post-treatment by heating. Food textures obtained ranged from crumbly to springy. This study highlights new opportunities to create protein-rich foods using binder jet 3D printing technology