Growth of Nanowires and Nanowire Heterostructures by Chemical Vapor Deposition and Vapor Transport

The ongoing miniaturization, power reduction, and performance improvements of nanoscale electronics continues to fuel research and developmental efforts into new materials, synthesis techniques, and fabrication methods. Bottom-up assemblies of nanowire structures, grown catalytically and non-catalytically, have the potential to significantly contribute to complex architectures leading to new applications and higher device performance. Here, the implementation of various reaction and thermochemical models in predicting suitable nanowire growth conditions is presented using the framework of chemical vapor deposition (CVD) and vapor transport (VT) nanowire growths. Investigating novel bottom-up structures in group IV nanowires, germanium nanowire growths are performed using CVD, where the introduction of a controlled quantity of oxygen forms an oxide which selectively rejects the adsorption of precursor species on the nanowire sidewall, limiting sidewall deposition and radial growth. The catalytic nature of the oxide formation permits the oxide sheath to be switched on and off controllably, leading to the ability to produce segments that are oxide-stabilized alongside regions where sidewall deposition is allowed, resulting in large controllable radial discontinuities along the nanowire. VT is a powerful alternative to CVD and allows for new avenues for materials synthesis and nanowire growth that cannot be achieved by CVD alone. VT growth of ZnO, Se, Ge, GeO_x, and binary chalcogenides is investigated, particularly tellurium, which is an ideal candidate for VT growths due to its highly anisotropic crystalline structure which readily lends itself to the formation of high aspect-ratio nanostructures. Growth mechanism studies on tellurium guide an understanding of the energetic landscape of nanowire growths and provide effective activation energies consistent with the reaction modeling, allowing for the controlled growth of tellurium mesh nanowire networks of tailorable porosity. Additional VT growths of thermoelectrically relevant group V-VI nanowires guided by thermochemical modeling are shown to be successful in producing core-shell structures and axial transitions. Precise modeling of the growth space and the necessary modifications for catalytic and non-catalytic growths are determined for Bi_2Se_3 and Bi_2Te_3 nanowire growths, the characterization of which illustrates the importance and utility of pairing predictive thermochemical modeling with reactor design and nanowire growth.Ph.D., Materials Science and Engineering -- Drexel University, 201

Evidence for Distinct Components of the Galactic Stellar Halo from 838 RR Lyrae Stars Discovered in the LONEOS-I Survey

We present 838 ab-type RR Lyrae stars from the Lowell Observatory Near Earth Objects Survey Phase I (LONEOS-I). These objects cover 1430 deg^2 and span distances ranging from 3-30 kpc from the Galactic Center. Object selection is based on phased, photometric data with 28-50 epochs. We use this large sample to explore the bulk properties of the stellar halo, including the spatial distribution. The period-amplitude distribution of this sample shows that the majority of these RR Lyrae stars resemble Oosterhoff type I, but there is a significant fraction (26 %) which have longer periods and appear to be Oosterhoff type II. We find that the radial distributions of these two populations have significantly different profiles (rho_{OoI} ~ R^(-2.26 +- 0.07) and rho_{OoII} ~ R^(-2.88 +- 0.11). This suggests that the stellar halo was formed by at least two distinct accretion processes and supports dual-halo models.Comment: 18 pages, 28 figures, apjemulated, minor corrections and clarifications. Accepted to ApJ on Jan 21, 200

A Strategy for Finding Near Earth Objects with the SDSS Telescope

We present a detailed observational strategy for finding Near Earth Objects (NEOs) with the Sloan Digital Sky Survey (SDSS) telescope. We investigate strategies in normal, unbinned mode as well as binning the CCDs 2x2 or 3x3, which affects the sky coverage rate and the limiting apparent magnitude. We present results from 1 month, 3 year and 10 year simulations of such surveys. For each cadence and binning mode, we evaluate the possibility of achieving the Spaceguard goal of detecting 90% of 1 km NEOs (absolute magnitude H <= 18 for an albedo of 0.1). We find that an unbinned survey is most effective at detecting H <= 20 NEOs in our sample. However, a 3x3 binned survey reaches the Spaceguard Goal after only seven years of operation. As the proposed large survey telescopes (PanStarss; LSST) are at least 5-10 years from operation, an SDSS NEO survey could make a significant contribution to the detection and photometric characterization of the NEO population.Comment: Accepted by AJ -- 12 pages, 11 figure

My School? Critiquing the abstraction and quantification of education

This paper draws upon and critiques the Australian federal government's website My School as an archetypal example of the current tendency to abstract and quantify educational practice. Arguing in favour of a moral philosophical account of educational practice, the paper reveals how the My School website reduces complex educational practices to simple, supposedly objective, measures of student attainment, reflecting the broader 'audit' society/culture within which it is located. By revealing just how extensively the My School website reduces educational practices to numbers, the paper argues that we are in danger of losing sight of the 'internal' goods of Education which cannot be readily and simply codified, and that the teacher learning encouraged by the site marginalises more active and collective approaches. While having the potential to serve some beneficial diagnostic purposes, the My School website reinforces a view of teachers as passive consumers of information generated beyond their everyday practice

Simultaneous Extreme-Ultraviolet Explorer and Optical Observations of Ad Leonis: Evidence for Large Coronal Loops and the Neupert Effect in Stellar Flares

We report on the first simultaneous Extreme-Ultraviolet Explorer (EUVE) and optical observations of flares on the dMe flare star AD Leonis. The data show the following features: (1) Two flares (one large and one of moderate size) of several hours duration were observed in the EUV wavelength range; (2) Flare emission observed in the optical precedes the emission seen with EUVE; and (3) Several diminutions (DIMs) in the optical continuum were observed during the period of optical flare activity. To interpret these data, we develop a technique for deriving the coronal loop length from the observed rise and decay behavior of the EUV flare. The technique is generally applicable to existing and future coronal observations of stellar flares. We also determine the pressure, column depth, emission measure, loop cross-sectional area, and peak thermal energy during the two EUV flares, and the temperature, area coverage, and energy of the optical continuum emission. When the optical and coronal data are combined, we find convincing evidence of a stellar 'Neupert effect' which is a strong signature of chromospheric evaporation models. We then argue that the known spatial correlation of white-light emission with hard X-ray emission in solar flares, and the identification of the hard X-ray emission with nonthermal bremsstrahlung produced by accelerated electrons, provides evidence that flare heating on dMe stars is produced by the same electron precipitation mechanism that is inferred to occur on the Sun. We provide a thorough picture of the physical processes that are operative during the largest EUV flare, compare and contrast this picture with the canonical solar flare model, and conclude that the coronal loop length may be the most important factor in determining the flare rise time and energetics

Genetic diversity of Plasmodium falciparum parasite by microsatellite markers after scale-up of insecticide-treated bed nets in western Kenya

Background: An initial study of genetic diversity of Plasmodium falciparum in Asembo, western Kenya showed that the parasite maintained overall genetic stability 5 years after insecticide-treated bed net (ITN) introduction in 1997. This study investigates further the genetic diversity of P. falciparum 10 years after initial ITN introduction in the same study area and compares this with two other neighbouring areas, where ITNs were introduced in 1998 (Gem) and 2004 (Karemo). Methods: From a cross-sectional survey conducted in 2007, 235 smear-positive blood samples collected from children ≤15-year-old in the original study area and two comparison areas were genotyped employing eight neutral microsatellites. Differences in multiple infections, allele frequency, parasite genetic diversity and parasite population structure between the three areas were assessed. Further, molecular data reported previously (1996 and 2001) were compared to the 2007 results in the original study area Asembo. Results: Overall proportion of multiple infections (M A ) declined with time in the original study area Asembo (from 95.9 %-2001 to 87.7 %-2007). In the neighbouring areas, M A was lower in the site where ITNs were introduced in 1998 (Gem 83.7 %) compared to where they were introduced in 2004 (Karemo 96.7 %) in 2007. Overall mean allele count (M AC ~ 2.65) and overall unbiased heterozygosity (H e ~ 0.77) remained unchanged in 1996, 2001 and 2007 in Asembo and was the same level across the two neighbouring areas in 2007. Overall parasite population differentiation remained low over time and in the three areas at F ST < 0.04. Both pairwise and multilocus linkage disequilibrium showed limited to no significant association between alleles in Asembo (1996, 2001 and 2007) and between three areas. Conclusions: This study showed the P. falciparum high genetic diversity and parasite population resilience on samples collected 10 years apart and in different areas in western Kenya. The results highlight the need for long-term molecular monitoring after implementation and use of combined and intensive prevention and intervention measures in the region

Two Rare Magnetic Cataclysmic Variables with Extreme Cyclotron Features Identified in the Sloan Digital Sky Survey

Two newly identified magnetic cataclysmic variables discovered in the Sloan Digital Sky Survey (SDSS), SDSSJ155331.12+551614.5 and SDSSJ132411.57+032050.5, have spectra showing highly prominent, narrow, strongly polarized cyclotron humps with amplitudes that vary on orbital periods of 4.39 and 2.6 hrs, respectively. In the former, the spacing of the humps indicates the 3rd and 4th harmonics in a magnetic field of ~60 MG. The narrowness of the cyclotron features and the lack of strong emission lines imply very low temperature plasmas and very low accretion rates, so that the accreting area is heated by particle collisions rather than accretion shocks. The detection of rare systems like these exemplifies the ability of the SDSS to find the lowest accretion rate close binaries.Comment: Accepted for publication in the Astrophysical Journal, vol. 583, February 1, 2003; slight revisions and additions in response to referee's comments; 17 pages, 6 figures, AASTeX v4.

Attenuation of AMPK signaling by ROQUIN promotes T follicular helper cell formation

T follicular helper cells (Tfh) are critical for the longevity and quality of antibody-mediated protection against infection. Yet few signaling pathways have been identified to be unique solely to Tfh development. ROQUIN is a post-transcriptional repressor of T cells, acting through its ROQ domain to destabilize mRNA targets important for Th1, Th17, and Tfh biology. Here, we report that ROQUIN has a paradoxical function on Tfh differentiation mediated by its RING domain: mice with a T cell-specific deletion of the ROQUIN RING domain have unchanged Th1, Th2, Th17, and Tregs during a T-dependent response but show a profoundly defective antigen-specific Tfh compartment. ROQUIN RING signaling directly antagonized the catalytic α1 subunit of adenosine monophosphate-activated protein kinase (AMPK), a central stress-responsive regulator of cellular metabolism and mTOR signaling, which is known to facilitate T-dependent humoral immunity. We therefore unexpectedly uncover a ROQUIN–AMPK metabolic signaling nexus essential for selectively promoting Tfh responses

Influence of caregiver network support and caregiver psychopathology on child mental health need and service use in the LONGSCAN study

Using structural equation modeling, this study examined the relationship of caregiver network support on caregiver and child mental health need, as well as child mental health service use among 1075 8-year-old children participating in the LONGSCAN study. The final model showed acceptable fit (χ2 = 301.476, df = 136, p<0.001; RMSEA = 0.052; CFI = 0.95). Caregiver and child mental health needs were positively related. As predicted, caregiver network support exerted a protective effect, with greater levels of caregiver network support predictive of lower caregiver and child need. Contrary to prediction, however, caregiver network support was not directly related to child service use. Higher child need was directly related to child service use, especially among children whose caregivers had mental health problems. The findings appear to indicate that lower levels of caregiver network support may exert its impact on child service use indirectly by increasing caregiver and child need, rather than by directly increasing the likelihood of receiving services, especially for African American children