149 research outputs found
Multiple high-pressure phase transitions in BiFeO3
We investigate the high-pressure phase transitions in BiFeO3 by single
crystal and powder x-ray diffraction, as well as single crystal Raman
spectroscopy. Six phase transitions are reported in the 0-60 GPa range. At low
pressures, up to 15 GPa, 4 transitions are evidenced at 4, 5, 7 and 11 GPa. In
this range, the crystals display large unit cells and complex domain
structures, which suggests a competition between complex tilt systems and
possibly off-center cation displacements. The non polar Pnma phase remains
stable over a large pressure range between 11 and 38 GPa, where the distortion
(tilt angles) changes only little with pressure. The two high-pressure phase
transitions at 38 and 48 GPa are marked by the occurence of larger unit cells
and an increase of the distorsion away from the cubic parent perovskite cell.
We find no evidence for a cubic phase at high pressure, nor indications that
the structure tends to become cubic. The previously reported insulator-to-metal
transition at 50 GPa appears to be symmetry breaking.Comment: 11 pages, 8 figure
Is combining massive bone allograft with free vascularized fibular flap the children's reconstruction answer to lower limb defects following bone tumour resection?
SummaryPurpose of the studyBone tumours are frequent conditions in children, and their surgical resection may lead to extensive defects which reconstruction is often challenging. Indeed, local conditions do not promote bone healing, and the achieved surgical result requires to be life-lasting. Capanna suggested a reconstruction technique combining massive allograft and free vascularized fibular flap. The first one is intended to withstand mechanical stress, and the second one offers biological and vascular support to improve bone healing and prevent infections.Materiel and methodsWe report our experience with this technique when applied to the lower limb in a prospective study including seven children, with a mean follow-up of 44 months.ResultsBone healing was achieved by one single procedure in 85.7% of the cases, usually 7 months after surgery. Six out of seven patients achieved a final and long-lasting outcome, five of them following a simple surgical history. Partial weight-bearing was post-operatively allowed at about 2 months, full weight-bearing was initiated at about 5.5 months.DiscussionA low complication rate was reported despite the extent of the disease and the type of the surgical procedure. Capanna's combined reconstructive technique appears very efficient in the management of massive bone defects following tumour resection in children's lower limb.Level of evidenceLevel IV. Retrospective therapeutic study
Phase transition close to room temperature in BiFeO3 thin films
BiFeO3 (BFO) multiferroic oxide has a complex phase diagram that can be
mapped by appropriately substrate-induced strain in epitaxial films. By using
Raman spectroscopy, we conclusively show that films of the so-called
supertetragonal T-BFO phase, stabilized under compressive strain, displays a
reversible temperature-induced phase transition at about 100\circ, thus close
to room temperature.Comment: accepted in J. Phys.: Condens. Matter (Fast Track Communication
Effect of high pressure on multiferroic BiFeO3
We report experimental evidence for pressure instabilities in the model
multiferroic BiFeO3 and namely reveal two structural phase transitions around 3
GPa and 10 GPa by using diffraction and far-infrared spectroscopy at a
synchrotron source. The intermediate phase from 3 to 9 GPa crystallizes in a
monoclinic space group, with octahedra tilts and small cation displacements.
When the pressure is further increased the cation displacements (and thus the
polar character) of BiFeO3 is suppressed above 10 GPa. The above 10 GPa
observed non-polar orthorhombic Pnma structure is in agreement with recent
theoretical ab-initio prediction, while the intermediate monoclinic phase was
not predicted theoretically.Comment: new version, accepted for publication in Phys. Rev.
Infrared and THz studies of polar phonons and improper magnetodielectric effect in multiferroic BFO3 ceramics
BFO3 ceramics were investigated by means of infrared reflectivity and time
domain THz transmission spectroscopy at temperatures 20 - 950 K, and the
magnetodielectric effect was studied at 10 - 300 K, with the magnetic field up
to 9 T. Below 175 K, the sum of polar phonon contributions into the
permittivity corresponds to the value of measured permittivity below 1 MHz. At
higher temperatures, a giant low-frequency permittivity was observed, obviously
due to the enhanced conductivity and possible Maxwell-Wagner contribution.
Above 200 K the observed magnetodielectric effect is caused essentially through
the combination of magnetoresistance and the Maxwell-Wagner effect, as recently
predicted by Catalan (Appl. Phys. Lett. 88, 102902 (2006)). Since the
magnetodielectric effect does not occur due to a coupling of polarization and
magnetization as expected in magnetoferroelectrics, we call it improper
magnetodielectric effect. Below 175 K the magnetodielectric effect is by
several orders of magnitude lower due to the decreased conductivity. Several
phonons exhibit gradual softening with increasing temperature, which explains
the previously observed high-frequency permittivity increase on heating. The
observed non-complete phonon softening seems to be the consequence of the
first-order nature of the ferroelectric transition.Comment: subm. to PRB. revised version according to referees' report
DNA immunisation. New histochemical and morphometric data.
Splenic germinal center reactions were measured during primary response to a plasmidic DNA intramuscular injection. Cardiotoxin-pretreated Balb/c mice were immunized with DNA plasmids encodmg or not the SAG1 protein, a membrane antigen of Toxoplasma gondii. Specific anti-SAG1 antibodies were detected on days 16 and 36 after injection of coding plasmids. The results of ELISAs showed that the SAG1-specific antibodies are of the IgG2a class. Morphometric analyses were done on serial immunostained cryosections of spleen and draining or non-draining lymph nodes. This new approach made it possible to evaluate the chronological changes induced by DNA immunisation in the germinal centres (in number and in size). Significant increases in the number of germinal centres were measured in the spleen and only in draining lymph nodes after plasmid injection, the measured changes of the germinal centers appeared to result from the adjuvant stimulatory effect of the plasmidic DNA since both the coding and the noncoding plasmid DNA induced them. No measurable changes were recorded in the T-dependent zone of lymph organs
Voxelization of Free-Form Solids Represented by Catmull-Clark Subdivision Surfaces
www.cs.uky.edu/∼cheng Abstract. A voxelization technique and its applications for objects with arbitrary topology are presented. It converts a free-form object from its continuous geometric representation into a set of voxels that best approximates the geometry of the object. Unlike traditional 3D scan-conversion based methods, our voxelization method is performed by recursively subdividing the 2D parameter space and sampling 3D points from selected 2D parameter space points. Moreover, our voxelization of 3D closed objects is guaranteed to be leak-free when a 3D flooding operation is performed. This is ensured by proving that our voxelization results satisfy the properties of separability, accuracy and minimality.
Magnetoelectric ordering of BiFeO3 from the perspective of crystal chemistry
In this paper we examine the role of crystal chemistry factors in creating
conditions for formation of magnetoelectric ordering in BiFeO3. It is generally
accepted that the main reason of the ferroelectric distortion in BiFeO3 is
concerned with a stereochemical activity of the Bi lone pair. However, the lone
pair is stereochemically active in the paraelectric orthorhombic beta-phase as
well. We demonstrate that a crucial role in emerging of phase transitions of
the metal-insulator, paraelectric-ferroelectric and magnetic disorder-order
types belongs to the change of the degree of the lone pair stereochemical
activity - its consecutive increase with the temperature decrease. Using the
structural data, we calculated the sign and strength of magnetic couplings in
BiFeO3 in the range from 945 C down to 25 C and found the couplings, which
undergo the antiferromagnetic-ferromagnetic transition with the temperature
decrease and give rise to the antiferromagnetic ordering and its delay in
regard to temperature, as compared to the ferroelectric ordering. We discuss
the reasons of emerging of the spatially modulated spin structure and its
suppression by doping with La3+.Comment: 18 pages, 5 figures, 3 table
Quantitative EEG in type 1 diabetic adults with childhood exposure to severe hypoglycaemia: a 16 year follow-up study
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