Simultaneous recovery of metals and degradation of organic species: Copper and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T)

In mixed wastewater streams, the presence of metal ions can retard the destruction of organic contaminants and the efficiency of recovery of the metal is reduced by the presence of organic species. The reduction in the efficiency of these methods is due to the formation of complexes between the organic species and the metal ions in solution. Results are presented for copper - 2,4,5-T system in which both effects occur. A photolytic cell alone can achieve the complete degradation of 2,4,5-T, in the presence of TiO2 or H2O2, at pH 3.5. The addition of Cu(II) ions, however, retard the degradation of 2,4,5-T and complete mineralization of 2,4,5-T was not achieved and the system also leaves Cu(II) ions in solution. An electrolytic cell alone can be used to recover copper in pH range 1.5 – 4.5 but is not capable of achieving complete disappearance of 2,4,5-T by anodic oxidation. A combined photolytic – electrolytic system is capable of achieving simultaneous destruction of 2,4,5-T and recovery of copper from mixed wastewater streams at pH 3.5. The percentage destruction of 2,4,5-T and the recovery of copper can be increased further by using a combined photolytic and an activated carbon concentrator cell system. This system can achieve the simultaneous recovery of copper and the degradation of 2,4,5-T without the use of an additional oxidants or catalysts.Pakistan High Commissio

An overview of factors responsible for geographic distribution pattern of ixodid ticks in the Sudan

Tick fauna in the Sudan comprises over 70 species prevalent in diverse ecological zones. Among these are the most economically important ticks in Africa, namely Rhipicephalus appendiculatus, Hyalomma anatolicum, Amblyomma variegatum, Amblyomma lepidum, Rhipicephalus (Boophilus) decoloratus and Rhipicephalus (Boophilus) annulatus. Several factors determine the dynamic changes of tick distribution in the Sudan. These are animal movement either for trade, nomadism, or migration due to civil unrest etc., habitat modification such as deforestation, large-scale mechanized cultivation and urbanization; drought and desertification, and global climate change. The accelerated change in tick distribution results in outbreaks of several tick-borne diseases. Examples of these are East Coast fever, tropical theileriosis, malignant ovine theileriosis, heartwater and babesiosis by Babesia bovis. Emergence of these diseases in districts believed to be free is alarming and has adverse effects in the process of animal resources development. This communication discusses distribution patterns of the economically important livestock ticks in the Sudan and identifies new zones where ticks have established and the possible factors determining such distribution.Keywords: Distribution, Factors, Livestock, Sudan, Ticks

Nutritional and Antinutritional Composition of Sclerocarya birrea Fruit Juice

The juice of Sclerocarya birrea fruit was evaluated for its nutritional and antinutritional compositions. The results show that the total solid, ash, crude protein, crude lipid, available carbohydrate and energy value are 12.32g/100cm3, 5.05%, 3.31%, 1.30%, 90.35% and 386.34kcal/100g dry weight respectively. The results of minerals content indicate that, the juice is a good source of both macro and micro elements with calcium as predominant. The 100 cm3 juice contained reasonable amount of pectin (2.10g), vitamin C (0.49g), glucose (0.21g) and sucrose (0.76g). Concentrations of hydrocyanic acid, nitrate, oxalate, and phytate are lower than the reference toxic standard level. The juice of the plant could have a potential nutritional uses

post-Adaptation vulnerability of cereals to rainfall and temperature variability in the federal capital territory of Nigeria

This study assessed the vulnerability of cereals yield to climate change using an integrated and multi-scale quantitative approach. The objectives of this study include determining the level of climate variability, assessment of cereals yield sensitivity index, determining climate exposure index, determining adaptive capacity of farmers, assessment of the post adaptation vulnerability of cereals yield to climate change. Socioeconomic data were obtained through administration of questionnaires. Thirty years data of temperature and rainfall as well as fifteen years data of annual cereals yield were used. Mean and standard deviation, standardized coefficient of skewness (Z1) and kurtosis (Z2), simple linear regression and time series statistics analysis were used in this study for the analysis of data. Finding depicts that the exposure index of rainfall is low but high for temperature. Cereals sensitivity index/degree of crop yield failure is more from 2000 – 2010 and significant difference was observed in sensitivity index for all the cereals. Adaptive capacity of farmers to climate change is high in Bwari and AMAC but low in Gwagwalada, Kuje, Abaji and Kwali. Post adaptation vulnerability of maize, rice and millet yield to rainfall and temperature is low in AMAC and Bwari but high in Gwagwalada, Kwali, Abaji and Kuje. Post adaptation vulnerability of sorghum in relation to rainfall is low in all the area councils in the FCT except Abaji. In relation to temperature, vulnerability of sorghum is high in Abaji and Kuje but low in AMAC, Gwagwalada, Kwali and Bwari. It was recommended that there is need to place climate change within the top priority of developmental context, and provision and infrastructure as well as reliable agricultural extension service.  Key Words: Cereals, Post-Adaptation, Vulnerability, Rainfall, Temperature, Variability, FC

Acute and subchronic toxicity studies of kernel extract of Sclerocarya birrea in rats

Sclerocarya birrea fruits are widely eaten in developing countries especially in rural areas and serves as nutrients supplements. However, they also contain phyto-toxin which may affect the normal functioning of the body. Acute toxicity was performed by a single oral administration at a dose of 3000 mg/kg body weight. Sub chronic evaluation was done by oral feeding of the rats with the seed kernel extract daily at doses of 1000, 2000, 3000 and 4000 mg/kg body weight for 28 days. The results of acute toxicity showed no mortality and general behavior changes. The lethal dosage (LD50) was greater than 3000 mg/kg body weight. Rats fed with 1000 and 2000 mg/kg body weight of the extract showed increased body weights throughout the period of treatment but not significantly (p<0.05) different from the control group. Significant (p<0.05) reduction in the body weights were noticed in those administered with 3000 and 4000 mg/kg body weightat the 4th and all the weeks respectively. Significant (p<0.05) increasedin serum total protein, albumin, bilirubin, transaminases, creatinine,urea, uric acid and electrolytes were observed in rats fed with 3000 to4000 mg/kg body weight of the extract, suggesting liver and kidneytoxicity. Therefore, the seed kernel extract of S. birrea may be relatively toxic at doses of 3000 and 4000 mg/kg body weight

Gastrointestinal Basidiobolomycosis Mimicking Colon Cancer in a Sudanese Patient

Basidiobolomycosisis a rare disease caused by the fungus Basidiobolus ranarum. The incidence Rate of Gastrointestinal Basidiobolomycosis is approximately 1 in 45,333,334 or 0.00% in every 5 people in USA), member of the class Zygomycetes found worldwide (1).Basidiobolomycosis is usually a subcutaneous infection but rarely gastrointestinal1. This fungus is found mainly in the soil and on decaying vegetations2. It has been isolated from the banks of tropical rivers in West Africa, and has also been found in association with some insects2. The fungus is known to be present in the gastrointestinal tracts of reptiles, amphibians, and some bat species3. Definitive diagnosis requires culture and serological testing may be helpful. The fungal morphology and the Splendore-Hoeppli phenomenon are characteristic histological features. Basidiobolomycosis is treated with surgical resection and itracanzole 200mg BD for three months or Amphotericin B 5mg /kg iv/24 hrs4.Keywords: Zygomycetes, vegetations, subcutaneous infection.

Influence of catalyst (Yeast) on the Biomethanization of Selected Organic Waste Materials

Yeast catalyzed the rate of biomethanization of waste materials and rate at which it alter the reaction rate has been determined. It was observed that addition of yeast improved the quality and quantity of biogas generated and also fastened the acid and methane forming stages during biomethanization. The volumes of biogas in the catalyzed process was found to be 6550 cm3 for cow dung, 5640 cm3 for millet husk, 3240 cm3 for rice husk ,1000 cm3 for saw dust and 800 cm3 for the paper waste, as against 5430 cm3, 5230 cm3, 2110 cm3, 950 cm3 and 590 cm3 respectively for the uncatalyzed biomethanization process

Nutritional value OF Bottle Gourd (Lagenaria siceraria) Seeds

Whole seeds, dehulled seeds and seed coats of bottle gourd seed (Lagenaria siceraria) were analysed for their proximate, amino acids and mineral compositions. The results of the analysis showed that, whole seed has highest content of moisture (17.5  0.21%) and ash (5.80  0.83%) while dehulled had highest amount of crude protein (35.0  0.48%) and crude lipid (39.22  1.48%) and seed coat contain highest amount of crude fiber (59.05  0.98%). The study showed a profile of seventeen amino acids (isoleucine, leucine, lysine, methionine, cysteine, phenylalanine, tyrosine, threonine, valine, alanine, arginine, aspartic acid, glutamic acid, glycine, histidine, proline and serine) with glutamic acid, leucine and aspartic acid being the predominant amino acid. The percentages (%) of essential and non-essential amino acids in dehulled seeds, whole seeds and seed coats were 44 vs 56, 41 vs 59 and 51 vs 49 respectively. The dehulled seeds contained essential amino acids that were found to be higher than WHO/FAO/UNU requirement. In whole seeds, threonine, lysine and lysine were found to be the most limiting amino acids. Seed coats were deficient in all the essential amino acids except for valine. Generally, the mineral composition of the seed was found to be relatively high, indicating the seed to be a good source of dietary elements, except for Ca, Zn, Co and Cr where very low values were obtained. Finally, the results of the study indicate that, bottle gourd seed is a potential source of protein, lipid, micro and macronutrients, and if properly utilised, could contribute in solving the problem of malnutrition and also serve as raw material for agro-based industries Keywords: Bottle gourd seeds, seed coat, proximate analysis, minerals and Amino acid composition.Global Journal of Pure and Applied Sciences Vol. 14 (3) 2008: pp. 301-30

Comparative Study of Biogas Production from Locally Sourced Substrate Materials

Comparative study of biogas production from Cow dung (CD), Millet husk (MH), Rice husk (RH), Saw dust (SD) and Paper waste (PW) was conducted. The biogas production potentials for the substrates were of the order: Cow dung (8772.50cm3) > Millet husk (6680 cm3) > Rice husk (1386.25 cm3) > Saw dust (973.75 cm3) > Paper waste (476.25 cm3). Physico - chemical analysis revealed decreasing pH in the spent slurry indicating acidification of the content. The ash content is higher in the spent slurry ranging from 16 – 24% for the raw substrate and between 18 and 29% for the spent slurry. Kinetic studies show the slurry concentration have a direct relationship to the volume of biogas produced from all the substrates. There was strong  correlation between slurry concentration and the volume of biogas generated