596 research outputs found

    A direct numerical simulation study of vorticity transformation in weakly turbulent premixed flames

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    Database obtained earlier in 3D Direct Numerical Simulations (DNS) of statistically stationary, 1D, planar turbulent flames characterized by three different density ratios σ is processed in order to investigate vorticity transformation in premixed combustion under conditions of moderately weak turbulence (rms turbulent velocity and laminar flame speed are roughly equal to one another). In cases H and M characterized by σ = 7.53 and 5.0, respectively, anisotropic generation of vorticity within the flame brush is reported. In order to study physical mechanisms that control this phenomenon, various terms in vorticity and enstrophy balance equations are analyzed, with both mean terms and terms conditioned on a particular value c of the combustion progress variable being addressed. Results indicate an important role played by baroclinic torque and dilatation in transformation of average vorticity and enstrophy within both flamelets and flame brush. Besides these widely recognized physical mechanisms, two other effects are documented. First, viscous stresses redistribute enstrophy within flamelets, but play a minor role in the balance of the mean enstrophy Ω ¯ ¯ ¯ within turbulent flame brush. Second, negative correlation u ′ ⋅∇Ω ′ ¯ ¯ ¯ ¯ ¯ ¯ ¯ ¯ ¯ ¯ ¯ ¯ between fluctuations in velocity u and enstrophy gradient contributes substantially to an increase in the mean Ω ¯ ¯ ¯ within turbulent flame brush. This negative correlation is mainly controlled by the positive correlation between fluctuations in the enstrophy and dilatation and, therefore, dilatation fluctuations substantially reduce the damping effect of the mean dilatation on the vorticity and enstrophy fields. In case L characterized by σ = 2.5, these effects are weakly pronounced and Ω ¯ ¯ ¯ is reduced mainly due to viscosity. Under conditions of the present DNS, vortex stretching plays a minor role in the balance of vorticity and enstrophy within turbulent flame brush in all three cases

    Three reversible states controlled on a gold monoatomic contact by the electrochemical potential

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    Conductance of an Au mono atomic contact was investigated under the electrochemical potential control. The Au contact showed three different behaviors depending on the potential: 1 G0G_{0} (G0G_{0} = 2e2/h2e^{2}/h), 0.5 G0G_{0} and not-well defined values below 1 G0G_{0} were shown when the potential of the contact was kept at -0.6 V (double layer potential), -1.0 V (hydrogen evolution potential), and 0.8 V (oxide formation potential) versus Ag/AgCl in 0.1 M Na2_{2}SO4_{4} solution, respectively. These three reversible states and their respective conductances could be fully controlled by the electrochemical potential. These changes in the conductance values are discussed based on the proposed structure models of hydrogen adsorbed and oxygen incorporated on an Au mono atomic contact.Comment: 8 pages, 4 figures, to be appeared in Physical Review

    Saccharification of lignocellulosic biomass under mild condition using ionic liquid

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    Biomass is expected to be an alternative resource to fossil resources. In this study, the development of a biomass conversion method into the valuable chemical, reducing sugar, was examined. For the conversion, thermochemical technology was focused on for its advantage of short reaction time, and ionic liquid was focused on as a reagent to overcome the unpreferable disadvantage of thermochemical technology, which is the low selectivity. Cedar and crystalline cellulose were pretreated with ionic liquid for reforming into desirable precursors of reducing sugar. Especially when they were pretreated by 1-ethyl-3-methylimidazolium methylphosphonate at 150°C for 1 h, the pretreatment worked effectively by decreasing the crystallinity of samples. Pretreated cedar and crystalline cellulose were converted into reducing sugar under hydrothermal conditions, respectively, by 39 C-% and 90 C-%. Recovery of ionic liquid was also examined. When cedar was used as a material, lignin was dissolved into ionic liquid through pretreatment, which was undesirable because of difficult separation thereof. When crystalline cellulose was used as a material, 98.3% of the ionic liquid was recovered after the conversion with the highest yield of reducing sugar (90 C-%)

    Application of conditioned structure functions to exploring influence of premixed combustion on two-point turbulence statistics

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    International audienceIn order to investigate the influence of combustion-induced thermal expansion on turbulent flow within a premixed flame brush, a new method is introduced. The method consists in analyzing structure functions of the velocity field, which characterize velocity difference in two points A and B, with the structure functions being conditioned to various events; (i) unburned reactants in both points, (ii) combustion products in both points, (iii) intermediate states of the mixture in both points, (iv) the reactants in one point and the products in another point, (v) the reactants in one point and an intermediate state in another point, and (vi) the products in one point and an intermediate state in another point. Such structure functions and relevant probabilities are defined in the paper. Subsequently, the structure functions and the probabilities are extracted from Direct Numerical Simulation (DNS) data obtained from two statistically 1D, planar, fully-developed, weakly turbulent, premixed flames characterized by two significantly different (7.53 and 2.50) density ratios, with all other things being approximately equal. Obtained results indicate that (i) the conditioned structure functions differ significantly from the mean structure functions and (ii) the newly introduced approach could convey information important for understanding fundamentals of flame-turbulence interaction and finding issues that require further research. In particular, application of the approach to the aforementioned DNS data shows that the combustion-induced thermal expansion substantially affects small-scale two-point velocity statistics in the incoming constant-density turbulent flow of unburned reactants within a premixed flame brush

    A DNS study of the physical mechanisms associated with density ratio influence on turbulent burning velocity in premixed flames

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    International audienceData obtained in 3D direct numerical simulations of statistically planar, 1D weakly turbulent flames characterized by different density ratios σ are analyzed in order to study the influence of thermal expansion on flame surface area and turbulent burning rate. Obtained results show that, on the one hand, pressure gradient induced within the flame brush due to heat release in flamelets significantly accelerates unburned gas that deeply intrudes into combustion products in a form of an unburned mixture finger, thus, causing large-scale oscillations of the turbulent burning rate and flame brush thickness. Under conditions of the present simulations, contribution of this mechanism to creation of flame surface area is substantial and is increased by the density ratio, thus, implying an increase in the burning rate by σ. On the other hand, the total flame surface areas simulated at σ = 7.53 and 2.5 are approximately equal to one another. Apparent inconsistency between these results implies existence of another thermal expansion effect that reduces the influence of the density ratio on the flame surface area and burning rate. Investigation of the issue shows that the axial flow acceleration by the combustion-induced pressure gradient not only straightforwardly creates flame surface area by pushing a finger tip into products, but also mitigates wrinkling of the flame surface (the side surface of the finger) by turbulent eddies. The latter effect is attributed to a high-speed (at σ = 7.53) axial 1 flow (a jet) of unburned gas, which is induced by the axial pressure gradient within the flame brush (and the finger). This axial flow acceleration reduces a residence time of a turbulent eddy in an unburned zone of the flame brush (e.g. within the finger). Therefore, the capability of the eddy for wrinkling the flamelet surface (e.g. the side finger surface) is weakened due to a shorter residence time
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