Effects on Amorphous Silicon Photovoltaic Performance from High-temperature Annealing Pulses in Photovoltaic Thermal Hybrid Devices

There is a renewed interest in photovoltaic solar thermal (PVT) hybrid systems, which harvest solar energy for heat and electricity. Typically, a main focus of a PVT system is to cool the photovoltaic (PV) cells to improve the electrical performance, however, this causes the thermal component to under-perform compared to a solar thermal collector. The low temperature coefficients of amorphous silicon (a-Si:H) allow for the PV cells to be operated at higher temperatures and are a potential candidate for a more symbiotic PVT system. The fundamental challenge of a-Si:H PV is light-induced degradation known as the Staebler-Wronski effect (SWE). Fortunately, SWE is reversible and the a-Si:H PV efficiency can be returned to its initial state if the cell is annealed. Thus an opportunity exists to deposit a-Si:H directly on the solar thermal absorber plate where the cells could reach the high temperatures required for annealing. In this study, this opportunity is explored experimentally. First a-Si:H PV cells were annealed for 1 hour at 100\degreeC on a 12 hour cycle and for the remaining time the cells were degraded at 50\degreeC in order to simulate stagnation of a PVT system for 1 hour once a day. It was found that, when comparing the cells after stabilization at normal 50\degreeC degradation, this annealing sequence resulted in a 10.6% energy gain when compared to a cell that was only degraded at 50\degreeC

Spectral determinants and zeta functions of Schr\"odinger operators on metric graphs

A derivation of the spectral determinant of the Schr\"odinger operator on a metric graph is presented where the local matching conditions at the vertices are of the general form classified according to the scheme of Kostrykin and Schrader. To formulate the spectral determinant we first derive the spectral zeta function of the Schr\"odinger operator using an appropriate secular equation. The result obtained for the spectral determinant is along the lines of the recent conjecture.Comment: 16 pages, 2 figure

A new quantum fluid at high magnetic fields in the marginal charge-density-wave system α\alpha-(BEDT-TTF)2M_2MHg(SCN)4_4 (where M=M=~K and Rb)

Single crystals of the organic charge-transfer salts $\alpha$-(BEDT-TTF)$_2M$Hg(SCN)$_4$ have been studied using Hall-potential measurements ($M=$K) and magnetization experiments ($M$ = K, Rb). The data show that two types of screening currents occur within the high-field, low-temperature CDW$_x$ phases of these salts in response to time-dependent magnetic fields. The first, which gives rise to the induced Hall potential, is a free current (${\bf j}_{\rm free}$), present at the surface of the sample. The time constant for the decay of these currents is much longer than that expected from the sample resistivity. The second component of the current appears to be magnetic (${\bf j}_{\rm mag}$), in that it is a microscopic, quasi-orbital effect; it is evenly distributed within the bulk of the sample upon saturation. To explain these data, we propose a simple model invoking a new type of quantum fluid comprising a CDW coexisting with a two-dimensional Fermi-surface pocket which describes the two types of current. The model and data are able to account for the body of previous experimental data which had generated apparently contradictory interpretations in terms of the quantum Hall effect or superconductivity.Comment: 13 pages, 11 figure

A Graphical Language for Proof Strategies

Complex automated proof strategies are often difficult to extract, visualise, modify, and debug. Traditional tactic languages, often based on stack-based goal propagation, make it easy to write proofs that obscure the flow of goals between tactics and are fragile to minor changes in input, proof structure or changes to tactics themselves. Here, we address this by introducing a graphical language called PSGraph for writing proof strategies. Strategies are constructed visually by "wiring together" collections of tactics and evaluated by propagating goal nodes through the diagram via graph rewriting. Tactic nodes can have many output wires, and use a filtering procedure based on goal-types (predicates describing the features of a goal) to decide where best to send newly-generated sub-goals. In addition to making the flow of goal information explicit, the graphical language can fulfil the role of many tacticals using visual idioms like branching, merging, and feedback loops. We argue that this language enables development of more robust proof strategies and provide several examples, along with a prototype implementation in Isabelle

Validation of a model of regulation in the tryptophan operon against multiple experiment data using global optimisation

This paper is concerned with validating a mathematical model of regulation in the tryptophan operon using global optimization. Although a number of models for this biochemical network are proposed, in many cases only qualitative agreement between the model output and experimental data was demonstrated, since very little information is currently available to guide the selection of parameter values for the models. This paper presents a model validating method using both multiple experimental data and global optimization

Non-linear effect of uniaxial pressure on superconductivity in CeCoIn5

We study single-crystal CeCoIn5 with uniaxial pressure up to 3.97 kbar applied along the c-axis. We find a non-linear dependence of the superconducting transition temperature Tc on pressure, with a maximum close to 2 kbar. The transition also broadens significantly as pressure increases. We discuss the temperature dependence in terms of the general trend that Tc decreases in anisotropic heavy-fermion compounds as they move towards three-dimensional behavior.Comment: 6 pages, 4 figure

Gamma-Ray Burst Spectral Features: Interpretation as X-ray Emission From A Photoionized Plasma

Numerous reports have been made of features, either in emission or absorption, in the 10 - 1000 keV spectra of some gamma-ray bursts. Originally interpreted in the context of Galactic neutron star models as cyclotron line emission and $e^+ - e^-$ annihilation features, the recent demonstration that the majority of GRBs lie at cosmological distances make these explanations unlikely. In this letter, we adopt a relativistic fireball model for cosmological GRBs in which dense, metal rich blobs or filaments of plasma are entrained in the relativistic outflow. In the context of this model, we investigate the conditions under which broadband features, similar to those detected, can be observed. We find a limited region of parameter space capable of reproducing the observed GRB spectra. Finally, we discuss possible constraints further high-energy spectral observations could place on fireball model parameters.Comment: Accepted for publication in Astrophysical Journal Letters Four pages, 2 figure

Synthesis of polyethers of hexafluorobenzene and hexafluoropentanediol

Two new polyethers, poly /hexafluoropentamethylene tetrafluoro-p-phenylene ether/ and a completely hydroxyl-terminated polyether, is prepared by reactions of hexafluorobenzene with hexafluoropentanediol. The polyethers can be prepared as low molecular weight oils, as intermediate molecular weight waxes, or as high molecular weight elastomers