Localized hydrogels based on cellulose nanofibers and wood pulp for rapid removal of methylene blue

Access to clean water has become increasingly difficult, motivating the need for materials that can efficiently remove pollutants. Hydrogels have been explored for remediation, but they often require long times to reach high levels of adsorption. To overcome this limitation, we developed a rapid, locally formed hydrogel that adsorbs dye during gelation. These hydrogels are derived from cellulose—a renewable, nontoxic, and biodegradable resource. More specifically, we found that sulfated cellulose nanofibers or sulfated wood pulps, when mixed with a water‐soluble, cationic cellulose derivative, efficiently remove methylene blue (a cationic dye) within seconds. The maximum adsorption capacity was found to be 340 ± 40 mg methylene blue/g cellulose. As such, these localized hydrogels (and structural analogues) may be useful for remediating other pollutants.Access to clean water has become increasingly difficult, motivating the need for materials that can efficiently remove pollutants. In this work, locally formed hydrogels made from mixing anionic and cationic cellulose derivatives are developed, which rapidly adsorb cationic dye during the gel formation process. A maximum adsorption efficiency of 340 ± 40mg methylene blue/g cellulose was observed, rivaling comparable cellulose‐based gels reported. These localized hydrogels (and structural analogues) may be useful for remediating other pollutants.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/163385/2/pola29833.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/163385/1/pola29833_am.pd

Mean-Field and Anomalous Behavior on a Small-World Network

We use scaling results to identify the crossover to mean-field behavior of equilibrium statistical mechanics models on a variant of the small world network. The results are generalizable to a wide-range of equilibrium systems. Anomalous scaling is found in the width of the mean-field region, as well as in the mean-field amplitudes. Finally, we consider non-equilibrium processes.Comment: 4 pages, 0 figures; reference adde

Quantum critical behavior in disordered itinerant ferromagnets: Logarithmic corrections to scaling

The quantum critical behavior of disordered itinerant ferromagnets is determined exactly by solving a recently developed effective field theory. It is shown that there are logarithmic corrections to a previous calculation of the critical behavior, and that the exact critical behavior coincides with that found earlier for a phase transition of undetermined nature in disordered interacting electron systems. This confirms a previous suggestion that the unspecified transition should be identified with the ferromagnetic transition. The behavior of the conductivity, the tunneling density of states, and the phase and quasiparticle relaxation rates across the ferromagnetic transition is also calculated.Comment: 15pp., REVTeX, 8 eps figs, final version as publishe

Generating Function for Particle-Number Probability Distribution in Directed Percolation

We derive a generic expression for the generating function (GF) of the particle-number probability distribution (PNPD) for a simple reaction diffusion model that belongs to the directed percolation universality class. Starting with a single particle on a lattice, we show that the GF of the PNPD can be written as an infinite series of cumulants taken at zero momentum. This series can be summed up into a complete form at the level of a mean-field approximation. Using the renormalization group techniques, we determine logarithmic corrections for the GF at the upper critical dimension. We also find the critical scaling form for the PNPD and check its universality numerically in one dimension. The critical scaling function is found to be universal up to two non-universal metric factors.Comment: (v1,2) 8 pages, 5 figures; one-loop calculation corrected in response to criticism received from Hans-Karl Janssen, (v3) content as publishe

A metal-insulator transition as a quantum glass problem

We discuss a recent mapping of the Anderson-Mott metal-insulator transition onto a random field magnet problem. The most important new idea introduced is to describe the metal-insulator transition in terms of an order parameter expansion rather than in terms of soft modes via a nonlinear sigma model. For spatial dimensions d>6 a mean field theory gives the exact critical exponents. In an epsilon expansion about d=6 the critical exponents are identical to those for a random field Ising model. Dangerous irrelevant quantum fluctuations modify Wegner's scaling law relating the conductivity exponent to the correlation or localization length exponent. This invalidates the bound s>2/3 for the conductivity exponent s in d=3. We also argue that activated scaling might be relevant for describing the AMT in three-dimensional systems.Comment: 10 pp., REvTeX, 1 eps fig., Sitges Conference Proceedings, final version as publishe

Critical Exponents for Diluted Resistor Networks

An approach by Stephen is used to investigate the critical properties of randomly diluted resistor networks near the percolation threshold by means of renormalized field theory. We reformulate an existing field theory by Harris and Lubensky. By a decomposition of the principal Feynman diagrams we obtain a type of diagrams which again can be interpreted as resistor networks. This new interpretation provides for an alternative way of evaluating the Feynman diagrams for random resistor networks. We calculate the resistance crossover exponent $\phi$ up to second order in $\epsilon=6-d$, where $d$ is the spatial dimension. Our result $\phi=1+\epsilon /42 +4\epsilon^2 /3087$ verifies a previous calculation by Lubensky and Wang, which itself was based on the Potts--model formulation of the random resistor network.Comment: 27 pages, 14 figure

Long-range order versus random-singlet phases in quantum antiferromagnetic systems with quenched disorder

The stability of antiferromagnetic long-range order against quenched disorder is considered. A simple model of an antiferromagnet with a spatially varying Neel temperature is shown to possess a nontrivial fixed point corresponding to long-range order that is stable unless either the order parameter or the spatial dimensionality exceeds a critical value. The instability of this fixed point corresponds to the system entering a random-singlet phase. The stabilization of long-range order is due to quantum fluctuations, whose role in determining the phase diagram is discussed.Comment: 5 pp., REVTeX, epsf, 3 eps figs, final version as published, including erratu

Linear response theory and transient fluctuation theorems for diffusion processes: a backward point of view

On the basis of perturbed Kolmogorov backward equations and path integral representation, we unify the derivations of the linear response theory and transient fluctuation theorems for continuous diffusion processes from a backward point of view. We find that a variety of transient fluctuation theorems could be interpreted as a consequence of a generalized Chapman-Kolmogorov equation, which intrinsically arises from the Markovian characteristic of diffusion processes