Hydrogeochemical Characterization of GeothermalWater in Arjuno-Welirang, East Java, Indonesia

Arjuno-Welirang Volcanic Complex (AWVC) is one of geothermal fields whichlocated in East Java province, Indonesia. It belongs to a Quarternary volcanic arc and has potential for development of electricity. The field is situated in a steep volcanic terrain and there are only few geothermal manifestations, i.e., hot springs, fumaroles, solfataras, steaming ground and hydrothermal alteration. This study aims to classify the type and source of geothermal fluid and to estimate the reservoir condition of Arjuno- Welirang geothermal system. Data are obtained from collecting water samples including hot springs, cold springs, river waters and rain water, then they are analyzed using ICP-AES, titration and ion chromatography.All thermal waters have temperatures from 39.5–53°C and weakly acidic pH (5.2–6.5). Cangar and Padusanhot springs show bicarbonate water, formed by steam condensing or groundwater mixing. On the other hand, Songgoriti shows Cl-HCO3 type, formed by dilution of chloride fluid by either groundwater or bicarbonate water during lateral flow. All of the waters represent immature waters, indicating no strong outflow of neutral Cl-rich deep waters in AWVC. Cl/B ratios show that all water samples have a similar mixing ratio, showing they are from common fluid sources. However, Padusan and Songgoriti have higher Cl/B ratios than Cangar, suggesting that geothermal fluids possibly have reacted with sedimentary rocks before ascending to the surface. All waters were possibly mixed with shallow groundwater and they underwent rock-water reactions at depth before ascending to the surface. An estimated temperatures reservoir calculated using CO2 geothermometer yielded temperatures of 262–263 °C based on collecting of fumarole gas at Mt. Welirang crater. According to their characteristics, Cangar and Padusan are associated with AWVC, while Songgoriti is associated with Mt. Kawi

Study on Epithermal Gold Mineralization System at Shwebontha Prospect, Monywa Copper-Gold Ore Field, Central Myanmar

The Shwebontha prospect area is situated in the Central Volcanic Belt, central Myanmar, where the well-known Sagaing Fault serves as its eastern boundary. This study aims to document key the mineralogy, host rock geochemistry and ore mineralizing fluids. The mineralization, hosted by Upper Oligocene to Middle Miocene rhyolites, displays a strong lithological control. Mineralization is characterized by gold-bearing silicified massive ore and chalcedonic quartz veins in which sulfides are clustered and disseminated not only in quartz gangue but also in rhyolite host rocks. The significant ore minerals in the mineralized veins include pyrite, sphalerite, galena, chalcopyrite, and gold. Common hydrothermal alterations such as silicic, argillic and propylitic alteration types are recognized. According to the fluid inclusion data and interpretation, ore mineralizing fluids in the research area are characterized by formation temperatures of 260-280 °C and salinity of 0.35-2.41 % wt. NaCl eq. respectively. Mixing of hydrothermal fluids was generally considered to be an effective mechanism for ore transport and deposition

Fluid Inclusion Study of Epithermal Quartz Veins from the Kyaukmyet Prospect, Monywa Copper-Gold Ore Field, Central Myanmar

The Kyaukmyet prospect is located near the main ore bodies of the Kyisintaung and Sabetaung high-sulfidation Cu-Au deposits, Monywa copper-gold ore field, central Myanmar. Lithologic units in the research area are of mainly rhyolite lava, lapilli tuff and silicified sandstone, mudstone and siltstone units of Magyigon Formation which hosted to be polymetallic mineralization. Our field study recorded that epithermal quartz veins are hosted largely in rhyolite lava and lapilli tuff units. Those quartz veins show crustiform, banded (colloform), lattice bladed texture and comb quartz. The main objectives of the present research in which fluid inclusion studies were considered to conduct the nature, characteristics and hydrothermal fluids evolution from the epithermal quartz veins. In this research, there are three main types of fluid inclusions are classified according to their phase relationship (1) two-phase liquid-rich inclusions, (2) the coexisting liquid-rich and vapor-rich inclusions, and (3) only vapor-rich inclusions. Microthermometric measurements of fluid inclusions yielded homogenization temperatures (Th) of 148–282 °C and final ice-melting temperature (Tm)  of -0.2°C to -1.4°C . The value of (Tm) are equal to the salinities reaching up 0.35 to 2.07 wt % NaCl equiv. respectively. Estimation formation temperature of the quartz veins provide 190°C and 210°C and paleo-depth of formation are estimated to be between 130m and 210m. Petrography of fluid inclusion and microthermometric data suggest that fluid boiling as well as mixing processes were likely to be happened during the hydrothermal fluid evolution at the Kyaukmyet prospect. According to the characteristics of many parameters including petrography of fluid inclusion, microthermometric data, paleo-depth, evidence of quartz vein textures and types of hydrothermal alteration from the Kyaukmyet prospect allows to interpret these data to be the low-sulfidation epithermal system

Petrographic Characteristics and Geochemistry of Volcanic Rocks in the Kyaukmyet Prospect, Monywa District, Central Myanmar

The Kyaukmyet prospect lies approximately 5 km ENE of the highsulfidation Kyisintaung copper-gold deposit, Monywa district, central Myanmar. Geologically, the research area is remarked by magmatic extrusion that occurred during the Late Oligocene to Middle Miocene of Magyigon Formation which led to the outcrops of volcanic rocks. Study detailed on petrographical and geochemical of the Kyaukmyet volcanic rocks has not been performed before the present work. The principal aim of this paper is to document the petrographical and geochemical characteristics of volcanic suite rocks exposed in the Kyaukmyet prospect. The results of this data have provided insight into the origin of the rocks and petrogenetic processes during evolution. Petrographically, all the studied volcanic rocks in the research area show that trachytic and porphyritic textures with phenocrysts of quartz, plagioclase, and K-feldspar which are embedded in a fine to medium grained groundmass. The accessory minerals of this rock consist of biotite, chlorite and opaque mineral.Geochemically, these volcanic rocks having calc-alkaline nature and classified as volcanic field (rhyolite) as well as volcanic arc setting. Based on the chondrite normalized spider diagram, LREE has enriched to HREE in this area which indicated negative Eu anomaly and subduction tectonic setting

Variation of Slab Component in Ancient and Modern Merapi Products: A Detailed Look into Slab Derived Fluid Fluctuation over the Living Span of One of the Most Active Volcanoes in Sunda Arc

Holocene eruptions of Merapi have produced both medium-K and high-K calc alkaline series which correspond to products older and younger than 1900 years respectively. The change has been attributed to increasing sediment input as the volcano matures. This study presents two Merapi samples which represent Ancient and Modern Merapi. The two samples are analyzed for subduction components including B, Ba, Sr, and Pb using X-ray fluorescence (XRF) spectrometer and prompt gamma ray analysis (PGA). Our finding shows that Ancient Merapi sample from Plawangan Hill lava is close in affinities with younger than 1900 years high-K magma series. On the other hand, Modern Merapi sample from 2006 eruption juvenile is plotted within medium-K magma series which are observed in eruption products older than 1900 years. Ratios of fluid mobile elements to high field strength element (HFSE) (i.e. B/Nb, Ba/Y, Pb/Nb) consistently show that Ancient Merapi sample has higher input of slab derived fluid than Modern Merapi sample. A model using B/Nb and Ba/Nb suggests that Plawangan magma requires 1.5 % of sediment derived fluid, higher than estimated in 2006 eruption magma (1.2 %) and medium-K series magma, and within the range of high-K series magma, to explain its slab component enrichment. This evidence suggests that slab derived component addition to the sub-arc mantle wedge highly fluctuates over short period of evolution of a volcano. One possible explanation is the presence of veined hydrous metasomatized sub-arc mantle as Merapi magma source which allows melting of different mantle area to produce fluctuation of slab components in the course of evolution of Merapi magmas

Estimated Emplacement Temperatures for a Pyroclastic Deposits From the Sundoro Volcano, Indonesia, Using Charcoal Reflectance Analyses

DOI: 10.17014/ijog.5.1.1-11This study applies the charcoalification measurement method to infer the emplacement temperature of pyroclastic flow deposits erupted from the Sundoro Volcano, Indonesia. This pyroclastic flow partially covered the Liyangan archeological site, a site where Hindu temples were constructed approximately 1,000 years ago. Five samples of charcoal collected from this area were analyzed for reflectance and elemental composition. Charcoalification temperatures were determined based on mean random optical reflectance values (Ro) plotted on published Ro-Temperature curves. Charcoalification temperatures were also estimated using a published formula based on the charcoal\u27s hydrogen to carbon (H/C) ratio. These two methods for determining pyroclastic flow deposition temperatures indicated that the pyroclastic deposits that entombed the Liyangan archeological site ranged from 295° to 487°C when they were deposited. This study used very simple, rapid, precise, and low-cost methods of charcoalification temperature measurement to infer the emplacement temperature of a pyroclastic deposit. This estimation procedure could be applied widely to predict emplacement temperatures in volcanic area in Indonesia to enhance volcanic hazard mitigation

Mineral paragenesis and fluid inclusions of the Bincanai epithermal silver-base metal vein at Baturappe area, South Sulawesi, Indonesia

The Baturappe prospect located at southern part of Sulawesi island, Indonesia, is a hydrothermal mineralization district which is characterized by occurrence of epithermal silver-base metal deposits. The mineralization is hosted in basaltic-andesitic volcanic rocks of the late Middle-Miocene Baturappe Volcanics. More than 20 units of quartz – base metal veins are distributed in the area, and one of the most significant is the Bincanai vein. This study is aimed to characterize the mineral paragenesis and to elucidate the physicochemical conditions of the formation of the deposit on the basis of mineral assemblage and fluid inclusion mictrothermometry. Sulphide assemblages in the vein indicate an intermediate sulfidation state epithermal; beside galena and sphalerite as the early stage minerals, chalcopyrite, tennantite, and tetrahedrite are also identified as the later stage. Microthermometric study of fluid inclusions in quartz indicates formation temperature of the vein ranges from about 230 to 280°C Histogram of homogenization temperature suggests that there are two generations of hydrothermal fluid responsible for the ore mineralization in the vein; the higher temperature range represents formation temperature of the base metal (galena, sphalerite), while the lower temperature range is correlate with the precipitation of the rest relatively lower temperature sulphides (chalcopyrite, pyrite, tetrahedrite, tennantite, polybasite, and Bi-Ag-Cu-Fe-bearing sulfide). The sequence is also consistent with the mineral paragenetic. The mean of salinity (2.0–2.5 wt.% NaCl eq.) indicates that fluid responsible for the mineralization in the Bincanai vein is relatively low-salinity fluid

Estimated Emplacement Temperatures for a Pyroclastic Deposits From the Sundoro Volcano, Indonesia, Using Charcoal Reflectance Analyses

DOI: 10.17014/ijog.5.1.1-11This study applies the charcoalification measurement method to infer the emplacement temperature of pyroclastic flow deposits erupted from the Sundoro Volcano, Indonesia. This pyroclastic flow partially covered the Liyangan archeological site, a site where Hindu temples were constructed approximately 1,000 years ago. Five samples of charcoal collected from this area were analyzed for reflectance and elemental composition. Charcoalification temperatures were determined based on mean random optical reflectance values (Ro) plotted on published Ro-Temperature curves. Charcoalification temperatures were also estimated using a published formula based on the charcoal\u27s hydrogen to carbon (H/C) ratio. These two methods for determining pyroclastic flow deposition temperatures indicated that the pyroclastic deposits that entombed the Liyangan archeological site ranged from 295° to 487°C when they were deposited. This study used very simple, rapid, precise, and low-cost methods of charcoalification temperature measurement to infer the emplacement temperature of a pyroclastic deposit. This estimation procedure could be applied widely to predict emplacement temperatures in volcanic area in Indonesia to enhance volcanic hazard mitigation

Emplacement Temperature of the Overbank and Dilute-Detached Pyroclastic Density Currents of Merapi 5 November 2010 Events using Reflectance Analysis of Associated Charcoal

Merapi eruption in 2010 produced 17 km high column of ash and southward pyroclastic density current (PDC). Based on the deposits characteristics and distributions, the PDC is divided into channel and overbank facies (pyroclastic flow), and associated diluted PDC (pyroclastic surge). The hot overbank PDCs and the associated dilute-detached PDCs are the main cause of high casualty (367 fatalities) in medial-distal area (5–16 km), especially near main valley of Kali Gendol. We reported the emplacement temperature of these two deposits using reflectance analysis of charcoal. We used both entombed charcoals in the overbank PDC and charcoals in singed house nearby. Samples were collected on 6–13 km distance southward from summit. Charcoalification temperatures of the entombed charcoals represent deposition temperature of the overbank PDCs, whereas those of charcoals in the singed house resembles temperature of the associated dilute-detached PDCs. Results show mean random reflectance (Ro%) values of entombed charcoal mainly range 1.1–1.9 correspond to temperature range 328–444 °C, whereas charcoal in singed house range 0.61–1.12 with estimated temperature range 304–358 °C. The new temperature data of the dilute-detached PDCs in the medial-distal area is crucial for assessing impact scenarios for exposed populations as it affects them lethally and destructivel

VEINS AND HYDROTHERMAL BRECCIAS OF THE RANDU KUNING PORPHYRY Cu-Au AND EPITHERMAL Au DEPOSITS AT SELOGIRI AREA, CENTRAL JAVA INDONESIA

The Randu Kuning prospect is situated at Selogiri area, Wonogiri, Central Java, Indonesia. This location is about 40 km to the south-east from Solo city or approximately 70 km east of Yogyakarta city. Many Tertiary dioritic rocks related alterationmineralisation were found at the Randu Kuning area and its vicinity, including hornblende microdiorite, hornblende-pyroxene diorite and quartz diorite. Mineralisation type of the Randu Kuning prospect was interpreted as porphyry Cu-Au and a number epithermal Au-base metals deposits in its surrounding. The closed existing of porphyry Cu-Au and epithermal Au-base metals type deposits at the Randu Kuning area produced a very complex of veins and hydrothermal breccias crosscutting relationship. A lot of porphyry veins types were found and observed at the Randu Kuning area, and classified into at least seven types. Most of the porphyry veins were cross cut by epithermal type veins. Many epithermal veins also are found and crosscut into deeply porphyry vein types. There are genetically at least two type of hydrothermal breccias have recognized in the research area, i.e. magmatic-hydrothermal breccia and phreatomagmatic breccia. Magmatic hydrothermal breccias are mostly occured in contact between hornblende microdiorite or quartz diorite and hornblende-pyroxene diorite, characterized by angular fragments/clasts supported or infilled by silicas, carbonates and sulphides matrix derived from hydrothermal fluids precipitation. Phreatomagmatic breccias are characterized by abundant of the juvenile clasts, indicated contact between hot magma with fluid or water as well as many wall rock fragments such as altered diorites and volcaniclastic rock clasts set in clastical matrix. The juvenile clasts usually compossed by volcanic glasses and aphanitic rocks in rounded-irregular shape. Both veining and brecciation processes have an important role in gold and copper mineralisation of the Randu Kuning Porphyry Cu-Au and epithermal Au-base metals deposits, mostly related to the presence of quartz veins/veinlets containing significant sulphides, i.e., quartz with thin centre line sulphides (Abtype) veins, pyrite±chalcopyrite (C type) veinlets, pyrite+quartz± chalcopyrire±carbonate (D type) veins of porphyry types as well as epithermal environment quarts+ sulphides+carbonate veins