347 research outputs found
Exploring the relationship between effective and reflective practice in applied sport psychology
This study offers an investigation into the concept of effective practice in applied sport psychology (ASP) with emphasis being placed upon the role that reflective practice may have in helping practitioners to develop the effectiveness of their service delivery. Focus groups (n = 2), consisting of accredited and trainee sport psychologists, were conducted to generate a working definition of effective practice, and discuss the concept of effectiveness development through engagement in reflective practices. The resulting definition encapsulated a multidimensional process involving reflection-on-practice. Initial support for the definition was gained through consensus validation involving accredited sport psychologists (n = 34) who agreed with the notion that although effectiveness is context specific it is related to activities designed to meet client needs. Reflective practice emerged as a vital component in the development of effectiveness, with participants highlighting that reflection is intrinsically linked to service delivery, and a key tool for experiential learning.</jats:p
Confirmatory factor analysis of the Test of Performance Strategies (TOPS) among adolescent athletes
The aim of the present study was to examine the factorial validity of the Test of Performance Strategies (TOPS; Thomas et al., 1999) among adolescent athletes using confirmatory factor analysis. The TOPS was designed to assess eight psychological strategies used in competition (i.e. activation, automaticity, emotional control, goal-setting, imagery, negative thinking, relaxation and self-talk,) and eight used in practice (the same strategies except negative thinking is replaced by attentional control). National-level athletes (n = 584) completed the 64-item TOPS during training camps. Fit indices provided partial support for the overall measurement model for the competition items (robust comparative fit index = 0.92, Tucker-Lewis index = 0.88, root mean square error of approximation = 0.05) but minimal support for the training items (robust comparative fit index = 0.86, Tucker-Lewis index = 0.81, root mean square error of approximation = 0.06). For the competition items, the automaticity, goal-setting, relaxation and self-talk scales showed good fit, whereas the activation, emotional control, imagery and negative thinking scales did not. For the practice items, the attentional control, emotional control, goal-setting, imagery and self-talk scales showed good fit, whereas the activation, automaticity and relaxation scales did not. Overall, it appears that the factorial validity of the TOPS for use with adolescents is questionable at present and further development is required
Solid State Systems for Electron Electric Dipole Moment and other Fundamental Measurements
In 1968, F.L. Shapiro published the suggestion that one could search for an
electron EDM by applying a strong electric field to a substance that has an
unpaired electron spin; at low temperature, the EDM interaction would lead to a
net sample magnetization that can be detected with a SQUID magnetometer. One
experimental EDM search based on this technique was published, and for a number
of reasons including high sample conductivity, high operating temperature, and
limited SQUID technology, the result was not particularly sensitive compared to
other experiments in the late 1970's.
Advances in SQUID and conventional magnetometery had led us to reconsider
this type of experiment, which can be extended to searches and tests other than
EDMs (e.g., test of Lorentz invariance). In addition, the complementary
measurement of an EDM-induced sample electric polarization due to application
of a magnetic field to a paramagnetic sample might be effective using modern
ultrasensitive charge measurement techniques. A possible paramagnetic material
is Gd-substituted YIG which has very low conductivity and a net enhancement
(atomic enhancement times crystal screening) of order unity. Use of a
reasonable volume (100's of cc) sample of this material at 50 mK and 10 kV/cm
might yield an electron EDM sensitivity of e cm or better, a factor
of improvement over current experimental limits.Comment: 6 pages. Prepared for ITAMP workshop on fundamental physics that was
to be held Sept 20-22 2001 in Cambride, MA, but was canceled due to terrorist
attack on U.S New version incorporates a number of small changes, most
notably the scaling of the sensitivity of the Faraday magnetometer with
linewidth is now treated in a saner fashion. The possibility of operating at
an even lower temperarture, say 10 microkelvin, is also discusse
Characterization of Polyphosphoesters by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
FT-ICR mass spectrometry, together with collision-induced dissociation and electron capture dissociation, has been used to characterize the polyphosphoester poly[1,4-bis(hydroxyethyl)terephthalate-alt-ethyloxyphosphate] and its degradation products. Three degradation pathways
were elucidated: hydrolysis of the phosphate–[1,4-bis(hydroxyethyl)terephthalate]bonds; hydrolysis of the phosphate–ethoxy bonds; and hydrolysis of the ethyl–terephthalate bonds. The dominant degradation reactions were those that involved the phosphate groups. This work constitutes the first application of mass spectrometry to the characterization of polyphosphoesters and demonstrates the suitability of high mass accuracy FT-ICR mass spectrometry, with CID and ECD, for the structural analysis of polyphosphoesters and their degradation products
Phenyl 2,3-O-isopropylidene-1-thio-α-d-rhamnopyranoside
In the title compound, C15H20O4S, a dioxolane ring is fused to the pyran ring of the sugar which carries a thiophenyl substituent on the anomeric C atom. The dioxolane ring adopts an envelope conformation and the pyran ring system a distorted 4
C
1 chair. The structure is stabilized by O—H⋯O hydrogen bonds, forming centrosymmetric dimers that generate an R
2
2(10) ring motif. Additional C—H⋯O interactions form an extended network. Two C atoms of the phenyl ring are disordered over two positions; the site occupancy factors are ca. 0.7 and 0.3
Effects of precompetition state anxiety interventions on performance time and accuracy among amateur soccer players: Revisiting the matching hypothesis
In this study, we tested the matching ypothesis, which contends that administration of a cognitive or somatic anxiety intervention should be matched to a participant's dominant anxiety response. Sixty-one male soccer players (mean age 31.6 years, s=6.3) were assigned to one of four groups based on their responses to the Competitive State Anxiety Inventory-2, which was modified to include a directional scale. Interventions were randomly administered in a counterbalanced order 10 min before each performance trial on a soccer skill test. The dominantly cognitive anxious group (n=17), the dominantly somatic anxious group (n=17), and the non-anxious control intervention group (n=14) completed a baseline performance trial. The second and third trials were completed with random administration of brief cognitive and somatic interventions. The non-anxious control group (n=13) completed three trials with no intervention. A mixed-model, GroupTreatment multivariate analysis of variance indicated significant (P0.05), or performance time or accuracy (P>0.05). The present findings do not provide support for the matching hypothesis for state anxiety intensity and direction, or for performance
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