Construct-Validity of the Engagement with Challenge Measure for Adolescents: Structural- and Criterion-Validity Evidence

For adolescents, engaging with challenge is a key developmental task, hypothesized to support development of adult-like competencies (e.g., agency and self-direction; Larson, 2000). This study aimed to assess the construct-validity (structural- and concurrent-validity) of a new self-report measure assessing adolescents’ engagement with challenge to help researchers understand how different settings and the conditions in these settings support adolescents’ development. The sample consisted of 337 adolescents in 10 FFA programs along with the adult advisors in each program. Adolescents completed a questionnaire, which included the Engagement with Challenge measure and the following criterion variables: number of contests completed, participation frequency, and leadership roles. In addition to the self-reported criterion variables, the adult advisor evaluated Engagement with Challenge for each FFA student member in that program using a single item. The findings of this study provided strong evidence for the structural-validity of the engagement with challenge construct measured by the new scale, including having passed confirmatory factor analysis configural, weak, and strong invariance tests across four grade groupings. The findings also provided further evidence of construct-validity, as Engagement with Challenge correlated in the a priori hypothesized direction and magnitude. Suggestions for analysis with the new measure and for future research are presented

The Potential Constants of Ethane

The infrared and Raman data of light and heavy ethane (C2H6 and C2D6) have been reexamined for the purpose of determining as accurately as possible the potential constants of the ethane molecule. In order to fill in some of the gaps in the spectroscopic data, additional high resolution measurements have been made on the infrared spectrum of heavy ethane which have given more precise values for the active fundamental frequencies and zeta‐values. Resolution of the fine structure associated with the parallel band ν5* has given the value of the large moment of inertia of C2D6, thus completing the information required for the spectroscopic determination of the dimensions of ethane. The data yield, C☒C distance=1.543A, C☒H distance=1.102A, H☒C☒C angle=109°37′, and H☒C☒H angle=109°19′. The twenty‐two distinct potential constants compatible with the D3d symmetry of ethane have been determined through their relationships to the normal frequencies and zeta‐values of C2H6 and C2D6. The normal frequencies have been obtained by addition of anharmonic corrections to the spectroscopically observed fundamental frequencies. These corrections were estimated by means of the known anharmonic corrections for methane and the conditions imposed by the Teller product rule. The fundamental frequencies and zeta‐values have been taken directly from the observed band centers and rotational spacings wherever possible. In the cases of resonance, the influence of the couplings were either calculated or estimated and the corresponding unperturbed values for the frequencies and zeta‐values selected. The potential function is determined first in terms of a set of simple symmetry coordinates, and then reexpressed in terms of valence coordinates to permit comparison of the valence force constants of ethane and methane.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70194/2/JCPSA6-20-2-313-1.pd

The Use of Mixtures of Market and Experimental Choice Data in Establishing Guideline Weights for Evaluating Competitive Bids in a Transport Organisation

The government sector is increasingly using competitive bidding for service deliveries such as the provision of bus and rail services as well as the purchasing of professional engineering services such as project planning, design, and project supervision. As part of a program to simplify and introduce consistency in the tender evaluation process, one government transport agency in New Zealand financed a study to investigate the potential of combined revealed and stated preference methods as a way of establishing weights to attach to the criteria used to evaluate offers of engineering services. These techniques have mainly been used in the study of travel choices yet they have a much broader appeal in studying the decision making process of organisations. In this paper we use a data-mixing model to capture the decision expertise of a transport organisation through the revelation of preference weights for each evaluation criterion. Using choice information based on both market-driven and experimentally-derived choice sets, we should be able to increase the robustness of the evaluation weights in comparison to the weights obtained from single data-sourced models. The resulting parameterised tool can be used in subsequent tender evaluations to provide an additional source of advise to supplement or replace that provided by current members of a bid evaluation team

Selective Bibliography on Sociology in Brazil

Exact date of working paper unknown

Construct-Validity of the Engagement with Challenge Measure for Adolescents: Structural- and Criterion-Validity Evidence

This is the published version.For adolescents, engaging with challenge is a key developmental task, hypothesized to support development of adult-like competencies (e.g., agency and self-direction; Larson, 2000). This study aimed to assess the construct-validity (structural- and concurrent-validity) of a new self-report measure assessing adolescents’ engagement with challenge to help researchers understand how different settings and the conditions in these settings support adolescents’ development. The sample consisted of 337 adolescents in 10 FFA programs along with the adult advisors in each program. Adolescents completed a questionnaire, which included the Engagement with Challenge measure and the following criterion variables: number of contests completed, participation frequency, and leadership roles. In addition to the self-reported criterion variables, the adult advisor evaluated Engagement with Challenge for each FFA student member in that program using a single item. The findings of this study provided strong evidence for the structural-validity of the engagement with challenge construct measured by the new scale, including having passed confirmatory factor analysis configural, weak, and strong invariance tests across four grade groupings. The findings also provided further evidence of construct-validity, as Engagement with Challenge correlated in the a priori hypothesized direction and magnitude. Suggestions for analysis with the new measure and for future research are presented

Youth Program Adult Leader\u27s Directive Assistance and Autonomy Support and Development of Adolescents’ Agency Capacity

Developing a capacity for exercising agency is an important developmental task of adolescence. Many organized youth programs provide adolescents opportunities to build their capacity to exercise agency. The researchers tested hypotheses that adult youth program leader\u27s directive assistance and autonomy support would promote adolescents’ capacity for agency. They surveyed 441 high school adolescents and 11 adult advisors from 10 Future Farmers of America chapters twice over 2 years. Adolescents self‐reported on their capacity for agency and advisors reported on each adolescent\u27s capacity. Directive assistance and autonomy support correlated with the capacity for agency within both time points. Only autonomy support predicted adolescents’ capacity for agency over time. Implications of leader\u27s support for adolescents’ capacity for exercising agency are discussed

Langevin Equation for the Density of a System of Interacting Langevin Processes

We present a simple derivation of the stochastic equation obeyed by the density function for a system of Langevin processes interacting via a pairwise potential. The resulting equation is considerably different from the phenomenological equations usually used to describe the dynamics of non conserved (Model A) and conserved (Model B) particle systems. The major feature is that the spatial white noise for this system appears not additively but multiplicatively. This simply expresses the fact that the density cannot fluctuate in regions devoid of particles. The steady state for the density function may however still be recovered formally as a functional integral over the coursed grained free energy of the system as in Models A and B.Comment: 6 pages, latex, no figure

Thermally controlled widening of droplet etched nanoholes

We describe a method to control the shape of nanoholes in GaAs (001) which combines the technique of local droplet etching using Ga droplets with long-time thermal annealing. The cone-like shape of inverted nanoholes formed by droplet etching is transformed during long-time annealing into widened holes with flat bottoms and reduced depth. This is qualitatively understood using a simplified model of mass transport incorporating surface diffusion and evaporation. The hole diameter can be thermally controlled by varying the annealing time or annealing temperature which provides a method for tuning template morphology for subsequent nanostructure nucleation. We also demonstrate the integration of the combined droplet/thermal etching process with heteroepitaxy by the thermal control of hole depth in AlGaAs layers

Microarray and Growth Analyses Identify Differences and Similarities of Early Corn Response to Weeds, Shade, and Nitrogen Stress

Weed interference with crop growth is often attributed to water, nutrient, or light competition; however, specific physiological responses to these stresses are not well described. This study\u27s objective was to compare growth, yield, and gene expression responses of corn to nitrogen (N), low light (40% shade), and weed stresses. Corn vegetative parameters from V2 to V12 stages, yield parameters, and gene expression using transcriptome (2008) and quantitative polymerase chain reaction (qPCR) (2008/09) analyses at V8 were compared among the stresses and with nonstressed corn. N stress did not affect vegetative parameters, although grain yield was reduced by 40% compared with nonstressed plants. Shade, present until V2, reduced biomass and leaf area \u3e 50% at V2, and recovering plants remained smaller than nonstressed plants at V12. However, grain yields of shade-stressed and nonstressed plants were similar, unless shade remained until V8. Weed stress reduced corn growth and yield in 2008 when weeds remained until V6. In 2009, weed stress until V2 reduced corn vegetative growth, but yield reductions occurred only if weed stress remained until V6 or later. Principle component analysis of differentially expressed genes indicated that shade and weed stress had more similar gene expression patterns to each other than they did to nonstressed or N-stressed tissues. However, corn grown in N-stressed conditions shared 252 differentially expressed genes with weed-stressed plants. Ontologies associated with light/photosynthesis, energy conversion, and signaling were down-regulated in response to all three stresses. Shade and weed stress clustered most tightly together, based on gene expression, but shared only three ontologies, O-METHYLTRANSFERASE activity (lignification processes), POLY(U)-BINDING activity (posttranscriptional gene regulation), and stomatal movement. Based on morphologic and genomic observations, weed stress to corn was not explained by individual effects of N or light stress. Therefore, we hypothesize that these stresses share limited signaling mechanisms