Effect of polymer concentration and length of hydrophobic end block on the unimer-micelle transition broadness in amphiphilic ABA symmetric triblock copolymer solutions

The effects of the length of each hydrophobic end block N_{st} and polymer concentration \bar{\phi}_{P} on the transition broadness in amphiphilic ABA symmetric triblock copolymer solutions are studied using the self-consistent field lattice model. When the system is cooled, micelles are observed, i.e.,the homogenous solution (unimer)-micelle transition occurs. When N_{st} is increased, at fixed \bar{\phi}_{P}, micelles occur at higher temperature, and the temperature-dependent range of micellar aggregation and half-width of specific heat peak for unimer-micelle transition increase monotonously. Compared with associative polymers, it is found that the magnitude of the transition broadness is determined by the ratio of hydrophobic to hydrophilic blocks, instead of chain length. When \bar{\phi}_{P} is decreased, given a large N_{st}, the temperature-dependent range of micellar aggregation and half-width of specific heat peak initially decease, and then remain nearly constant. It is shown that the transition broadness is concerned with the changes of the relative magnitudes of the eductions of nonstickers and solvents from micellar cores.Comment: 8 pages, 4 figure

The effect of asymmetry of the coil block on self-assembly in ABC coil-rod-coil triblock copolymers

Using the self-consistent field approach, the effect of asymmetry of the coil block on the microphase separation is focused in ABC coil-rod-coil triblock copolymers. For different fractions of the rod block $f_{\text B}$, some stable structures are observed, i.e., lamellae, cylinders, gyroid, and core-shell hexagonal lattice, and the phase diagrams are constructed. The calculated results show that the effect of the coil block fraction $f_{\text A}$ is dependent on $f_{\text B}$. When $f_{\text B}=0.2$, the effect of asymmetry of the coil block is similar to that of the ABC flexible triblock copolymers; When $f_{\text B}=0.4$, the self-assembly of ABC coil-rod-coil triblock copolymers behaves like rod-coil diblock copolymers under some condition. When $f_{\text B}$ continues to increase, the effect of asymmetry of the coil block reduces. For $f_{\text B}=0.4$, under the symmetrical and rather asymmetrical conditions, an increase in the interaction parameter between different components leads to different transitions between cylinders and lamellae. The results indicate some remarkable effect of the chain architecture on self-assembly, and can provide the guidance for the design and synthesis of copolymer materials.Comment: 9 pages, 3 figure

Thermal and non-thermal emission in the Cygnus X region

Radio continuum observations detect non-thermal synchrotron and thermal bremsstrahlung radiation. Separation of the two different emission components is crucial to study the properties of diffuse interstellar medium. The Cygnus X region is one of the most complex areas in the radio sky which contains a number of massive stars and HII regions on the diffuse thermal and non-thermal background. More supernova remnants are expected to be discovered. We aim to develop a method which can properly separate the non-thermal and thermal radio continuum emission and apply it to the Cygnus X region. The result can be used to study the properties of different emission components and search for new supernova remnants in the complex. Multi-frequency radio continuum data from large-scale surveys are used to develop a new component separation method. Spectral analysis is done pixel by pixel for the non-thermal synchrotron emission with a realistic spectral index distribution and a fixed spectral index of beta = -2.1 for the thermal bremsstrahlung emission. With the new method, we separate the non-thermal and thermal components of the Cygnus X region at an angular resolution of 9.5arcmin. The thermal emission component is found to comprise 75% of the total continuum emission at 6cm. Thermal diffuse emission, rather than the discrete HII regions, is found to be the major contributor to the entire thermal budget. A smooth non-thermal emission background of 100 mK Tb is found. We successfully make the large-extent known supernova remnants and the HII regions embedded in the complex standing out, but no new large SNRs brighter than Sigma_1GHz = 3.7 x 10^-21 W m^-2 Hz^-1 sr^-1 are found.Comment: 9 pages, 5 figures, accepted by A&A. The quality of the figures is reduced due to file size limit of the websit

From cyber-security deception to manipulation and gratification through gamification

Over the last two decades the field of cyber-security has experienced numerous changes associated with the evolution of other fields, such as networking, mobile communications, and recently the Internet of Things (IoT) [3]. Changes in mindsets have also been witnessed, a couple of years ago the cyber-security industry only blamed users for their mistakes often depicted as the number one reason behind security breaches. Nowadays, companies are empowering users, modifying their perception of being the weak link, into being the center-piece of the network design [4]. Users are by definition "in control" and therefore a cyber-security asset. Researchers have focused on the gamification of cyber- security elements, helping users to learn and understand the concepts of attacks and threats, allowing them to become the first line of defense to report anoma- lies [5]. However, over the past years numerous infrastructures have suffered from malicious intent, data breaches, and crypto-ransomeware, clearly showing the technical "know-how" of hackers and their ability to bypass any security in place, demonstrating that no infrastructure, software or device can be consid- ered secure. Researchers concentrated on the gamification, learning and teaching theory of cyber-security to end-users in numerous fields through various techniques and scenarios to raise cyber-situational awareness [2][1]. However, they overlooked the users’ ability to gather information on these attacks. In this paper, we argue that there is an endemic issue in the the understanding of hacking practices leading to vulnerable devices, software and architectures. We therefore propose a transparent gamification platform for hackers. The platform is designed with hacker user-interaction and deception in mind enabling researchers to gather data on the techniques and practices of hackers. To this end, we developed a fully extendable gamification architecture allowing researchers to deploy virtualised hosts on the internet. Each virtualised hosts contains a specific vulnerability (i.e. web application, software, etc). Each vulnerability is connected to a game engine, an interaction engine and a scoring engine

Cultural differences in neurocognitive mechanisms underlying believing

Believing as a fundamental mental process influences other cognitive/affective processes and behavior. However, it is unclear whether believing engages distinct neurocognitive mechanisms in people with different cultural experiences. We addressed this issue by scanning Chinese and Danish adults using functional MRI during believing judgments on personality traits of oneself and a celebrity. Drift diffusion model analyses of behavioral performances revealed that speed/quality of information acquisition varied between believing judgments on positive and negative personality traits in Chinese but not in Danes. Chinese adopted a more conservative strategy of decision-making during celebrity- than self-believing judgments whereas an opposite pattern was observed in Danes. Non-decisional processes were longer for celebrity- than for self-believing in Danes but not in Chinese. Believing judgments activated the medial prefrontal cortex (mPFC) in both cultural groups but elicited stronger left anterior insular and ventral frontal activations in Chinese. Greater mPFC activity in Chinese was associated with longer duration of non-decision processes during believing-judgments, which predicted slower retrieval of self-related information in a memory test. Greater mPFC activity in Danes, however, was associated with a less degree of adopting a conservative strategy during believing judgments, which predicted faster retrieval of self-related information. Our findings highlight different neurocognitive processes engaged in believing between individuals from East Asian and Western cultures

Study on flow and temperature drop behavior of six-stream tundish with less-flow casting

In this paper, numerical simulation method was used to study the influence of closing different nozzles on the flow state and temperature distribution of molten steel in the six-stream tundish, which provides a theoretical basis for ensuring the temperature uniformity of molten steel in the tundish and the subsequent stable continuous casting production during the less-flow casting. The results show that: (a) In the case of closing one nozzle, when the No. 3 nozzle is closed, the overall temperature is relatively uniform. (b) In the case of closing two nozzles, when the No. 2 and No. 3 nozzles are closed, the overall temperature is more uniform