71,045 research outputs found
The effect of asymmetry of the coil block on self-assembly in ABC coil-rod-coil triblock copolymers
Using the self-consistent field approach, the effect of asymmetry of the coil
block on the microphase separation is focused in ABC coil-rod-coil triblock
copolymers. For different fractions of the rod block , some stable
structures are observed, i.e., lamellae, cylinders, gyroid, and core-shell
hexagonal lattice, and the phase diagrams are constructed. The calculated
results show that the effect of the coil block fraction is
dependent on . When , the effect of asymmetry of
the coil block is similar to that of the ABC flexible triblock copolymers; When
, the self-assembly of ABC coil-rod-coil triblock copolymers
behaves like rod-coil diblock copolymers under some condition. When continues to increase, the effect of asymmetry of the coil block reduces.
For , under the symmetrical and rather asymmetrical
conditions, an increase in the interaction parameter between different
components leads to different transitions between cylinders and lamellae. The
results indicate some remarkable effect of the chain architecture on
self-assembly, and can provide the guidance for the design and synthesis of
copolymer materials.Comment: 9 pages, 3 figure
Effect of polymer concentration and length of hydrophobic end block on the unimer-micelle transition broadness in amphiphilic ABA symmetric triblock copolymer solutions
The effects of the length of each hydrophobic end block N_{st} and polymer
concentration \bar{\phi}_{P} on the transition broadness in amphiphilic ABA
symmetric triblock copolymer solutions are studied using the self-consistent
field lattice model. When the system is cooled, micelles are observed, i.e.,the
homogenous solution (unimer)-micelle transition occurs. When N_{st} is
increased, at fixed \bar{\phi}_{P}, micelles occur at higher temperature, and
the temperature-dependent range of micellar aggregation and half-width of
specific heat peak for unimer-micelle transition increase monotonously.
Compared with associative polymers, it is found that the magnitude of the
transition broadness is determined by the ratio of hydrophobic to hydrophilic
blocks, instead of chain length. When \bar{\phi}_{P} is decreased, given a
large N_{st}, the temperature-dependent range of micellar aggregation and
half-width of specific heat peak initially decease, and then remain nearly
constant. It is shown that the transition broadness is concerned with the
changes of the relative magnitudes of the eductions of nonstickers and solvents
from micellar cores.Comment: 8 pages, 4 figure
Generating entanglement between microwave photons and qubits in multiple cavities coupled by a superconducting qutrit
We discuss how to generate entangled coherent states of four
\textrm{microwave} resonators \textrm{(a.k.a. cavities)} coupled by a
superconducting qubit. We also show \textrm{that} a GHZ state of four
superconducting qubits embedded in four different resonators \textrm{can be
created with this scheme}. In principle, \textrm{the proposed method} can be
extended to create an entangled coherent state of resonators and to prepare
a Greenberger-Horne-Zeilinger (GHZ) state of qubits distributed over
cavities in a quantum network. In addition, it is noted that four resonators
coupled by a coupler qubit may be used as a basic circuit block to build a
two-dimensional quantum network, which is useful for scalable quantum
information processing.Comment: 13 pages, 7 figure
Stokes Parameters as a Minkowskian Four-vector
It is noted that the Jones-matrix formalism for polarization optics is a
six-parameter two-by-two representation of the Lorentz group. It is shown that
the four independent Stokes parameters form a Minkowskian four-vector, just
like the energy-momentum four-vector in special relativity. The optical filters
are represented by four-by-four Lorentz-transformation matrices. This
four-by-four formalism can deal with partial coherence described by the Stokes
parameters. A four-by-four matrix formulation is given for decoherence effects
on the Stokes parameters, and a possible experiment is proposed. It is shown
also that this Lorentz-group formalism leads to optical filters with a symmetry
property corresponding to that of two-dimensional Euclidean transformations.Comment: RevTeX, 22 pages, no figures, submitted to Phys. Rev.
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