Viscosity model of Heavy Oil with calibration of shear velocity data

Summary New data of the shear wave velocity of heavy oils using the transmission wave at low temperature combined with the data using reflection wave at high temperature provides the probability to build a complete model of shear velocity from liquid phase to solid phase. To get the more reasonable viscosity of heavy oils at low temperature, we modified the existing viscosity models with calibration by glass and liquid points from the shear velocity model. The HN frequency model with new optimal parameters can be used to fit the data with updated viscosity from the modified model. The HN model gives the estimation of shear properties of heavy oils including attenuation in frequency domain

Modeling the elastic characteristics of overpressure due to thermal maturation in organic shales

Modeling the overpressure of organic shales caused by thermal maturation and its elastic responses is crucial for geophysical characterization of source rocks and unconventional shale reservoirs. Thermal maturation involves the generation of excess fluid contents (oil and gas) and can cause the overpressure if an organic shale preserves the produced fluids partly or wholly. The solid organic matter (e.g., kerogen or solid bitumen) with the potential of generating hydrocarbon presents two types of morphology in organic shales: scattered patches as pore-fillings and continuous network as load-bearings. According to the kerogen morphology, two bulk volume models are devised to simulate the elasticity of organic shales using respective rock-physics modeling schemes. The rock physics modeling combined with the density and compressibility of pore-fillings are demonstrated to effectively capture the excess pore pressure characteristics due to thermal maturation in organic shales. The basic principle of solving the overpressure is that the pore space volume equals the total volume of all components within the pores before and after the maturation. According to the modeling results, the elastic characteristics of overpressure due to thermal maturation reveal a decrease in velocity and a slight decrease in density. Besides, for an organic shale with a relatively rigid framework, it tends to yield higher overpressure than a shale with a relatively compliant framework. With proper calibration, the modeling strategy shows its potential in quantitatively interpreting the well-log data of organic shale formation within the thermal maturation window.Document Type: Original articleCited as: Qin, X., Zhao, L., Zhu, J., Han, D. Modeling the elastic characteristics of overpressure due to thermal maturation in organic shales. Advances in Geo-Energy Research, 2023, 10(3): 174-188. https://doi.org/10.46690/ager.2023.12.0

Combined effects of permeability and fluid saturation on seismic wave dispersion and attenuation in partially-saturated sandstone

Knowledge of dispersion and attenuation is essential for better reservoir characterization and hydrocarbon identification. However, limited by reliable laboratory data at seismic frequency bands, the roles of rock and fluid properties in inducing dispersion and attenuation are still poorly understood. Here we perform a series of laboratory measurements on Bentheimer and Bandera sandstone under both vacuum-dry and partially water-saturated conditions at frequencies ranging from 2 to 600 Hz. At vacuum-dry conditions, the bulk dispersion and attenuation in Bandera sandstone with more clay contents are distinctly larger than those in Bentheimer sandstone, suggesting clay contents might contribute to the inelasticity of the rock frame. The partially water-saturated results show the combined effects of rock permeability and fluid saturation on bulk dispersion and attenuation. Even a few percent of gas can substantially dominate the pore-fluid relaxation by providing a quick and short communication path for pore pressure gradients. The consequent bulk dispersion and attenuation are negligible. Only as the samples are approaching fully water-saturated conditions, rock permeability begins to play an essential role in the pore-fluid relaxation. For Bandera sandstone with lower permeability, a partially relaxed status of pore fluids is achieved when the gas saturation is lower than 5%, accompanied by significant attenuation and dispersion.Cited as: Wei, Q., Wang, Y., Han, D., Sun, M., Huang, Q. Combined effects of permeability and fluid saturation on seismic wave dispersion and attenuation in partially-saturated sandstone. Advances in Geo-Energy Research, 2021, 5(2): 181-190, doi: 10.46690/ager.2021.02.0

Modeling of effective pressure effect on porous reservoir rocks

Summary Effective pressure effect on porous reservoir formation is one of the most important factors contributing to time-lapse seismic attribute changes. Our research shows that the existing commonly used models tend to overestimate effective pressure effect at high effective pressure, which might cause significant misinterpretation of 4D seismic data. Based on analysis of a large quantity of lab data, a new model that is simpler and has clearer physical meaning was brought up in this study. This new model should be sufficient to describe the effective pressure effect on various porous reservoir rocks

Novel 5, 6-Dihydropyrrolo[2,1-a]isoquinolines as Scaffolds for Synthesis of Lamellarin Analogues

As core skeletons of lamellarins: 5,6-Dihydropyrrolo[2,1-a]isoquinolines are one of the important alkaloids that exhibit significant biological activities, in this study, an efficient synthetic route was described for two novel compounds, 5,6-dihydropyrrolo[2,1-a]isoquinolines I and II. Compound I was synthesized from isovanillin with 28.3% overall yield by a six-step reaction while II from 2-(3, 4-dimethoxyphenyl) ethanamine was with 61.6% overall yield by a three-step reaction. And the structures of these two compounds were confirmed by means of IR spectrum, 1H NMR, 13C NMR, MS, HRMS, and melting point measurements

Infection of Ophiocordyceps sinensis fungus causes dramatic changes in the microbiota of its Thitarodes host

The Chinese cordyceps is a unique and valuable parasitic complex of Thitarodes/Hepialus ghost moths and the Ophiocordyceps sinensis fungus for medicine and health foods from the Tibetan Plateau. During artificial cultivation of Chinese cordyceps, the induction of blastospores into hyphae is a prerequisite for mummification of the infected Thitarodes larvae. To explore the microbial involvement in the induction of mycelia-blastospore transition, the microbiota of the hemolymph and gut from Thitarodes xiaojinensis larvae with or without injected O. sinensis blastospores were investigated by culture-dependent and -independent methods. Twenty-five culturable bacterial species and 14 fungal species, together with 537 bacterial operational taxonomic units (OTUs) and 218 fungal OTUs, were identified from the hemolymph and gut of samples from five stages including living larvae without injected fungi (A) or with high blastospore load (B), mummifying larvae without mycelia coating (C), freshly mummifying larvae coated with mycelia (D), and completely mummified larvae with mycelia (E). Two culturable bacterial species (Serratia plymuthica, Serratia proteamaculans), and 47 bacterial and 15 fungal OTUs were considered as shared species. The uninfected larval hemolymph contained 13 culturable bacterial species but no fungal species, together with 164 bacterial and 73 fungal OTUs. To our knowledge, this is the first study to detect large bacterial communities from the hemolymph of healthy insect larvae. When the living larvae contained high blastospore load, the culturable bacterial community was sharply inhibited in the hemolymph but the bacterial and fungal community greatly increased in the gut. In general, high blastospore load increased bacterial diversity but sharply decreased fungal diversity in the hemolymph and gut by OTUs. The bacterial loads of four culturable species (Chryseobacterium sp., Pseudomonas fragi, S. plymuthica, S. proteamaculans) increased significantly and O. sinensis and Pseudomonas spp. became dominant microbes, when the infected larvae became mummified, indicating their possible involvement in the larval mummification process. The discovery of many opportunistic pathogenic bacteria in the hemolymph of the healthy larvae, the larval microbial diversity influenced by O. sinensis challenge and the involvement of dominant bacteria during larval mummification process provide new insight into the infection and mummification mechanisms of O. sinensis in its Thitarodes hosts

Attenuation estimation with continuous wavelet transforms

SUMMARY Seismic attenuation measurements from surface seismic data using spectral ratios are particularly sensitive to inaccurate spectral estimation. Spectral ratios of Fourier spectral estimates are subject to inaccuracies due to windowing effects, noise, and spectral nulls caused by interfering reflectors. We have found that spectral ratios obtained using continuous wavelet transforms as compared to Fourier ratios are more accurate, less subject to windowing problems, and more robust in the presence of noise

(S)-Perillaldehyde azine

The C=N–N=C linkage [torsion angle −172.5 (2)°] in the title azine, C20H28N2, adopts a trans conformation. The six-membered rings adopt sofa conformations