3,488 research outputs found
The Structure of Barium in the hcp Phase Under High Pressure
Recent experimental results on two hcp phases of barium under high pressure
show interesting variation of the lattice parameters. They are here interpreted
in terms of electronic structure calculation by using the LMTO method and
generalized pseudopotential theory (GPT) with a NFE-TBB approach. In phase II
the dramatic drop in c/a is an instability analogous to that in the group II
metals but with the transfer of s to d electrons playing a crucial role in Ba.
Meanwhile in phase V, the instability decrease a lot due to the core repulsion
at very high pressure. PACS numbers: 62.50+p, 61.66Bi, 71.15.Ap, 71.15Hx,
71.15LaComment: 29 pages, 8 figure
Quantum Particles Constrained on Cylindrical Surfaces with Non-constant Diameter
We present a theoretical formulation of the one-electron problem constrained
on the surface of a cylindrical tubule with varying diameter. Because of the
cylindrical symmetry, we may reduce the problem to a one-dimensional equation
for each angular momentum quantum number along the cylindrical axis. The
geometrical properties of the surface determine the electronic structures
through the geometry dependent term in the equation. Magnetic fields parallel
to the axis can readily be incorporated. Our formulation is applied to simple
examples such as the catenoid and the sinusoidal tubules. The existence of
bound states as well as the band structures, which are induced geometrically,
for these surfaces are shown. To show that the electronic structures can be
altered significantly by applying a magnetic field, Aharonov-Bohm effects in
these examples are demonstrated.Comment: 7 pages, 7 figures, submitted to J. Phys. Soc. Jp
Improvements in Gold Nanorod Biocompatibility with Sodium Dodecyl Sulfate Stabilization
Due to their well-defined plasmonic properties, gold nanorods (GNRs) can be fabricated with optimal light absorption in the near-infrared region of the electromagnetic spectrum, which make them suitable for cancer-related theranostic applications. However, their controversial safety profile, as a result of surfactant stabilization during synthesis, limits their clinical translation. We report a facile method to improve GNR biocompatibility through the presence of sodium dodecyl sulfate (SDS). GNRs (120 × 40 nm) were synthesized through a seed-mediated approach, using cetyltrimethylammonium bromide (CTAB) as a cationic surfactant to direct the growth of nanorods and stabilize the particles. Post-synthesis, SDS was used as an exchange ligand to modify the net surface charge of the particles from positive to negative while maintaining rod stability in an aqueous environment. GNR cytotoxic effects, as well as the mechanisms of their cellular uptake, were examined in two different cancer cell lines, Lewis lung carcinoma (LLC) and HeLa cells. We not only found a significant dose-dependent effect of GNR treatment on cell viability but also a time-dependent effect of GNR surfactant charge on cytotoxicity over the two cell lines. Our results promote a better understanding of how we can mediate the undesired consequences of GNR synthesis byproducts when exposed to a living organism, which so far has limited GNR use in cancer theranostics
Optical interconnect solution with plasmonic modulator and Ge photodetector array
We report on an optical chip-to-chip interconnect solution, thereby demonstrating plasmonics as a solution for ultra-dense, high-speed short-reach communications. The interconnect comprises a densely integrated plasmonic Mach-Zehnder modulator array that is packaged with standard driving electronics. On the receiver side, a germanium photodetector array is integrated with trans-impedance amplifiers. A multicore fiber provides a compact optical interface to the array. We demonstrate 4 × 20 Gb/s on-off keying signaling with direct detection.ISSN:1041-1135ISSN:1941-017
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Neutron Source Strength Estimates from (a, n) Reactions in Binary Mixtures of Actinide Particles and Light Element Particles
The cumulative distribution of package dose rates, based on the 18 batches of historical PuO{sub 2} particle size distributions, is shown in Fig. 6 for ''Hanford 10-13% Pu-240'' plutonium. The calculated dose rates for all batches range from about 50 mrem/h to about 2,200 mrem/h, with over 50% of the batches being less than the 200 mrem/h limit for public transportation. A more refined analysis would show that almost all of the batches would be less than 200 mrem/h, but some could exceed this limit as seen by the distribution shape. Without detailed characterization of the BeO particle size distribution, additional analysis would not remove the uncertainty in these calculations. Because the actual amount of beryllium contamination is likely to be much less than 500 g, the dose rates would be expected to be much lower than those shown here. Based on the particle size distribution analysis of the 18 batches analyzed, it is also likely that most of the 3013 cans to be loaded in the 9975 Package will have dose rates that are less than the 200 mrem/h limit for the package surface. However, extra care will be required in performing, and verifying, the dose rate measurements at the surface of the package, prior to shipment
Non-volatile molecular memory elements based on ambipolar nanotube field effect transistors
We have fabricated air-stable n-type, ambipolar carbon nanotube field effect
transistors (CNFETs), and used them in nanoscale memory cells. N-type
transistors are achieved by annealing of nanotubes in hydrogen gas and
contacting them by cobalt electrodes. Scanning gate microscopy reveals that the
bulk response of these devices is similar to gold-contacted p-CNFETs,
confirming that Schottky barrier formation at the contact interface determines
accessibility of electron and hole transport regimes. The transfer
characteristics and Coulomb Blockade (CB) spectroscopy in ambipolar devices
show strongly enhanced gate coupling, most likely due to reduction of defect
density at the silicon/silicon-dioxide interface during hydrogen anneal. The CB
data in the ``on''-state indicates that these CNFETs are nearly ballistic
conductors at high electrostatic doping. Due to their nanoscale capacitance,
CNFETs are extremely sensitive to presence of individual charge around the
channel. We demonstrate that this property can be harnessed to construct data
storage elements that operate at the few-electron level.Comment: 6 pages text, 3 figures and 1 table of content graphic; available as
NanoLetters ASAP article on the we
Delayed electron emission in strong-field driven tun-nelling from a metallic nanotip in the multi-electronregime
Illuminating a nano-sized metallic tip with ultrashort laser pulses leads to the emission of electrons due to multiphoton excitations. As optical fields become stronger, tunnelling emission directly from the Fermi level becomes prevalent. This can generate coherent electron waves in vacuum leading to a variety of attosecond phenomena. Working at high emission currents where multi-electron effects are significant, we were able to characterize the transition from one regime to the other. Specifically, we found that the onset of laser-driven tunnelling emission is heralded by the appearance of a peculiar delayed emission channel. In this channel, the electrons emitted via laser-driven tunnelling emission are driven back into the metal, and some of the electrons reappear in the vacuum with some delay time after undergoing inelastic scattering and cascading processes inside the metal. Our understanding of these processes gives insights on attosecond tunnelling emission from solids and should prove useful in designing new types of pulsed electron sources.111410Ysciescopu
Using urban climate modelling and improved land use classifications to support climate change adaptation in urban environments: A case study for the city of Klagenfurt, Austria
This study outlines the results of current and future climate scenarios, and potentially realizable climate adaptation measures, for the city of Klagenfurt, Austria. For this purpose, we used the microscale urban climate model (MUKLIMO_3), in conjunction with the cuboid method, to calculate climate indices such as the average number of summer and hot days per year. For the baseline simulation, we used meteorological measurements from 1981 to 2010 from the weather station located at Klagenfurt Airport. Individual building structures and canopy cover from several land monitoring services were used to derive accurate properties for land use classes in the study domain. To characterize the effectiveness of climate adaptation strategies, we compared changes in the climate indices for several (future) climate adaptation scenarios to the reference simulation. Specifically, we considered two major adaptation pathways: (i) an increase in the albedo values of sealed areas (i.e., roofs, walls and streets) and (ii) an increase in green surfaces (i.e., lawns on streets and at roof level) and high vegetated areas (i.e., trees). The results indicate that some climate adaptation measures show higher potential in mitigating hot days than others, varying between reductions of 2.3 to 11.0%. An overall combination of adaptation measures leads to a maximum reduction of up to 44.0%, indicating a clear potential for reduction/mitigation of urban heat loads. Furthermore, the results for the future scenarios reveal the possibility to remain at the current level of urban heat load during the daytime over the next three decades for the overall combination of measures
Apple, condom, and cocaine - Body stuffing in prison: A case report
© 2018 The Author(s). Background: Drug dealers and drug users resort to body stuffing to hastily conceal illicit drugs by ingesting their drug packets. This practice represents a medical challenge because rupture of the often insecure packaging can be toxic and even lethal. In an emergency setting, official guidelines are needed to help the medical team decide on the proper treatment. A preliminary observation period is generally accepted but its duration varies from hours to eventual packet expulsion. Case presentation: This case involves a 20-year-old white man in detention who claimed to have ingested one cocaine packet wrapped in plastic food-wrap and a condom in anticipation of an impending cell search. He reached out to medical professionals on day 4 after having unsuccessfully tried several methods to expel the drug packet, including swallowing olive oil, natural laxatives, liters of water, and 12 carved apple chunks. An initial computed tomography scan confirmed multiple packet-sized images throughout his stomach and bowel. After 24 hours of observation and normal bowel movements without expelling any packets, a subsequent scan found only one air-lined packet afloat in the gastric content. Due to the prolonged retention of the package there was an increased risk of rupture. The packet was eventually removed by laparoscopic gastrotomy. Conclusions: This case report illustrates that observation time needs to be adapted to each individual case of body stuffing. Proof of complete drug package evacuation ensures secure patient discharge. Body stuffers should be routinely asked for a detailed history, including how the drug is wrapped, and whether or not they ingested other substances to help expel the packets. The history enables the accurate interpretation of imaging. Repeated imaging can help follow the progress of packets if not all have been expelled during the observation period. Drug packets should be surgically removed in case of prolonged retention. To ensure the best possible outcomes, patients should have access to high-quality, private, and confidential medical care, which is equal to that offered to the general population. This is paramount to earning trust and collaboration from people in detention who resort to body stuffing
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