Solar electric propulsion for Mars transport vehicles

Solar electric propulsion (SEP) is an alternative to chemical and nuclear powered propulsion systems for both piloted and unpiloted Mars transport vehicles. Photovoltaic solar cell and array technologies were evaluated as components of SEP power systems. Of the systems considered, the SEP power system composed of multijunction solar cells in an ENTECH domed fresnel concentrator array had the least array mass and area. Trip times to Mars optimized for minimum propellant mass were calculated. Additionally, a preliminary vehicle concept was designed

Outer jet X-ray and radio emission in R Aquarii: 1999.8 to 2004.0

Chandra and VLA observations of the symbiotic star R Aqr in 2004 reveal significant changes over the three to four year interval between these observations and previous observations taken with the VLA in 1999 and with Chandra in 2000. This paper reports on the evolution of the outer thermal X-ray lobe-jets and radio jets. The emission from the outer X-ray lobe-jets lies farther away from the central binary than the outer radio jets, and comes from material interpreted as being shock heated to ~10^6 K, a likely result of collision between high speed material ejected from the central binary and regions of enhanced gas density. Between 2000 and 2004, the Northeast (NE) outer X-ray lobe-jet moved out away from the central binary, with an apparent projected motion of ~580 km s^-1. The Southwest (SW) outer X-ray lobe-jet almost disappeared between 2000 and 2004, presumably due to adiabatic expansion and cooling. The NE radio bright spot also moved away from the central binary between 2000 and 2004, but with a smaller apparent velocity than of the NE X-ray bright spot. The SW outer lobe-jet was not detected in the radio in either 1999 or 2004. The density and mass of the X-ray emitting material is estimated. Cooling times, shock speeds, pressure and confinement are discussed.Comment: 23 pages, 8 figure

Production and characterization of monoclonal antibodies raised against recombinant human granzymes A and B and showing cross reactions with the natural proteins

The human serine proteases granzymes A and B are expressed in cytotoplasmic granules of activated cytotoxic T lymphocytes and natural killer cells. Recombinant granzyme A and granzyme B proteins were produced in bacteria, purified and then used to raise specific mouse monoclonal antibodies. Seven monoclonal antibodies (mAb) were raised against granzyme A, which all recognized the same or overlapping epitopes. They reacted specifically in an immunoblot of interleukin-2 (IL-2) stimulated PBMNC with a disulfide-linked homodimer of 43 kDa consisting of 28 kDa subunits. Seven mAb against granzyme B were obtained, which could be divided into two groups, each recognizing a different epitope. On an immunoblot, all mAb reacted with a monomer of 33 kDa protein. By immunohistochemistry, these mAb could be used to detect granzymes A and B expression in activated CTL and NK cells. The availability of these mAb may facilitate studies on the role of human cytotoxic cells in various immune reactions and may contribute to a better understanding of the role of granzmes A and B in the cytotoxic response in vivo

Engineering Catalyst Layers for Next-Generation Polymer Electrolyte Fuel Cells: A Review of Design, Materials, and Methods

Polymer electrolyte fuel cells (PEFCs) are a promising replacement for the fossil fuel–dependent automotive and energy sectors. They have become increasingly commercialized in the last decade; however, significant limitations on durability and performance limit their commercial uptake. Catalyst layer (CL) design is commonly reported to impact device power density and durability; although, a consensus is rarely reached due to differences in testing conditions, experimental design, and types of data reported. This is further exacerbated by aspects of CL design such as catalyst support, proton conduction, catalyst, fabrication, and morphology, being significantly interdependent; hence, a wider appreciation is required in order to optimize performance, improve durability, and reduce costs. Here, the cutting-edge research within the field of PEFCs is reviewed, investigating the effect of different manufacturing techniques, electrolyte distribution, support materials, surface chemistries, and total porosity on power density and durability. These are critically appraised from an applied perspective to inform the most relevant and promising pathways to make and test commercially viable cells. This holistic view of the competing aspects of CL design and preparation will facilitate the development of optimized CLs, especially the incorporation of novel catalyst support materials

Neutron studies of Na-ion battery materials

The relative vast abundance and more equitable global distribution of terrestrial sodium makes sodium-ion batteries (NIBs) potentially cheaper and more sustainable alternatives to commercial lithium-ion batteries (LIBs). However, the practical capacities and cycle lives of NIBs at present do not match those of LIBs and have therefore hindered their progress to commercialisation. The present drawback of NIB technology stems largely from the electrode materials and their associated Na+ion storage mechanisms. Increased understanding of the electrochemical storage mechanisms and kinetics is therefore vital for the development of current and novel materials to realise the commercial NIB. In contrast to x-ray techniques, the non-dependency of neutron scattering on the atomic number of elements (Z) can substantially increase the scattering contrast of small elements such as sodium and carbon, making neutron techniques powerful for the investigation of NIB electrode materials. Moreover, neutrons are far more penetrating which enables more complex sample environments including in situ and operando studies. Here, we introduce the theory of, and review the use of, neutron diffraction and quasi-elastic neutron scattering, to investigate the structural and dynamic properties of electrode and electrolyte materials for NIBs. To improve our understanding of the actual sodium storage mechanisms and identify intermediate stages during charge/discharge, ex situ, in situ, and operando neutron experiments are required. However, to date there are few studies where operando experiments are conducted during electrochemical cycling. This highlights an opportunity for research to elucidate the operating mechanisms within NIB materials that are under much debate at present

Research on the thermal decomposition of Mongolian Baganuur lignite and Naryn sukhait bituminous coal

The technical characteristics, elemental composition of the organic and mineral matters, ash melting behaviors and carbonization and gasification reactivities of coals from Baganuur and Naryn sukhait deposits were investigated. The results of proximate and ultimate analysis confirmed that the coal from Baganuur deposit can be graded as a low rank lignite B2 mark coal and Naryn sukhait coal is a bituminous G mark one. The carbonization and gasification experiments were performed using TGA apparatus and fixed bed quartz reactor. The data obtained with two experimental reactors showed that Baganuur lignite had lower thermal stability and much higher CO2 gasification reactivity at 950°C as compared to those for Naryn sukhait bituminous coal.Mongolian Journal of Chemistry 16 (42), 2015, 22-2

Neutron studies of Na-ion battery materials

The relative vast abundance and more equitable global distribution of terrestrial sodium makes sodium-ion batteries (NIBs) potentially cheaper and more sustainable alternatives to commercial lithium-ion batteries (LIBs). However, the practical capacities and cycle lives of NIBs at present do not match those of LIBs and have therefore hindered their progress to commercialisation. The present drawback of NIB technology stems largely from the electrode materials and their associated Na+ion storage mechanisms. Increased understanding of the electrochemical storage mechanisms and kinetics is therefore vital for the development of current and novel materials to realise the commercial NIB. In contrast to x-ray techniques, the non-dependency of neutron scattering on the atomic number of elements (Z) can substantially increase the scattering contrast of small elements such as sodium and carbon, making neutron techniques powerful for the investigation of NIB electrode materials. Moreover, neutrons are far more penetrating which enables more complex sample environments including in situ and operando studies. Here, we introduce the theory of, and review the use of, neutron diffraction and quasi-elastic neutron scattering, to investigate the structural and dynamic properties of electrode and electrolyte materials for NIBs. To improve our understanding of the actual sodium storage mechanisms and identify intermediate stages during charge/discharge, ex situ, in situ, and operando neutron experiments are required. However, to date there are few studies where operando experiments are conducted during electrochemical cycling. This highlights an opportunity for research to elucidate the operating mechanisms within NIB materials that are under much debate at present

An Analytical and Numerical Study of Optimal Channel Networks

We analyze the Optimal Channel Network model for river networks using both analytical and numerical approaches. This is a lattice model in which a functional describing the dissipated energy is introduced and minimized in order to find the optimal configurations. The fractal character of river networks is reflected in the power law behaviour of various quantities characterising the morphology of the basin. In the context of a finite size scaling Ansatz, the exponents describing the power law behaviour are calculated exactly and show mean field behaviour, except for two limiting values of a parameter characterizing the dissipated energy, for which the system belongs to different universality classes. Two modified versions of the model, incorporating quenched disorder are considered: the first simulates heterogeneities in the local properties of the soil, the second considers the effects of a non-uniform rainfall. In the region of mean field behaviour, the model is shown to be robust to both kinds of perturbations. In the two limiting cases the random rainfall is still irrelevant, whereas the heterogeneity in the soil properties leads to new universality classes. Results of a numerical analysis of the model are reported that confirm and complement the theoretical analysis of the global minimum. The statistics of the local minima are found to more strongly resemble observational data on real rivers.Comment: 27 pages, ps-file, 11 Postscript figure