Development of sustainable biodegradable lignocellulosic hemp fiber/polycaprolactone biocomposites for light weight applications

Biocomposites with poly(ε-caprolactone) (PCL) as matrix and lignocellulosic hemp fiber with varying average aspect ratios (19, 26, 30 and 38) as reinforcement were prepared using twin extrusion process. The influence of fiber aspect ratio on the water absorption behavior and mechanical properties are investigated. The percentage of moisture uptake increased with the aspect ratio, following Fickian behavior. The hemp fiber/PCL biocomposites showed enhanced properties (tensile, flexural and low-velocity impact). The biocomposite with 26 aspect ratio showed the optimal properties, with flexural strength and modulus of 169% and 285% respectively, higher than those of neat PCL. However, a clear reduction on the mechanical properties was observed for water-immersed samples, with reduction in tensile and flexural moduli for the aspect ratio of 26 by 90% and 62%, respectively than those of dry samples. Summarily, the optimal sample provides an eco-friendly alternative to conventional, petroleum-based and non-renewable composites for various applications.Peer reviewedFinal Accepted Versio

A new analytical critical thrust force model for delamination analysis of laminated composites during drilling operation

Fibre reinforced polymer (FRP) composite laminates are employed in many industrial applications due to their attractive mechanical and structural properties. Machining operation, such as drilling of FRP laminates, plays a significant role in the assembly of parts in aircraft and spacecraft production. Among other production bottlenecks, drilling-induced delamination remains a major defect which adversely affects the quality of assembly parts. An efficient strategy in preventing this problem is the calculation of the critical thrust force above which delamination is initiated. Therefore, in this study, a new analytical model is proposed to predict the critical thrust force for delamination. Unlike the general models in the literature which derived only mode I strain energy release rate based on the assumption of classical laminate plate theory (CLPT) combined with linear elastic fracture mechanics (LEFM) mode I considerations in the elliptic delamination zone, the proposed analytical model is derived based on first-order shear deformation theory (FSDT) and accounts for mode I and mode II strain energy release rates in the delamination zone. This strategy allows to activate mixed mode criteria for delamination initiation which is a valid assumption for laminates with layers of different orientations. The present model is partly derived for general laminates subject to distributed loading and further extended to cross-ply laminate sequence subject to a mixed load condition. The results show that the effect of shear deformation in the prediction of the critical thrust force is influential with increasing ply thickness and the effect of chisel edge on shear deformation is more profound in the distributed load regime

Abrasive water jet drilling of advanced sustainable bio-fibre-reinforced polymer/hybrid composites : a comprehensive analysis of machining-induced damage responses

This paper aims at investigating the effects of variable traverse speeds on machining-induced damage of fibre-reinforced composites, using the abrasive water jet (AWJ) drilling. Three different types of epoxy-based composites laminates fabricated by vacuum bagging technique containing unidirectional (UD) flax, hybrid carbon-flax and carbon fibre-reinforced composite were used. The drilling parameters used were traverse speeds of 20, 40, 60 and 80 mm/min, constant water jet pressure of 300 MPa and a hole diameter of 10 mm. The results obtained depict that the traverse speed had a significant effect with respect to both surface roughness and delamination drilling-induced damage responses. Evidently, an increase in water jet traverse speed caused an increase in both damage responses of the three samples. Significantly, the CFRP composite sample recorded the lowest surface roughness damage response, followed by C-FFRP, while FFRP exhibited the highest. However, samples of FFRP and hybrid C-FFRP recorded lowest and highest delamination damage responses, respectively. The discrepancy in both damage responses, as further validated with micrographs of colour video microscopy (CVM), scanning electron microscopy (SEM) and X-ray micro-computed tomography (X-ray μCT), is attributed to the different mechanical properties of the reinforced fibres, fibre orientation/ply stacking and hybridisation of the samples.Peer reviewe

Inorganic Fillers and Their Effects on the Properties of Flax/PLA Composites after UV Degradation

Data Availability Statement: The data that support the findings of this study are available on request from the corresponding author.Copyright © 2023 by the authors. The present investigation seeks to assess the impact of fillers on the mechanical characteristics of entirely biodegradable composites, introducing an advanced solution to fulfil long-term durability demands within point-of-purchase (POP) industries. The inclusion of calcium carbonate (CaCO3) fillers on the various properties of the flax fibre-reinforced composites, after accelerated irradiation in an ultraviolet (UV) radiation exposure has been investigated in the present study. Different types of flax fibre-reinforced poly lactic acid (PLA) biocomposites (with and without filler) were fabricated. The mechanical (tensile and flexural), and physical properties of the specimens were assessed after 500 h of exposure to accelerated UV irradiation of 0.48 W/m2 at 50 °C and were compared with those of the unexposed specimens. The results indicate that the presence of the inorganic filler significantly improved the performance of the biocomposites compared to the unfilled biocomposites after UV exposure. After adding 20% of fillers, the tensile strength was increased by 2% after UV degradation, whereas the biocomposite without filler lost 18% of its strength after UV exposure. This can be attributed to the change in the photo-degradation of the PLA due to the presence of the CaCO3 filler, which acts as a safeguard against UV light penetration by creating a protective barrier. The scanning electron microscopy (SEM) images of the degraded specimen surface show substantial difference in the surface topography of the composites with and without fillers.INTERREG VA Program, FLOWER project, grant number 23

Influence of halloysite nanotubes on physical and mechanical properties of cellulose fibres reinforced vinyl ester composites

Natural fibres are generally added to polymer matrix composites to produce materials with the desirable mechanical properties of higher specific strength and higher specific modulus while at the same time to maintain a low density and low cost. The physical and mechanical properties of polymer composites can be enhanced through the addition of nanofillers such as halloysite nanotubes. This article describes the fabrication of vinyl ester eco-composites and eco-nanocomposites and characterizes these samples in terms of water absorption, mechanical and thermal properties. Weight gain test and Fourier transform infrared analysis indicated that 5% halloysite nanotube addition gave favourable reduction in the water absorption and increased the fibre–matrix adhesion leading to improved strength properties in the eco-nanocomposites. However, halloysite nanotube addition resulted in reduced toughness but improved thermal stability

Mechanical properties of cotton fabric reinforced geopolymer composites at 200-1000 °C

Geopolymer composites containing woven cotton fabric (0–8.3 wt%) were fabricated using the hand lay-up technique, and were exposed to elevated temperatures of 200 °C, 400 °C, 600 °C, 800 °C and 1000 °C. With an increase in temperature, the geopolymer composites exhibited a reduction in compressive strength, flexural strength and fracture toughness. When heated above 600 °C, the composites exhibited a significant reduction in mechanical properties. They also exhibited brittle behavior due to severe degradation of cotton fibres and the creation of additional porosity in the composites. Microstructural images verified the existence of voids and small channels in the composites due to fibre degradation

Property changes in plant fibres during the processing of bio-based composites

Over the past decades, the use of plant fibre reinforced composites has increased significantly due to their many attractive attributes such as high specific strength and modulus, wide availability, low cost and high environmental credibility compared to their synthetic counterparts. These attributes are especially attractive for lightweight applications in automotive, marine, aerospace and sporting goods sectors. This growth is expected to continue in the future. To improve the design and performance of bio-based composites, an improved understanding of processing-structure-property relations in such bio-based composites is required, the fibres being the key component of the composite to obtain performing properties. This is due to the sensitivity of the constituent plant fibres to mechanical stress (pressure), temperature, water and other parameters. The purpose of this review is to critically synthesise literature on the impact of composites processing steps on plant fibre cell wall structure and properties. The impact of plant fibre composites processing steps from the polymer impregnation stage right through to the end-of-life recycling stage is reviewed. Additionally, mechanical, morphological and hygroscopic properties of plant fibres are considered in conjunction with process times, temperature and shear rate. This review will aid process and product designers to develop new performing plant fibre composite products, taking into account the process parameters to select the most optimised process and (their effects on) plant fibres. Considering how fibre properties change with biocomposites processing steps is indeed essential to understanding the links between the micro and macro scales, and to be able to design optimised plant fibre composite materials.The authors thank the INTERREG IV Cross Channel programme for funding this work through the FLOWER projec