Catalytic microwave pyrolysis of waste engine oil using metallic pyrolysis char

Microwave pyrolysis was performed on waste engine oil pre-mixed with different amounts of metallic-char catalyst produced previously from a similar microwave pyrolysis process. The metallic-char catalyst was first prepared by pretreatment with calcination followed by analyses to determine its various properties. The heating characteristics of the mixture of waste oil and metallic-char during the pyrolysis were investigated, and the catalytic influence of the metallic-char on the yield and characteristics of the pyrolysis products are discussed with emphasis on the composition of oil and gaseous products. The metallic-char, detected to have a porous structure and high surface area (124 m2/g), showed high thermal stability in a N2 atmosphere and it was also found to have phases of metals and metal oxides attached or adsorbed onto the char, representing a potentially suitable catalyst to be used in pyrolysis cracking process. The metallic-char initially acted as an adsorptive-support to adsorb metals, metal oxides and waste oil. Then, the char became a microwave absorbent that absorbed microwave energy and heated up to a high temperature in a short time and it was found to generate arcing and sparks during microwave pyrolysis of the waste oil, resulting in the formation of hot spots (high temperature sites with temperature up to 650 °C) within the reactor under the influence of microwave heating. The presence of this high temperature metallic-char, the amounts of which are likely to increase when increasing amounts of metallic-char were added to the waste oil (5, 10, and 20 wt% of the amount of waste oil added to the reactor), had provided a reducing chemical environment in which the metallic-char acted as an intermediate reductant to reduce the adsorbed metals or metal oxides into metallic states, which then functioned as a catalyst to provide more reaction sites that enhanced the cracking and heterogeneous reactions that occurred during the pyrolysis to convert the waste oil to produce higher yields of light hydrocarbons, H2 and CO gases in the pyrolysis products, recording a yield of up to 74 wt% of light C5–C10 hydrocarbons and 42 vol% of H2 and CO gases. The catalytic microwave pyrolysis produced 65–85 wt% yield of pyrolysis-oil containing C5–C20 hydrocarbons that can potentially be upgraded to produce transport-grade fuels. In addition, the recovered pyrolysis-gases (up to 33 wt%) were dominated by aliphatic hydrocarbons (up to 78 vol% of C1–C6 hydrocarbons) and significant amounts of valuable syngas (up to 42 vol% of H2 and CO in total) with low heating values (LHV) ranging from 4.7 to 5.5 MJ/m3, indicating that the pyrolysis-gases could also be used as a gaseous fuel or upgraded to produce more hydrogen as a second-generation fuel. The results indicate that the metallic-char shows advantages for use as a catalyst in microwave pyrolysis treatment of problematic waste oils. [Graphical abstract - see article]The authors acknowledges the financial support by the Ministry of Science, Technology, and Innovation Malaysia (MOSTI), Ministry of Higher Education Malaysia (MOHE), and University Malaysia Terengganu for the conduct of the research under the E-Science fund (UMT/RMC/SF/13/52072(5), Vot No: 52072), the Fundamental Research Grant Scheme (Project No: FRGS/1/2013/TK05/UMT/02/2, Vot No: 59296), and the Research Acculturation Grant Scheme (Project No: RAGS/2012/UMT/TK07/3, Vot No: 57085).This is the author accepted manuscript. The final version is available from [publisher] via http://dx.doi.org/10.1016/j.apcatb.2015.04.01

Universal Loss Dynamics in a Unitary Bose Gas

The low temperature unitary Bose gas is a fundamental paradigm in few-body and many-body physics, attracting wide theoretical and experimental interest. Here we first present a theoretical model that describes the dynamic competition between two-body evaporation and three-body re-combination in a harmonically trapped unitary atomic gas above the condensation temperature. We identify a universal magic trap depth where, within some parameter range, evaporative cooling is balanced by recombination heating and the gas temperature stays constant. Our model is developed for the usual three-dimensional evaporation regime as well as the 2D evaporation case. Experiments performed with unitary 133 Cs and 7 Li atoms fully support our predictions and enable quantitative measurements of the 3-body recombination rate in the low temperature domain. In particular, we measure for the first time the Efimov inelasticity parameter $\eta$ * = 0.098(7) for the 47.8-G d-wave Feshbach resonance in 133 Cs. Combined 133 Cs and 7 Li experimental data allow investigations of loss dynamics over two orders of magnitude in temperature and four orders of magnitude in three-body loss. We confirm the 1/T 2 temperature universality law up to the constant $\eta$ *

Size dependent line broadening in the emission spectra of single GaAs quantum dots: Impact of surface charges on spectral diffusion

Making use of droplet epitaxy, we systematically controlled the height of self-assembled GaAs quantum dots by more than one order of magnitude. The photoluminescence spectra of single quantum dots revealed the strong dependence of the spectral linewidth on the dot height. Tall dots with a height of ~30 nm showed broad spectral peaks with an average width as large as ~5 meV, but shallow dots with a height of ~2 nm showed resolution-limited spectral lines (<120 micro eV). The measured height dependence of the linewidths is in good agreement with Stark coefficients calculated for the experimental shape variation. We attribute the microscopic source of fluctuating electric fields to the random motion of surface charges at the vacuum-semiconductor interface. Our results offer guidelines for creating frequency-locked photon sources, which will serve as key devices for long-distance quantum key distribution.Comment: 6 pages, 6 figures; updated figs and their description