3,360 research outputs found
Predicted Abundances of Carbon Compounds in Volcanic Gases on Io
We use chemical equilibrium calculations to model the speciation of carbon in
volcanic gases on Io. The calculations cover wide temperature (500-2000 K),
pressure (10^-8 to 10^+2 bars), and composition ranges (bulk O/S atomic ratios
\~0 to 3), which overlap the nominal conditions at Pele (1760 K, 0.01 bar, O/S
~ 1.5). Bulk C/S atomic ratios ranging from 10^-6 to 10^-1 in volcanic gases
are used with a nominal value of 10^-3 based upon upper limits from Voyager for
carbon in the Loki plume on Io. Carbon monoxide and CO2 are the two major
carbon gases under all conditions studied. Carbonyl sulfide and CS2 are orders
of magnitude less abundant. Consideration of different loss processes
(photolysis, condensation, kinetic reactions in the plume) indicates that
photolysis is probably the major loss process for all gases. Both CO and CO2
should be observable in volcanic plumes and in Io's atmosphere at abundances of
several hundred parts per million by volume for a bulk C/S ratio of 10^-3.Comment: 21 pages, 4 figures, 4 tables; accepted by Astrophysical Journa
Development of portable NMR polarimeter system for polarized HD target
A portable NMR polarimeter system has been developed to measure the
polarization of a polarized Hydrogen-Deuteride (HD) target for hadron
photoproduction experiments at SPring-8. The polarized HD target is produced at
the Research Center for Nuclear Physics (RCNP), Osaka university and is
transported to SPring-8. The HD polarization should be monitored at both
places. We have constructed the portable NMR polarimeter system by replacing
the devices in the conventional system with the software system with PCI
eXtensions for Instrumentation (PXI). The weight of the NMR system is downsized
from 80 kg to 7 kg, and the cost is reduced to 25%. We check the performance of
the portable NMR polarimeter system. The signal-to-noise (S/N) ratio of the NMR
signal for the portable system is about 50% of that for the conventional NMR
system. This performance of the portable NMR system is proved to be compatible
with the conventional NMR system for the polarization measurement.Comment: 6 page, 8 figures, 2011/Mar/9 Replace Author
Magnetic and transport studies of pure V_2O_3 under pressure
We report a systematic study of the resistivity and magnetic susceptibility of pure V_2O_3, the original Mott-Hubbard system at half filling, for pressures 0≤P≤25 kbar and temperatures 0.35≤T≤300 K. We also study (V_(0.99)Ti_(0.01)_2O_3 under pressure in order to elucidate the role of disorder on a metal-insulator transition in the highly correlated limit. Despite the low level of doping, we find that the two systems are very different. We observe a conventional collapsing of the Mott-Hubbard gap only for stoichiometric V_2_O3; the Ti disorder stabilizes the long-range antiferromagnetic order and a magnetic Slater gap. Moreover, we discover different P-T phase diagrams for the two systems, with a decoupling of the charge and spin degrees of freedom at the approach to the T=0, pressure-driven metal-insulator transition in pure V_2O_3
Brillouin scattering studies in FeO across the Verwey transition
Brillouin scattering studies have been carried out on high quality single
crystals of FeO with [100] and [110] faces in the temperature range of
300 to 30 K. The room temperature spectrum shows a surface Rayleigh wave (SRW)
mode at 8 GHz and a longitudinal acoustic (LA) mode at 60 GHz. The SRW mode
frequency shows a minimum at the Verwey transition temperature of 123 K.
The softening of the SRW mode frequency from about 250 K to can be
quantitatively understood as a result of a decrease in the shear elastic
constant C, arising from the coupling of shear strain to charge
fluctuations. On the other hand, the LA mode frequency does not show any
significant change around , but shows a large change in its intensity. The
latter shows a maximum at around 120 K in the cooling run and at 165 K in the
heating run, exhibiting a large hysteresis of 45 K. This significant change in
intensity may be related to the presence of stress-induced ordering of
Fe and Fe at the octahedral sites, as well as to stress-induced
domain wall motion.Comment: 14 pages, 3 figures, accepted in Physical Review B 200
Origin of atomic clusters during ion sputtering
Previous studies have shown that the size distributions of small clusters ( n<=40 n = number of atoms/cluster) generated by sputtering obey an inverse power law with an exponent between -8 and -4. Here we report electron microscopy studies of the size distributions of larger clusters ( n>=500) sputtered by high-energy ion impacts. These new measurements also yield an inverse power law, but one with an exponent of -2 and one independent of sputtering yield, indicating that the large clusters are produced when shock waves, generated by subsurface displacement cascades, ablate the surface
Optical Conductivity in Mott-Hubbard Systems
We study the transfer of spectral weight in the optical spectra of a strongly
correlated electron system as a function of temperature and interaction
strength. Within a dynamical mean field theory of the Hubbard model that
becomes exact in the limit of large lattice coordination, we predict an
anomalous enhancement of spectral weight as a function of temperature in the
correlated metallic state and report on experimental measurements which agree
with this prediction in . We argue that the optical conductivity
anomalies in the metal are connected to the proximity to a crossover region in
the phase diagram of the model.Comment: 12 pages and 4 figures, to appear in Phys. Rev. Lett., v 75, p 105
(1995
Measurements of polarized photo-pion production on longitudinally polarized HD and Implications for Convergence of the GDH Integral
We report new measurements of inclusive pion production from frozen-spin HD
for polarized photon beams covering the Delta(1232) resonance. These provide
data simultaneously on both H and D with nearly complete angular distributions
of the spin-difference cross sections entering the Gerasimov-Drell-Hearn (GDH)
sum rule. Recent results from Mainz and Bonn exceed the GDH prediction for the
proton by 22 microbarns, suggesting as yet unmeasured high-energy components.
Our pi0 data reveal a different angular dependence than assumed in Mainz
analyses and integrate to a value that is 18 microbarns lower, suggesting a
more rapid convergence. Our results for deuterium are somewhat lower than
published data, considerably more precise and generally lower than available
calculations.Comment: 4 pages, 4 figures. Submitted for publication in Physical Review
Letter
A large geometric distortion in the first photointermediate of rhodopsin, determined by double-quantum solid-state NMR
Double-quantum magic-angle-spinning NMR experiments were performed on 11,12-C-13(2)-retinylidene-rhodopsin under illumination at low temperature, in order to characterize torsional angle changes at the C11-C12 photoisomerization site. The sample was illuminated in the NMR rotor at low temperature (similar to 120 K) in order to trap the primary photointermediate, bathorhodopsin. The NMR data are consistent with a strong torsional twist of the HCCH moiety at the isomerization site. Although the HCCH torsional twist was determined to be at least 40A degrees, it was not possible to quantify it more closely. The presence of a strong twist is in agreement with previous Raman observations. The energetic implications of this geometric distortion are discussed
Like-charge attraction through hydrodynamic interaction
We demonstrate that the attractive interaction measured between like-charged
colloidal spheres near a wall can be accounted for by a nonequilibrium
hydrodynamic effect. We present both analytical results and Brownian dynamics
simulations which quantitatively capture the one-wall experiments of Larsen and
Grier (Nature 385, p. 230, 1997).Comment: 10 pages, 4 figure
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