2,044 research outputs found
Internal Energy of the Potts model on the Triangular Lattice with Two- and Three-body Interactions
We calculate the internal energy of the Potts model on the triangular lattice
with two- and three-body interactions at the transition point satisfying
certain conditions for coupling constants. The method is a duality
transformation. Therefore we have to make assumptions on uniqueness of the
transition point and that the transition is of second order. These assumptions
have been verified to hold by numerical simulations for q=2, 3 and 4, and our
results for the internal energy are expected to be exact in these cases.Comment: 9 pages, 4 figure
What do emulsification failure and Bose-Einstein condensation have in common?
Ideal bosons and classical ring polymers formed via self-assembly, are known
to have the same partition function, and so analogous phase transitions. In
ring polymers, the analogue of Bose-Einstein condensation occurs when a ring
polymer of macroscopic size appears. We show that a transition of the same
general form occurs within a whole class of systems with self-assembly, and
illustrate it with the emulsification failure of a microemulsion phase of
water, oil and surfactant. As with Bose-Einstein condensation, the transition
occurs even in the absence of interactions.Comment: 7 pages, 1 figure, typeset with EUROTeX, uses epsfi
Hodge Theory on Metric Spaces
Hodge theory is a beautiful synthesis of geometry, topology, and analysis,
which has been developed in the setting of Riemannian manifolds. On the other
hand, spaces of images, which are important in the mathematical foundations of
vision and pattern recognition, do not fit this framework. This motivates us to
develop a version of Hodge theory on metric spaces with a probability measure.
We believe that this constitutes a step towards understanding the geometry of
vision.
The appendix by Anthony Baker provides a separable, compact metric space with
infinite dimensional \alpha-scale homology.Comment: appendix by Anthony W. Baker, 48 pages, AMS-LaTeX. v2: final version,
to appear in Foundations of Computational Mathematics. Minor changes and
addition
Abrupt grain boundary melting in ice
The effect of impurities on the grain boundary melting of ice is investigated
through an extension of Derjaguin-Landau-Verwey-Overbeek theory, in which we
include retarded potential effects in a calculation of the full frequency
dependent van der Waals and Coulombic interactions within a grain boundary. At
high dopant concentrations the classical solutal effect dominates the melting
behavior. However, depending on the amount of impurity and the surface charge
density, as temperature decreases, the attractive tail of the dispersion force
interaction begins to compete effectively with the repulsive screened Coulomb
interaction. This leads to a film-thickness/temperature curve that changes
depending on the relative strengths of these interactions and exhibits a
decrease in the film thickness with increasing impurity level. More striking is
the fact that at very large film thicknesses, the repulsive Coulomb interaction
can be effectively screened leading to an abrupt reduction to zero film
thickness.Comment: 8 pages, 1 figur
Some comments on developments in exact solutions in statistical mechanics since 1944
Lars Onsager and Bruria Kaufman calculated the partition function of the
Ising model exactly in 1944 and 1949. Since then there have been many
developments in the exact solution of similar, but usually more complicated,
models. Here I shall mention a few, and show how some of the latest work seems
to be returning once again to the properties observed by Onsager and Kaufman.Comment: 28 pages, 5 figures, section on six-vertex model revise
Monte Carlo Study of an Extended 3-State Potts Model on the Triangular Lattice
By introducing a chiral term into the Hamiltonian of the 3-state Potts model
on a triangular lattice additional symmetries are achieved between the
clockwise and anticlockwise states and the ferromagnetic state. This model is
investigated using Monte Carlo methods. We investigate the full phase diagram
and find evidence for a line tricritical points separating the ferromagnetic
and antiferromagnetic phases.Comment: 6 pages, 10 figure
Segmental relaxation in semicrystalline polymers: a mean field model for the distribution of relaxation times in confined regimes
The effect of confinement in the segmental relaxation of polymers is
considered. On the basis of a thermodynamic model we discuss the emerging
relevance of the fast degrees of freedom in stimulating the much slower
segmental relaxation, as an effect of the constraints at the walls of the
amorphous regions. In the case that confinement is due to the presence of
crystalline domains, a quasi-poissonian distribution of local constraining
conditions is derived as a result of thermodynamic equilibrium. This implies
that the average free energy barrier for conformational
rearrangement is of the same order of the dispersion of the barrier heights,
, around . As an example, we apply the results to
the analysis of the -relaxation as observed by dielectric broad band
spectroscopy in semicrystalline poly(ethylene terephthalate) cold-crystallized
from either an isotropic or an oriented glass. It is found that in the latter
case the regions of cooperative rearrangement are significantly larger than in
the former.Comment: 10 pages, 4 figures .ep
Renormalisation group determination of the order of the DNA denaturation transition
We report on the nature of the thermal denaturation transition of homogeneous
DNA as determined from a renormalisation group analysis of the
Peyrard-Bishop-Dauxois model. Our approach is based on an analogy with the
phenomenon of critical wetting that goes further than previous qualitative
comparisons, and shows that the transition is continuous for the average
base-pair separation. However, since the range of universal critical behaviour
appears to be very narrow, numerically observed denaturation transitions may
look first-order, as it has been reported in the literature.Comment: 6 pages; no figures; to appear in Europhysics Letter
Frustration and Melting of Colloidal Molecular Crystals
Using numerical simulations we show that a variety of novel colloidal
crystalline states and multi-step melting phenomena occur on square and
triangular two-dimensional periodic substrates. At half-integer fillings
different kinds of frustration effects can be realized. A two-step melting
transition can occur in which individual colloidal molecules initially rotate,
destroying the overall orientational order, followed by the onset of interwell
colloidal hopping, in good agreement with recent experiments.Comment: 6 pages, 3 postscript figures. Procedings of International Conference
on Strongly Coupled Coulomb Systems, Santa Fe, 200
Single vibronic level emission spectroscopic studies of the ground state energy levels and molecular structures of jet-cooled HGeBr, DGeBr, HGeI, and DGeI
Single vibronic level dispersed fluorescence spectra of jet-cooled HGeBr, DGeBr, HGeI, and DGeI have been obtained by laser excitation of selected bands of the à A″1-X̃ A′1 electronic transition. The measured ground state vibrational intervals were assigned and fitted to anharmonicity expressions, which allowed the harmonic frequencies to be determined for both isotopomers. In some cases, lack of a suitable range of emission data necessitated that some of the anharmonicity constants and vibrational frequencies be estimated from those of HGeCl∕DGeCl and the corresponding silylenes (HSiX). Harmonic force fields were obtained for both molecules, although only four of the six force constants could be determined. The ground state effective rotational constants and force field data were combined to calculate average (rz) and approximate equilibrium (rze) structures. For HGeBr rze(GeH)=1.593(9)Å, rze(GeBr)=2.325(21)Å, and the bond angle was fixed at our CCSD(T)/aug-cc-pVTZ ab initio value of 93.6°. For HGeI we obtained rze(GeH)=1.589(1)Å, rze(GeI)=2.525(5)Å, and bond angle=93.2°. Franck-Condon simulations of the emission spectra using ab initio Cartesian displacement coordinates reproduce the observed intensity distributions satisfactorily. The trends in structural parameters in the halogermylenes and halosilylenes can be readily understood based on the electronegativity of the halogen substituent. ACKNOWLEDGMENT
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