1,389 research outputs found

    Shaking Table Tests on Transient Flow of Liquefied Ground

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    An attempt was made to predict the time history of the lateral displacement of ground that liquefied due to earthquakes. The study was initiated by model tests to examine the nature of liquefied sand. The knowledge thus obtained was combined with the theory of Lagrangean equation of motion in order to develop a method of prediction. Comparison was then made between prediction and observation

    A box model study on photochemical interactions between VOCs and reactive halogen species in the marine boundary layer

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    International audienceA new chemical scheme is developed for the multiphase photochemical box model SEAMAC (size-SEgregated Aerosol model for Marine Air Chemistry) to investigate photochemical interactions between volatile organic compounds (VOCs) and reactive halogen species in the marine boundary layer (MBL). Based primarily on critically evaluated kinetic and photochemical rate parameters as well as a protocol for chemical mechanism development, the new scheme has achieved a near-explicit description of oxidative degradation of up to C3-hydrocarbons (CH4, C2H6, C3H8, C2H4, C3H6, and C2H2) initiated by reactions with OH radicals, Cl- and Br-atoms, and O3. Rate constants and product yields for reactions involving halogen species are taken from the literature where available, but the majority of them need to be estimated. In particular, addition reactions of halogen atoms with alkenes will result in forming halogenated organic intermediates, whose photochemical loss rates are carefully evaluated in the present work. Model calculations with the new chemical scheme reveal that the oceanic emissions of acetaldehyde (CH3CHO) and alkenes (especially C3H6) are important factors for regulating reactive halogen chemistry in the MBL by promoting the conversion of Br atoms into HBr or more stable brominated intermediates in the organic form. The latter include brominated hydroperoxides, bromoacetaldehyde, and bromoacetone, which sequester bromine from a reactive inorganic pool. The total mixing ratio of brominated organic species thus produced is likely to reach 10-20% or more of that of inorganic gaseous bromine species over wide regions over the ocean. The reaction between Br atoms and C2H2 is shown to be unimportant for determining the degree of bromine activation in the remote MBL. These results imply that reactive halogen chemistry can mediate a link between the oceanic emissions of VOCs and the behaviors of compounds that are sensitive to halogen chemistry such as dimethyl sulfide, NOx, and O3 in the MBL

    Low Temperature Ground States and Field-Induced Phase Transitions in α-(BEDT-TTF)_2-MHg(XCN)_4 (M=K, Tl, Rb, NH_4; X=S, Se) (Research in High Magnetic Fields)

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    There have been observed in a series of isostructural α-(BEDT-TTF)_2MHg(XCN)_4\u27s a variety of ground states such as spin-density-wave metallic state (M=K, Tl, Rb; X=S), superconducting one (M=NH_4; X=S), and simple metallic one (M=K, Tl; X=Se). Current status of these researches is outlined, including the magnetic field effects on the first group which appear in high fields more than 20T at low temperatures

    Luttinger parameters and momentum distribution function for the half-filled spinless fermion Holstein model: A DMRG approach

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    We reexamine the nature of the metallic phase of the one-dimensional half-filled Holstein model of spinless fermions. To this end we determine the Tomonaga-Luttinger-liquid correlation parameter KρK_\rho by large-scale density-matrix renormalisation-group (DMRG) calculations, exploiting (i) the leading-order scaling relations between the ground-state energy and the single-particle excitation gap and (ii) the static charge structure factor in the long-wavelength limit. While both approaches give almost identical results for intermediate-to-large phonon frequencies, we find contrasting behaviour in the adiabatic regime: (i) Kρ>1K_\rho>1 (attractive) versus (ii) Kρ<1K_\rho<1 (repulsive). The latter result for the correlation exponent is corroborated by data obtained for the momentum distribution function n(k)n(k), which puts the existence of an attractive metallic state in the spinless fermion Holstein model into question. We conclude that the scaling relation must be modified in the presence of electron-phonon interactions with noticeable retardation.Comment: 6 pages, 5 figures, revised versio

    Long-range nonlocal flow of vortices in narrow superconducting channels

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    We report a new nonlocal effect in vortex matter, where an electric current confined to a small region of a long and sufficiently narrow superconducting wire causes vortex flow at distances hundreds of inter-vortex separations away. The observed remote traffic of vortices is attributed to a very efficient transfer of a local strain through the one-dimensional vortex lattice, even in the presence of disorder. We also observe mesoscopic fluctuations in the nonlocal vortex flow, which arise due to "traffic jams" when vortex arrangements do not match a local geometry of a superconducting channel.Comment: a slightly longer version of a tentatively accepted PR
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