Development of Heterogeneous Photosensitized Transition Metal Oxide Water-Splitting Catalysts on Silica Support

The research presented in this manuscript describes the development of photosensitized inexpensive catalysts based on readily available materials. The investigation covers synthesis and characterization of photosensitizers based on porphyrins, mechanical and thermal coating of solid support with semiconducting transition metal oxides, photosensitization of the semiconducting layer, and characterization of the photoelectrochemical properties displayed by the new materials. The process of water oxidation is of primary interest here, with little emphasis put on reduction of protons to gaseous hydrogen. Photoelectrochemically produced protons serve as a probe of effectiveness of the catalysts. Several systems are described, and two catalysts are identified as the most efficient

Use of a large jet transport as an inflight dynamic simulator

Modified jet transport used as inflight dynamic simulator for supersonic transport low speed approach and landing characteristic

Small amplitude lateral sloshing in a cylindrical tank with a hemispherical bottom under low gravitational conditions Summary report

Small amplitude lateral sloshing in cylindrical tank with hemispherical bottom under low gravitational condition

Spin Foam Models of Matter Coupled to Gravity

We construct a class of spin foam models describing matter coupled to gravity, such that the gravitational sector is described by the unitary irreducible representations of the appropriate symmetry group, while the matter sector is described by the finite-dimensional irreducible representations of that group. The corresponding spin foam amplitudes in the four-dimensional gravity case are expressed in terms of the spin network amplitudes for pentagrams with additional external and internal matter edges. We also give a quantum field theory formulation of the model, where the matter degrees of freedom are described by spin network fields carrying the indices from the appropriate group representation. In the non-topological Lorentzian gravity case, we argue that the matter representations should be appropriate SO(3) or SO(2) representations contained in a given Lorentz matter representation, depending on whether one wants to describe a massive or a massless matter field. The corresponding spin network amplitudes are given as multiple integrals of propagators which are matrix spherical functions.Comment: 30 pages, 9 figures, further remarks and references added. Version to appear in Class. Quant. Gra

Policy measures and cyber insurance: a framework

The role of the insurance industry in driving improvements in cyber security has been identified as mutually beneficial for both insurers and policy-makers. To date, there has been no consideration of the roles governments and the insurance industry should pursue in support of this public–private partnership. This paper rectifies this omission and presents a framework to help underpin such a partnership, giving particular consideration to possible government interventions that might affect the cyber insurance market. We have undertaken a qualitative analysis of reports published by policy-making institutions and organisations working in the cyber insurance domain; we have also conducted interviews with cyber insurance professionals. Together, these constitute a stakeholder analysis upon which we build our framework. In addition, we present a research roadmap to demonstrate how the ideas described might be taken forward

Spectral characteristics of normal and nutrient-deficient maize leaves

Reflectance, transmittance and absorbance spectra of normal and six types of mineral-deficient (N,P,K,S,Mg and Ca) maize (Zea mays L.) leaves were analyzed at 30 selected wavelengths along the electromagnetic spectrum from 500 to 2600 nm. Chlorophyll content and percent leaf moisture were also determined. Leaf thermograms were obtained for normal, N- and S- deficient leaves. The results of the analysis of variance showed significant differences in reflectance, transmittance and absorbance in the visible wavelengths among leaf numbers 3, 4, and 5, among the seven nutrient treatments, and among the interactions of leaves and treatments. In the reflective infrared wavelengths only treatments produced significant differences. The chlorophyll content of leaves was reduced in all deficiencies in comparison to controls. Percent moisture was increased in S-, Mg- and N- deficiencies. Positive correlation (r = 0.707) between moisture content and percent absorption at both 1450 and 1930 nm were obtained. Polynomial regression analysis of leaf thickness and leaf moisture content showed that these two variables were significantly and directly related (r = 0.894)

Electron Transfer Reactivity of Type Zero Pseudomonas aeruginosa Azurin

Type zero copper is a hard-ligand analogue of the classical type 1 or blue site in copper proteins that function as electron transfer (ET) agents in photosynthesis and other biological processes. The EPR spectroscopic features of type zero Cu^(II) are very similar to those of blue copper, although lacking the deep blue color, due to the absence of thiolate ligation. We have measured the rates of intramolecular ET from the pulse radiolytically generated C3−C26 disulfide radical anion to the Cu^(II) in both type zero C112D/M121L and type 2 C112D Pseudomonas aeruginosa azurins in pH 7.0 aqueous solutions between 8 and 45 °C. We also have obtained rate/temperature (10−30 °C) profiles for ET reactions between these mutants and the wild-type azurin. Analysis of the rates and activation parameters for both intramolecular and intermolecular ET reactions indicates that the type zero copper reorganization energy falls in a range (0.9−1.1 eV) slightly above that for type 1 (0.7−0.8 eV), but substantially smaller than that for type 2 (>2 eV), consistent with XAS and EXAFS data that reveal minimal type zero site reorientation during redox cycling

Must naive realists be relationalists?

Relationalism maintains that perceptual experience involves, as part of its nature, a distinctive kind of conscious perceptual relation between a subject of experience and an object of experience. Together with the claim that perceptual experience is presentational, relationalism is widely believed to be a core aspect of the naive realist outlook on perception. This is a mistake. I argue that naive realism about perception can be upheld without a commitment to relationalism

Invariants from classical field theory

We introduce a method that generates invariant functions from perturbative classical field theories depending on external parameters. Applying our methods to several field theories such as abelian BF, Chern-Simons and 2-dimensional Yang-Mills theory, we obtain, respectively, the linking number for embedded submanifolds in compact varieties, the Gauss' and the second Milnor's invariant for links in S^3, and invariants under area-preserving diffeomorphisms for configurations of immersed planar curves.Comment: 20 pages, 1 figure, to appear in J. Math. Phy

so(4) Plebanski Action and Relativistic Spin Foam Model

In this note we study the correspondence between the ``relativistic spin foam'' model introduced by Barrett, Crane and Baez and the so(4) Plebanski action. We argue that the $so(4)$ Plebanski model is the continuum analog of the relativistic spin foam model. We prove that the Plebanski action possess four phases, one of which is gravity and outline the discrepancy between this model and the model of Euclidean gravity. We also show that the Plebanski model possess another natural dicretisation and can be associate with another, new, spin foam model that appear to be the $so(4)$ counterpart of the spin foam model describing the self dual formulation of gravity.Comment: 12 pages, REVTeX using AMS fonts. Some minor corrections and improvement