Missing North Atlantic cyclonic precipitation in ECMWF numerical weather prediction and ERA-40 data detected through the satellite climatology HOAPS II

Intense precipitation associated with wintertime North Atlantic cyclones occurs not only in connection with frontal zones but also, and often mainly, embedded in strong cold air outbreaks to the west of mature cold fronts. Coherent structures of cloud clusters organized in mesoscale postfrontal low-pressure systems are frequently found in satellite data. Such postfrontal lows (PFL) can develop into severe weather events within few hours and can even reach Europe causing intense convective rainfall and gale force winds. Despite predicting the major storm systems numerical weather prediction (NWP) additionally needs to account for PFLs due to their frequent occurrence connected with high impact weather. But while the major cyclone systems are mostly well predicted, the forecast of PFLs remains poor. Using North Atlantic weather observations from the 1997 Fronts and Atlantic Storm Track Experiment (FASTEX) along with the standard voluntary observing ship (VOS) data led to a high quality validation data set for this usually data sparse region. For individual case studies of FASTEX cyclones with mesoscale PFLs investigations were carried out using the well calibrated precipitation estimates from HOAPS (Hamburg Ocean Atmosphere Parameters and fluxes from satellite data) compared to the NWP model output of the ECMWF (European Centre for Medium-Range Weather Forecasts). Preceding studies showed that the HOAPS precipitation structure and intensities are in good agreement with the VOS observations for all observed precipitation types within the cyclones, including PFLs. To assure that the results found in the 1997 data are still valid in the more recent ECMWF model system, a PFL rainfall comparison is carried out using HOAPS and ERA-40 (ECMWF Re-Analysis) data for the winter of 2001 and 2002. The results indicate that the ECMWF model is mostly well reproducing precipitation structures and intensities associated with frontal systems as observed in the VOS and HOAPS data, whereas PFL precipitation is mostly missing. Further investigations within the regions of PFL point out that the VOS observed surface pressure is systematically lower than reproduced in the models. This leads to the conclusion that the missing PFL precipitation in ECMWF may be primarily due to the absence of the corresponding mesoscale low-pressure syste

Is the aerosol emission detectable in the thermal infrared

The impact of aerosols on the thermal infrared radiation can be assessed by combining observations and radiative transfer calculations. Both have uncertainties, which are discussed in this paper. Observational uncertainties are obtained for two FTIR instruments operated side by side on the ground during the LACE 1998 field campaign. Radiative transfer uncertainties are assessed using a line-by-line model taking into account the uncertainties of the HITRAN 2004 spectroscopic database, uncertainties in the determination of the atmospheric profiles of water vapor and ozone, and differences in the treatment of the water vapor continuum absorption by the CKD 2.4.1 and MT_CKD 1.0 algorithms. The software package OPAC was used to describe the optical properties of aerosols for climate modeling. The corresponding radiative signature is a guideline to the assessment of the uncertainty ranges of observations and models. We found that the detection of aerosols depends strongly on the measurement accuracy of atmospheric profiles of water vapor and ozone and is easier for drier conditions. Within the atmospheric window, only the forcing of downward radiation at the surface by desert aerosol emerges clearly from the uncertainties of modeling and FTIR measurement. Urban and polluted continental aerosols are only partially detectable depending on the wave number and on the atmospheric water vapor amount. Simulations for the space-borne interferometer IASI show that only upward radiation above transported mineral dust aloft emerges out of the uncertainties. The detection of aerosols with weak radiative impact by FTIR instruments like ARIES and OASIS is made difficult by noise as demonstrated by the signal to noise ratio for clean continental aerosols. Altogether, the uncertainties found suggest that it is difficult to detect the optical depths of nonmineral and unpolluted aerosols

Climate mode simulation of North Atlantic polar lows in a limited area model

Polar lows are not properly resolved in global re-analyses. In order to describe the year-to-year variability and decadal trends in the formation of such mesoscale storms, atmospheric limited area models, which post-process re-analysis data, may be an appropriate tool. In this study we demonstrate the merits and potential of this approach. A series of 3-week long ensemble simulations of weather situations over the NE Atlantic with a limited area model/regional climate model (CLM) are examined. The model was driven with NCEP-NCAR re-analyses at the lateral and lower boundaries. Additionally, the spectral nudging technique was used to enforce the large-scale circulation, as given by the NCEP-NCAR reanalysis, on the simulation. The ensemble members differ by initial conditions taken from several consecutive days. In most of the cases, a polar low developed after a simulated time of about 2 weeks, that is, long after the initialization of the model calculations. The spectrally nudged version of the model is very insensitive to initial conditions. The observed polar lows were reproduced in all ensemble members. A reasonable correlation between the simulated polar low features and those derived from a satellite product (HOAPS-III) and operational high-resolution weather analyses (DWD) is found. The polar lows are considerably deepened compared to the driving NCEP-NCAR analysis, but the comparison with weather maps indicates some differences in detail. When CLM is run without the large-scale constraint of spectral nudging, considerable variability emerges across the different ensemble members and the observed polar low often does not emerge. [References: 42

Towards a contrail climatology from NOAA—satellite images over Europe

Contrail cloudiness over Europe and the eastern part of the North Atlantic Ocean was analyzed for the two periods Sept. 1979-Dec. 1981 and Sept. 1989-Aug. 1992 by visual inspection of quicklook photographic prints of NOAA/AVHRR infrared images. The averaged contrail cover exhibits maximum values along the transat- lantic flight corridor around 50°N (of almost 2%) and over western Europe resillting in 0.5% contrail cloudiness on the average. A strong yearly cycle appears with a maximum (< 2%) in spring and summer over the Atlantic and a smaller maximum (< 1%) in winter over southwestern Europe. Comparing the two time periods of one decade separation there is a significant decrease in contrail cloudiness over west- ern Europe and a significant increase over the North Atlantic observable between March and July. Contrail cloud cover during daytime is about twice as high as dur- ing nighttime. Contrails are preferably found in larger fields of 1000 km diameter which last usually for more than one day. Causes, possible errors and consequences are discussed

Activation Energy of Metastable Amorphous Ge2Sb2Te5 from Room Temperature to Melt

Resistivity of metastable amorphous Ge2Sb2Te5 (GST) measured at device level show an exponential decline with temperature matching with the steady-state thin-film resistivity measured at 858 K (melting temperature). This suggests that the free carrier activation mechanisms form a continuum in a large temperature scale (300 K - 858 K) and the metastable amorphous phase can be treated as a super-cooled liquid. The effective activation energy calculated using the resistivity versus temperature data follow a parabolic behavior, with a room temperature value of 333 meV, peaking to ~377 meV at ~465 K and reaching zero at ~930 K, using a reference activation energy of 111 meV (3kBT/2) at melt. Amorphous GST is expected to behave as a p-type semiconductor at Tmelt ~ 858 K and transitions from the semiconducting-liquid phase to the metallic-liquid phase at ~ 930 K at equilibrium. The simultaneous Seebeck (S) and resistivity versus temperature measurements of amorphous-fcc mixed-phase GST thin-films show linear S-T trends that meet S = 0 at 0 K, consistent with degenerate semiconductors, and the dS/dT and room temperature activation energy show a linear correlation. The single-crystal fcc is calculated to have dS/dT = 0.153 {\mu}V/K for an activation energy of zero and a Fermi level 0.16 eV below the valance band edge.Comment: 5 pages, 5 figure

Evaluation of HOAPS-3 ocean surface freshwater flux components

Today, latent heat flux and precipitation over the global ocean surface can be determined from microwave satellite data as a basis for estimating the related fields of the ocean surface freshwater flux. The Hamburg Ocean Atmosphere Parameters and Fluxes from Satellite Data (HOAPS) is the only generally available satellite-based dataset with consistently derived global fields of both evaporation and precipitation and hence of freshwater flux for the period 1987–2005. This paper presents a comparison of the evaporation E, precipitation P, and the resulting freshwater flux E − P in HOAPS with recently available reference datasets from reanalysis and other satellite observation projects as well as in situ ship measurements. In addition, the humidity and wind speed input parameters for the evaporation are examined to identify sources for differences between the datasets. Results show that the general climatological patterns are reproduced by all datasets. Global mean time series often agree within about 10% of the individual products, while locally larger deviations may be found for all parameters. HOAPS often agrees better with the other satellite-derived datasets than with the in situ or the reanalysis data. The agreement usually improves in regions of good in situ sampling statistics. The biggest deviations of the evaporation parameter result from differences in the near-surface humidity estimates. The precipitation datasets exhibit large differences in highly variable regimes with the largest absolute differences in the ITCZ and the largest relative biases in the extratropical storm-track regions. The resulting freshwater flux estimates exhibit distinct differences in terms of global averages as well as regional biases. In comparison with long-term mean global river runoff data, the ocean surface freshwater balance is not closed by any of the compared fields. The datasets exhibit a positive bias in E − P of 0.2–0.5 mm day−1, which is on the order of 10% of the evaporation and precipitation estimates

Suppression of thermoelectric Thomson effect in silicon microwires under large electrical bias and implications for phase-change memory devices

We have observed how thermoelectric effects that result in asymmetric melting of silicon wires are suppressed for increasing electric current density (J). The experimental results are investigated using numerical modeling of the self-heating process, which elucidates the relative contributions of the asymmetric thermoelectric Thomson heat (∼J) and symmetric Joule heating (∼J2) that lead to symmetric heating for higher current levels. These results are applied in modeling of the self-heating process in phase-change memory devices. While, phase-change memory devices show a clearly preferred operation polarity due to thermoelectric effects, nearly symmetric operation can be achieved with higher amplitude and shorter current pulses, which can lead to design of improved polarity-invariant memory circuitry. © 2014 AIP Publishing LLC

Micro-CT Based Experimental Liver Imaging Using a Nanoparticulate Contrast Agent: A Longitudinal Study in Mice

BACKGROUND: Micro-CT imaging of liver disease in mice relies on high soft tissue contrast to detect small lesions like liver metastases. Purpose of this study was to characterize the localization and time course of contrast enhancement of a nanoparticular alkaline earth metal-based contrast agent (VISCOVER ExiTron nano) developed for small animal liver CT imaging. METHODOLOGY: ExiTron nano 6000 and ExiTron nano 12000, formulated for liver/spleen imaging and angiography, respectively, were intravenously injected in C57BL/6J-mice. The distribution and time course of contrast enhancement were analysed by repeated micro-CT up to 6 months. Finally, mice developing liver metastases after intrasplenic injection of colon carcinoma cells underwent longitudinal micro-CT imaging after a single injection of ExiTron nano. PRINCIPAL FINDINGS: After a single injection of ExiTron nano the contrast of liver and spleen peaked after 4-8 hours, lasted up to several months and was tolerated well by all mice. In addition, strong contrast enhancement of abdominal and mediastinal lymph nodes and the adrenal glands was observed. Within the first two hours after injection, particularly ExiTron nano 12000 provided pronounced contrast for imaging of vascular structures. ExiTron nano facilitated detection of liver metastases and provided sufficient contrast for longitudinal observation of tumor development over weeks. CONCLUSIONS: The nanoparticulate contrast agents ExiTron nano 6000 and 12000 provide strong contrast of the liver, spleen, lymph nodes and adrenal glands up to weeks, hereby allowing longitudinal monitoring of pathological processes of these organs in small animals, with ExiTron nano 12000 being particularly optimized for angiography due to its very high initial vessel contrast

Exploiting Native Al2O3 for Multispectral Aluminum Plasmonics

Aluminum, despite its abundance and low cost, is usually avoided for plasmonic applications due to losses in visible/infrared regimes and its interband absorption at 800 nm. Yet, it is compatible with silicon CMOS processes, making it a promising alternative for integrated plasmonic applications. It is also well known that a thin layer of native Al2O3 is formed on aluminum when exposed to air, which must be taken into account properly while designing plasmonic structures. Here, for the first time we report exploitation of the native Al2O3 layer for fabrication of periodic metal-insulator-metal (MIM) plasmonic structures that exhibit resonances spanning a wide spectral range, from the near-ultraviolet to mid-infrared region of the spectrum. Through fabrication of silver nanoislands on aluminum surfaces and MIM plasmonic surfaces with a thin native Al2O3 layer, hierarchical plasmonic structures are formed and used in surface-enhanced infrared spectroscopy (SEIRA) and surface-enhanced Raman spectrocopy (SERS) for detection of self-assembled monolayers of dodecanethiol. (Chemical Equation Presented). © 2014 American Chemical Society