Development of thermally stable phosphonitrile elastomers for advanced aerospace structures

Attempts to prepare low molecular weight, curable poly-(fluoroalkoxyphosphazenes) have been successful. Derivatization of /Cl2PN/n polymer with alkoxides gave functionally reactive terpolymers. These terpolymers could be crosslinked with polyisocyanates at room temperature. Attempts to control molecular weight have not been as successful. The effects of (Cl2PN)3 monomer purity, use of (Cl2PN)3,4 mixture, and early termination of the bulk polymerization of (Cl2PN)3 were studied briefly. Both low and high molecular weight polymers were obtained. Reaction of NH4Cl with PCl5 with subsequent heating to give chain extension gave either gels of oils with molecular weights of several thousand. The stabilization of poly-(fluoroalkoxyphosphazene) was investigated. The results generally were inconclusive, but acids were found to be deleterious while bases had little discernible effect. Improvements in stability by modification of end groups was inconclusive

Development of thermally stable phosphonitrile elastomers for advanced aerospace structures

Both high and low molecular weight, curable poly(fluoroalkoxy phosphazene) terpolymers were prepared. These terpolymers resulted from reaction of (Cl2PNn) polymer with alkoxides derived from CF3CH2OH and C3F7CH2OH, and an alkoxide derived from CH3CH(OH)C2H4OH. The terpolymers were crosslinked with polyisocyanates at room temperature. High molecular weight materials were converted into isocyanate prepolymers which as films underwent moisture cures at room temperature. Prepolymer solutions were stable for several days, and showed good adhesion. Also the effects of polymerization of (Cl2PN)3 were studied. Purified octachlorophosphazene, thiocyanate salts, or hydrogen chloride were employed in attempts to decrease molecular weight. Hydrogen chloride was found to be a good agent for preparation of low molecular weight poly(dichloro phosphazene)

Incoherent pion photoproduction on the deuteron with polarization observables I: Formal expressions

Formal expressions are developed for the general five-fold differential cross section of incoherent $\pi$-photoproduction on the deuteron including beam and target polarization. The polarization observables of the cross section are described by various beam, target and beam-target asymmetries for polarized photons and/or polarized deuterons. They are given as bilinear hermitean forms in the reaction matrix elements divided by the unpolarized cross section. In addition, the corresponding observables for the semi-exclusive reaction $\vec d(\vec \gamma,\pi)NN$ are also given.Comment: 11 pages, 1 figur

Coherent description of the intrinsic and extrinsic anomalous Hall effect in disordered alloys on an abab initioinitio level

A coherent description of the anomalous Hall effect (AHE) is presented that is applicable to pure as well as disordered alloy systems by treating all sources of the AHE on equal footing. This is achieved by an implementation of the Kubo-St\v{r}eda equation using the fully relativistic Korringa-Kohn-Rostoker (KKR) Green's function method in combination with the Coherent Potential Approximation (CPA) alloy theory. Applications to the pure elemental ferromagnets bcc-Fe and fcc-Ni led to results in full accordance with previous work. For the alloy systems fcc-Fe$_x$Pd$_{1-x}$ and fcc-Ni$_x$Pd$_{1-x}$ very satisfying agreement with experiment could be achieved for the anomalous Hall conductivity (AHC) over the whole range of concentration. To interpret these results an extension of the definition for the intrinsic AHC is suggested. Plotting the corresponding extrinsic AHC versus the longitudinal conductivity a linear relation is found in the dilute regimes, that allows a detailed discussion of the role of the skew and side-jump scattering processes.Comment: * shortened manuscript * slight rewordings * changed line style in Fig 1 * corrected misprinted S (skewness) factor * merged Fig. 3 with Fig. 1 * new citation introduce

The limits of process: On (re)reading Henri Bergson

This article offers a reading of the work of Henri Bergson as it pertains to organizations through the lens of ideas drawn from critical realism. It suggests an alternative to interpretations based on a stark division between process and realist perspectives. Much of the existing literature presents a rather partial view of Bergson’s work. A review suggests some interesting parallels with themes in critical realism, notably the emergence of mind. Critical realism has a focus on process at its heart, but is also concerned with how the products of such processes become stabilized and form the conditions for action. This suggests that attention might usefully be paid to the relationship between organizational action and the sedimented practices grouped under the heading of ‘routines’. More attention to Bergson’s account of the relationship between instinct, intuition and intelligence provides a link to the social character of thought, something which can be mapped on to Archer’s work on reflexivity and the ‘internal conversation’. This suggests that our analyses need to pay attention to both memory and history, to building and dwelling, rather than the one-sided focus found in some process theory accounts

Characterisation of HTSC ceramics from their resistive transition

The resistivity vs. temperature relation in bulk ceramic HTSC under self-field conditions as well as in weak external magnetic fields is modelled by local Lorentz force induced fluxon motion with temperature dependent pinning. A pinning force density and two viscous drag coefficients in intergrain and intragrain regions, respectively, can be used as characteristic parameters describing the temperature, current, and external field dependences of the sample resistance.Comment: 12 pages, LaTeX2e, 6 figures (epsfig), to be published in Supercond. Sci. and Techno

Collective multipole-like signatures of entanglement in symmetric N-qubit systems

A cogent theory of collective multipole-like quantum correlations in symmetric multiqubit states is presented by employing SO(3) irreducible spherical tensor representation. An arbitrary bipartite division of this system leads to a family of inequalities to detect entanglement involving averages of these tensors expressed in terms of the total system angular momentum operator. Implications of this theory to the quantum nature of multipole-like correlations of all orders in the Dicke states are deduced. A selected set of examples illustrate these collective tests. Such tests detect entanglement in macroscopic atomic ensembles, where individual atoms are not accessible.Comment: REVTEX, 4 pages with 1 figure; To appear in Phys. Rev.

A fiber-optic current sensor for aerospace applications

A robust, accurate, broad-band, alternating current sensor using fiber optics is being developed for space applications at power frequencies as high as 20 kHz. It can also be used in low and high voltage 60 Hz terrestrial power systems and in 400 Hz aircraft systems. It is intrinsically electromagnetic interference (EMI) immune and has the added benefit of excellent isolation. The sensor uses the Faraday effect in optical fiber and standard polarimetric measurements to sense electrical current. The primary component of the sensor is a specially treated coil of single-mode optical fiber, through which the current carrying conductor passes. Improved precision is accomplished by temperature compensation by means of signals from a novel fiber-optic temperature sensor embedded in the sensing head. The technology contained in the sensor is examined and the results of precision tests conducted at various temperatures within the wide operating range are given. The results of early EMI tests are also given

Fiber-optic sensors for aerospace electrical measurements: An update

Fiber-optic sensors are being developed for electrical current, voltage, and power measurements in aerospace applications. These sensors are presently designed to cover ac frequencies from 60 Hz to 20 kHz. The current sensor, based on the Faraday effect in optical fiber, is in advanced development after some initial testing. Concentration is on packaging methods and ways to maintain consistent sensitivity with changes in temperature. The voltage sensor, utilizing the Pockels effect in a crystal, has excelled in temperature tests. This paper reports on the development of these sensors, the results of evaluation, improvements now in progress, and the future direction of the work