Comparative energetic assessment of methanol production from CO₂: chemical versus electrochemical process

Emerging emission-to-liquid (eTL) technologies that produce liquid fuels from CO₂ are a possible solution for both the global issues of greenhouse gas emissions and fossil fuel depletion. Among those technologies, CO₂ hydrogenation and high-temperature CO₂ electrolysis are two promising options suitable for large-scale applications. In this study, two CO₂ -to-methanol conversion processes, i.e., production of methanol by CO₂ hydrogenation and production of methanol based on high-temperature CO₂ electrolysis, are simulated using Aspen HYSYS. With Aspen Energy Analyzer, heat exchanger networks are optimized and minimal energy requirements are determined for the two different processes. The two processes are compared in terms of energy requirement and climate impact. It is found that the methanol production based on CO₂ electrolysis has an energy efficiency of 41%, almost double that of the CO₂ hydrogenation process provided that the required hydrogen is sourced from water electrolysis. The hydrogenation process produces more CO₂ when fossil fuel energy sources are used, but can result in more negative CO₂ emissions with renewable energies. The study reveals that both of the eTL processes can outperform the conventional fossil-fuel-based methanol production process in climate impacts as long as the renewable energy sources are implemented

Microscopic origin of granular ratcheting

Numerical simulations of assemblies of grains under cyclic loading exhibit ``granular ratcheting'': a small net deformation occurs with each cycle, leading to a linear accumulation of deformation with cycle number. We show that this is due to a curious property of the most frequently used models of the particle-particle interaction: namely, that the potential energy stored in contacts is path-dependent. There exist closed paths that change the stored energy, even if the particles remain in contact and do not slide. An alternative method for calculating the tangential force removes granular ratcheting.Comment: 13 pages, 18 figure