9,176 research outputs found
Electronic and magnetic properties of the kagome systems YBaCo4O7 and YBaCo3MO7 (M=Al, Fe)
We present a combined experimental and theoretical x-ray absorption
spectroscopy (XAS) study of the new class of cobaltates YBaCo4O7 and YBaCo3MO7
(M= Al, Fe). The focus is on the local electronic and magnetic properties of
the transition metal ions in these geometrically frustrated kagome compounds.
For the mixed valence cobaltate YBaCo4O7, both the Co2+ and Co3+ are found to
be in the high spin state. The stability of these high spin states in
tetrahedral coordination is compared with those in the more studied case of
octahedral coordination. For the new compound YBaCo3FeO7, we find exclusively
Co2+ and Fe3+ as charge states
Local electronic structure of Fe impurities in MgO thin films: Temperature-dependent soft x-ray absorption spectroscopy study
We report on the local electronic structure of Fe impurities in MgO thin
films. Using soft x-ray absorption spectroscopy (XAS) we verified that the Fe
impurities are all in the 2+ valence state. The fine details in the line shape
of the Fe edges provide direct evidence for the presence of a
dynamical Jahn-Teller distortion. We are able to determine the magnitude of the
effective crystal field energies. We also observed a strong
temperature dependence in the spectra which we can attribute to the thermal
population of low-lying excited states that are present due to the spin-orbit
coupling in the Fe 3d. Using this Fe impurity system as an example, we
show that an accurate measurement of the orbital moment in FeO will
provide a direct estimate for the effective local low-symmetry crystal fields
on the Fe sites, important for the theoretical modeling of the formation
of orbital ordering
Nonlinear optical probe of tunable surface electrons on a topological insulator
We use ultrafast laser pulses to experimentally demonstrate that the
second-order optical response of bulk single crystals of the topological
insulator BiSe is sensitive to its surface electrons. By performing
surface doping dependence measurements as a function of photon polarization and
sample orientation we show that second harmonic generation can simultaneously
probe both the surface crystalline structure and the surface charge of
BiSe. Furthermore, we find that second harmonic generation using
circularly polarized photons reveals the time-reversal symmetry properties of
the system and is surprisingly robust against surface charging, which makes it
a promising tool for spectroscopic studies of topological surfaces and buried
interfaces
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