2,974 research outputs found
Transport and thermoelectric properties of the LaAlO/SrTiO interface
The transport and thermoelectric properties of the interface between
SrTiO and a 26-monolayer thick LaAlO-layer grown at high
oxygen-pressure have been investigated at temperatures from 4.2 K to 100 K and
in magnetic fields up to 18 T. For 4.2 K, two different electron-like
charge carriers originating from two electron channels which contribute to
transport are observed. We probe the contributions of a degenerate and a
non-degenerate band to the thermoelectric power and develop a consistent model
to describe the temperature dependence of the thermoelectric tensor. Anomalies
in the data point to an additional magnetic field dependent scattering.Comment: 7 pages, 4 figure
Measurement of volatile organic compounds in sediments of the Scheldt estuary and the southern North Sea
The concentrations and distribution of 13 priority volatile organic compounds (VOCs) were determined in sediments of the Scheldt estuary and the Belgian continental shelf, using a modified Tekmar LSC 2000 purge-and-trap system coupled to GC-MS. The method allows a sample intake of up to 50 g wet weight and detection limits are between 0.003 ng/g (tetrachloromethane) and 0.16 ng/g (m- and p-xylene). The repeatability (n = 5) varied between 4% (benzene) and 17% (toluene) and the recoveries ranged from 59% (1,1-dichloroethane) to 99% (tetrachloromethane). Because of the nature of the contaminants, special attention was paid to analyte losses and contamination of the samples during storage aboard the research vessel. Spiked sediment samples were prepared in the laboratory and stored aboard under the same conditions as the environmental samples. The recoveries for these samples varied between 94 and 130%, which suggests that storage had no adverse effect on the samples. No detectable VOC concentrations were found for most of the sampling stations. However, in the Antwerp harbour area, significant concentrations of VOCs were found. The sorption behaviour as predicted from laboratory equilibrium partitioning experiments gives an indication of the in situ partitioning behaviour of VOCs. Although VOCs in sediments should, in general, not be regarded as a major problem in the marine environment, high local concentrations may be a cause of concern
Electronically coupled complementary interfaces between perovskite band insulators
Perovskite oxides exhibit a plethora of exceptional electronic properties,
providing the basis for novel concepts of oxide-electronic devices. The
interest in these materials is even extended by the remarkable characteristics
of their interfaces. Studies on single epitaxial connections between the two
wide-bandgap insulators LaAlO3 and SrTiO3 have revealed them to be either
high-mobility electron conductors or insulating, depending on the atomic
stacking sequences. In the latter case they are conceivably positively charged.
For device applications, as well as for basic understanding of the interface
conduction mechanism, it is important to investigate the electronic coupling of
closely-spaced complementary interfaces. Here we report the successful
realization of such electronically coupled complementary interfaces in SrTiO3 -
LaAlO3 thin film multilayer structures, in which the atomic stacking sequence
at the interfaces was confirmed by quantitative transmission electron
microscopy. We found a critical separation distance of 6 perovskite unit cell
layers, corresponding to approximately 2.3 nm, below which a decrease of the
interface conductivity and carrier density occurs. Interestingly, the high
carrier mobilities characterizing the separate electron doped interfaces are
found to be maintained in coupled structures down to sub-nanometer interface
spacing
Coronal density diagnostics with Helium-like triplets: CHANDRA--LETGS observations of Algol, Capella, Procyon, Eps Eri, Alpha Cen A&B, UX Ari, AD Leo, YY Gem, and HR1099
We present an analysis of ten cool stars (Algol, Capella, Procyon, Eps Eri,
Alpha Cen A&B, UX Ari, AD Leo, YY Gem, and HR1099) observed with the Low Energy
Transmission Grating Spectrometer (LETGS) on board the Chandra X-ray
Observatory. This sample contains all cools stars observed with the LETGS
presently available to us with integration times sufficiently long to warrant a
meaningful spectral analysis. Our sample comprises inactive, moderately active,
and hyperactive stars and samples the bulk part of activity levels encountered
in coronal X-ray sources. We use the LETGS spectra to carry out density and
temperature diagnostics with an emphasis on the H-like and the He-like ions. We
find a correlation between line flux ratios of the Lyman-Alpha and He-like
resonance lines with the mean X-ray surface flux. We determine densities using
the He-like triplets. For active stars we find no significant deviations from
the low-density limit for the ions of Ne, Mg, and Si, while the measured line
ratios for the ions of C, N, and O do show evidence for departures from the
low-density limit in the active stars, but not in the inactive stars. Best
measurements can be made for the OVII triplet where we find significant
deviations from the low-density limit for the stars Algol, Procyon, YY Gem, Eps
Eri, and HR1099. We discuss the influence of radiation fields on the
interpretation of the He-like triplet line ratios in the low-Z ions, which is
relevant for Algol, and the influence of dielectronic satellite lines, which is
relevant for Procyon. For the active stars YY Gem, Eps Eri, and HR1099 the low
f/i ratios can unambiguously be attributed to high densties in the range 1--3
10^10 cm^-3 at OVII temperatures. We find our LETGS spectra to be an extremely
useful tool for plasma diagnostics of stellar coronae.Comment: 17 pages, Latex2e, 12 figures. accepted for A&A under MS262
Gate-tunable band structure of the LaAlO-SrTiO interface
The 2-dimensional electron system at the interface between LaAlO and
SrTiO has several unique properties that can be tuned by an externally
applied gate voltage. In this work, we show that this gate-tunability extends
to the effective band structure of the system. We combine a magnetotransport
study on top-gated Hall bars with self-consistent Schr\"odinger-Poisson
calculations and observe a Lifshitz transition at a density of
cm. Above the transition, the carrier density of one
of the conducting bands decreases with increasing gate voltage. This surprising
decrease is accurately reproduced in the calculations if electronic
correlations are included. These results provide a clear, intuitive picture of
the physics governing the electronic structure at complex oxide interfaces.Comment: 14 pages, 4 figure
First Light Measurements of Capella with the Low Energy Transmission Grating Spectrometer aboard the Chandra X-ray Observatory
We present the first X-ray spectrum obtained by the Low Energy Transmission
Grating Spectrometer (LETGS) aboard the Chandra X-ray Observatory. The spectrum
is of Capella and covers a wavelength range of 5-175 A (2.5-0.07 keV). The
measured wavelength resolution, which is in good agreement with ground
calibration, is 0.06 A (FWHM). Although in-flight
calibration of the LETGS is in progress, the high spectral resolution and
unique wavelength coverage of the LETGS are well demonstrated by the results
from Capella, a coronal source rich in spectral emission lines. While the
primary purpose of this letter is to demonstrate the spectroscopic potential of
the LETGS, we also briefly present some preliminary astrophysical results. We
discuss plasma parameters derived from line ratios in narrow spectral bands,
such as the electron density diagnostics of the He-like triplets of carbon,
nitrogen, and oxygen, as well as resonance scattering of the strong Fe XVII
line at 15.014 A.Comment: 4 pages (ApJ letter LaTeX), 2 PostScript figures, accepted for
publication in ApJ Letters, 200
- …