Design of a 2.4 GHz High-Performance Up-Conversion Mixer with Current Mirror Topology

In this paper, a low voltage low power up-conversion mixer, designed in a Chartered 0.18 μm RFCMOS technology, is proposed to realize the transmitter front-end in the frequency band of 2.4 GHz. The up-conversion mixer uses the current mirror topology and current-bleeding technique in both the driver and switching stages with a simple degeneration resistor. The proposed mixer converts an input of 100 MHz intermediate frequency (IF) signal to an output of 2.4 GHz radio frequency (RF) signal, with a local oscillator (LO) power of 2 dBm at 2.3 GHz. A comparison with conventional CMOS up-conversion mixer shows that this mixer has advantages of low voltage, low power consumption and high-performance. The post-layout simulation results demonstrate that at 2.4 GHz, the circuit has a conversion gain of 7.1 dB, an input-referred third-order intercept point (IIP3) of 7.3 dBm and a noise figure of 11.9 dB, while drawing only 3.8 mA for the mixer core under a supply voltage of 1.2 V. The chip area including testing pads is only 0.62×0.65 mm2

Caging phenomena in reactions: Femtosecond observation of coherent, collisional confinement

We report striking observations of coherent caging of iodine, above the B state dissociation threshold, by single collisions with rare gas atoms at room-temperature. Despite the random nature of the solute–solvent interaction, the caged population retains coherence of the initially prepared unbound wave packet. We discuss some new concepts regarding dynamical coherent caging and the one-atom cage effect

Dynamics of ligand substitution in labile cobalt complexes resolved by ultrafast T-jump

Ligand exchange of hydrated metal complexes is common in chemical and biological systems. Using the ultrafast T-jump, we examined this process, specifically the transformation of aqua cobalt (II) complexes to their fully halogenated species. The results reveal a stepwise mechanism with time scales varying from hundreds of picoseconds to nanoseconds. The dynamics are significantly faster when the structure is retained but becomes rate-limited when the octahedral-to-tetrahedral structural change bottlenecks the transformation. Evidence is presented, from bimolecular kinetics and energetics (enthalpic and entropic), for a reaction in which the ligand assists the displacement of water molecules, with the retention of the entering ligand in the activated state. The reaction time scale deviates by one to two orders of magnitude from that of ionic diffusion, suggesting the involvement of a collisional barrier between the ion and the much larger complex

Mechanical and rheological properties of selected varieties of peppers.

Stress-relaxation rates for eight varieties of peppers were measured. The specimens were loaded at 454,907 and 1361 grams and allowed to relax for time periods of 3.8 and 30 minutes. Stress levels used were 914, 1828 and 2741 gm/cm2. Floral Gem and Jalapeno varieties of peppers received the most attention