105 research outputs found

    Removing pose from face images

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    This paper proposes a novel approach to pose removal from face images based on the inherent symmetry that is present in faces. In order for face recognition systems and expression classification systems to operate optimally, subjects must look directly into the camera. The removal of pose from face images after their capture removes this restriction. To obtain a pose-removed face image, the frequency components at each position of the face image, obtained through a wavelet transformation, are examined. A cost function based on the symmetry of this wavelet transformed face image is minimized to achieve pose removal.Experimental results are presented that demonstrate that the proposed algorithm improves upon existing techniques in the literature

    Continuous symmetry of C60 fullerene and its derivatives

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    Conventionally, the Ih symmetry of fullerene C60 is accepted which is supported by numerous calculations. However, this conclusion results from the consideration of the molecule electron system, of its odd electrons in particular, in a close-shell approximation without taking the electron spin into account. Passing to the open-shell approximation has lead to both the energy and the symmetry lowering up to Ci. Seemingly contradicting to a high-symmetry pattern of experimental recording, particularly concerning the molecule electronic spectra, the finding is considered in the current paper from the continuous symmetry viewpoint. Exploiting both continuous symmetry measure and continuous symmetry content, was shown that formal Ci symmetry of the molecule is by 99.99% Ih. A similar continuous symmetry analysis of the fullerene monoderivatives gives a reasonable explanation of a large variety of their optical spectra patterns within the framework of the same C1 formal symmetry exhibiting a strong stability of the C60 skeleton.Comment: 11 pages. 5 figures. 6 table

    Step-Wise Computational Synthesis of Fullerene C60 derivatives. 1.Fluorinated Fullerenes C60F2k

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    The reactions of fullerene C60 with atomic fluorine have been studied by unrestricted broken spin-symmetry Hartree-Fock (UBS HF) approach implemented in semiempirical codes based on AM1 technique. The calculations were focused on a sequential addition of fluorine atom to the fullerene cage following indication of the cage atom highest chemical susceptibility that is calculated at each step. The effectively-non-paired-electron concept of the fullerene atoms chemical susceptibility lays the foundation of the suggested computational synthesis. The obtained results are analyzed from energetic, symmetry, and the composition abundance viewpoints. A good fitting of the data to experimental findings proves a creative role of the suggested synthesis methodology.Comment: 33 pages, 11 figures, 2 tables, 2 chart

    Synthesis and solid-state characterisation of 4-substituted methylidene oxindoles

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    Background 4-substituted methylidene oxindoles are pharmacologically important. Detailed analysis and comparison of all the interactions present in crystal structures is necessary to understand how these structures arise. The XPac procedure allows comparison of complete crystal structures of related families of compounds to identify assemblies that are mainly the result of close-packing as well as networks of directed interactions. Results Five 4-substituted methylidene oxindoles have been synthesized by the Knoevenagel condensation of oxindole with para-substituted aromatic aldehydes and were characterized in the solid state by x-ray crystallography. Hence, the structures of (3E)-3-(4-Bromobenzylidene)-1,3-dihydro-2H-indol-2-one, 3a, (3E)-3-(4-Chlorobenzylidene)-1,3-dihydro-2H-indol-2-one, 3b, (3E)-3-(4-Methoxybenzylidene)-1,3-dihydro-2H-indol-2-one, 3c, (3E)-3-(4-Methylbenzylidene)-1,3-dihydro-2H-indol-2-one, 3d and (3E)-3-(4-Nitrobenzylidene)-1,3-dihydro-2H-indol-2-one, 3e, were elucidated using single crystal X-ray crystallography. Conclusions A hydrogen bonded dimer molecular assembly or supramolecular construct was identified in all the crystal structures examined along with a further four 1D supramolecular constructs which were common to at least two of the family of structures studied. The 1D supramolecular constructs indicate that once the obvious strong interaction is satisfied to form hydrogen bonded dimer it is the conventionally weaker interactions, such as steric bulk and edge-to-face interactions which compete to influence the final structure formation

    A Comparative Analysis of Detecting Symmetries in Toroidal Topology

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    In late 1940s and with the introduction of cellular automata, various types of problems in computer science and other multidisciplinary fields have started utilising this new technique. The generative capabilities of cellular automata have been used for simulating various natural, physical and chemical phenomena. Aside from these applications, the lattice grid of cellular automata has been providing a by-product interface to generate graphical patterns for digital art creation. One notable aspect of cellular automata is symmetry, detecting of which is often a difficult task and computationally expensive. This paper uses a swarm intelligence algorithm—Stochastic Diffusion Search—to extend and generalise previous works and detect partial symmetries in cellular automata generated patterns. The newly proposed technique tailored to address the spatially-independent symmetry problem is also capable of identifying the absolute point of symmetry (where symmetry holds from all perspectives) in a given pattern. Therefore, along with partially symmetric areas, the centre of symmetry is highlighted through the convergence of the agents of the swarm intelligence algorithm. Additionally this paper proposes the use of entropy and information gain measure as a complementary tool in order to offer insight into the structure of the input cellular automata generated images. It is shown that using these technique provides a comprehensive picture about both the structure of the images as well as the presence of any complete or spatially-independent symmetries. These technique are potentially applicable in the domain of aesthetic evaluation where symmetry is one of the measures

    Particle motion and heat transfer in an upward-flowing dense particle suspension: application in solar receivers

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    Concentrated solar power (CSP) plants conventionally make use of molten salt as the heat transfer medium, which transfers heat between the solar receiver and a steam turbine power circuit. A new approach uses particles of a heat-resistant particulate medium in the form of many dense upward-moving fluidised beds contained within an array of vertical tubes within the solar receiver. In most dense gas-solid fluidisation systems, particle circulation is induced by bubble motion and is the primary cause of particle convective heat transfer, which is the major contributing mechanism to overall heat transfer. The current work describes experiments designed to investigate the relationship between this solids convection and the heat transfer coefficient between the bed and the tube wall, which is shown to depend on the local particle concentration and their rate of renewal at the wall. Experiments were performed using 65 µm silicon carbide particles in a tube of diameter 30mm, replicating the conditions used in the real application. Solids motion and time-averaged solids concentration were measured using Positron Emission Particle Tracking (PEPT) and local heat transfer coefficients measured using small probes which employ electrical resistance heating and thermocouple temperature measurement. Results show that, as for other types of bubbling beds, the heat transfer coefficient first increases as the gas flow rate increases (because the rate of particle renewal at the wall increases), before passing through a maximum and decreasing again as the reducing local solids concentration at the wall becomes the dominant effect. Measured heat transfer coefficients are compared with theoretical approaches by Mickley and Fairbanks packet model and Thring correlation. The close correspondence between heat transfer coefficient and solids movement is here demonstrated by PEPT for the first time in a dense upward-moving fluidised bed
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