Spin-Dependent Electron Transmission Model for Chiral Molecules in Mesoscopic Devices

Various device-based experiments have indicated that electron transfer in certain chiral molecules may be spin-dependent, a phenomenon known as the Chiral Induced Spin Selectivity (CISS) effect. However, due to the complexity of these devices and a lack of theoretical understanding, it is not always clear to what extent the chiral character of the molecules actually contributes to the magnetic-field-dependent signals in these experiments. To address this issue, we report here an electron transmission model that evaluates the role of the CISS effect in two-terminal and multi-terminal linear-regime electron transport experiments. Our model reveals that for the CISS effect, the chirality-dependent spin transmission is accompanied by a spin-flip electron reflection process. Furthermore, we show that more than two terminals are required in order to probe the CISS effect in the linear regime. In addition, we propose two types of multi-terminal nonlocal transport measurements that can distinguish the CISS effect from other magnetic-field-dependent signals. Our model provides an effective tool to review and design CISS-related transport experiments, and to enlighten the mechanism of the CISS effect itself

Circuit-Model Analysis for Spintronic Devices with Chiral Molecules as Spin Injectors

Recent research discovered that charge transfer processes in chiral molecules can be spin selective and named the effect chiral-induced spin selectivity (CISS). Follow-up work studied hybrid spintronic devices with conventional electronic materials and chiral (bio)molecules. However, a theoretical foundation for the CISS effect is still in development and the spintronic signals were not evaluated quantitatively. We present a circuit-model approach that can provide quantitative evaluations. Our analysis assumes the scheme of a recent experiment that used photosystem~I (PSI) as spin injectors, for which we find that the experimentally observed signals are, under any reasonable assumptions on relevant PSI time scales, too high to be fully due to the CISS effect. We also show that the CISS effect can in principle be detected using the same type of solid-state device, and by replacing silver with graphene, the signals due to spin generation can be enlarged four orders of magnitude. Our approach thus provides a generic framework for analyzing this type of experiments and advancing the understanding of the CISS effect

Unified description of bulk and interface-enhanced spin pumping

The dynamics of non-equilibrium spin accumulation generated in metals or semiconductors by rf magnetic field pumping is treated within a diffusive picture. The dc spin accumulation produced in a uniform system by a rotating applied magnetic field or by a precessing magnetization of a weak ferromagnet is in general given by a (small) fraction of hbar omega, where omega is the rotation or precession frequency. With the addition of a neighboring, field-free region and allowing for the diffusion of spins, the spin accumulation is dramatically enhanced at the interface, saturating at the universal value hbar omega in the limit of long spin relaxation time. This effect can be maximized when the system dimensions are of the order of sqrt(2pi D omega), where D is the diffusion constant. We compare our results to the interface spin pumping theory of A. Brataas et al. [Phys. Rev. B 66, 060404(R) (2002)]

All-optical coherent population trapping with defect spin ensembles in silicon carbide

Divacancy defects in silicon carbide have long-lived electronic spin states and sharp optical transitions, with properties that are similar to the nitrogen-vacancy defect in diamond. We report experiments on 4H-SiC that investigate all-optical addressing of spin states with the zero-phonon-line transitions. Our magneto-spectroscopy results identify the spin $S=1$ structure of the ground and excited state, and a role for decay via intersystem crossing. We use these results for demonstrating coherent population trapping of spin states with divacancy ensembles that have particular orientations in the SiC crystal.Comment: 28 page document: Pages 1-14 main text (with 3 figures); pages 15-28 supplementary information (with 5 figues). v2 has minor correction

Chinantec shifting cultivation : InTERAcTIVE landuse : a case-study in the Chinantla, Mexico, on secondary vegetation, soils and crop performance under indigenous shifting cultivation

The development of secondary vegetation, soils and crop performance was studied in local variants of shifting cultivation in two villages in the Chinantla, Mexico. In Chapter 1, the institutional, social and political context of the research are presented and the reader is advertised that the scope of the study is limited to the interaction between ecological-productive aspects and the landuse pattern as practiced by the farmers.In Chapter 2 a conceptual framework is presented. Indigenous shifting cultivation is defined as a general form of landuse, characterized by the continuous recontextualization of a many-sided relation between man and nature, the continuous recreation of knowledge and the making and use of dynamic fields according to a landuse pattern. A great specificity of indigenous shifting cultivation in response to local environmental and socio-economical factors is observed.The ecology of secondary vegetation is reviewed, paying attention to mountain areas such as the Chinantla. The development of forest eco-units is not a simple, unilinear process, but, on the contrary, a process that can take one of many possible courses, influenced by environmental factors and the use-history of the land. Soils develop as an integral part of eco-units, as has been observed by comparing the soil in hurricane tracts and eco-units of different ages. The development of secondary vegetation and soils, as related to the landuse pattern for shifting cultivation, leads to variation in the ecological conditions within the mosaic of fields. Consequently, the performance of crops may vary within the mosaic of fields.In the Chinantla region a large variation in climate occurs due to a wide altitudinal range (Chapter 3). As a consequence, several vegetation types occur. Soils in the area have developed from limestone or sandstone/metamorphic rocks. Chapter 4 describes the variants of shifting cultivation and the landuse pattern in the Chinantec communities Santa Cruz Tepetotutla and Santiago Tlatepusco. Three variants of shifting cultivation were distinguished: shifting cultivation in the area of 'selva alta perennifolia de montaña' (the most widely practised), shifting cultivation in the limestone area, and shifting cultivation in the Quercus -forests. In all variants maize is the principal crop.In Chapter 5 the development of secondary vegetation as related to the use-history of fields is studied, concentrating on secondary vegetation in the area of 'selva alta perennifolia de montaña'. Secondary regrowths were sampled in 28 fields. Ages of regrowths varied from 5 to 50 years, and orders of regrowths (first-order regrowths develop after cutting primary or old secondary vegetation; second-order regrowths after cutting a first-order regrowth) varied from 1 to 4. On each field, data on the trees and shrubs with a diameter at breast-height of more than 2 cm were recorded in four transects, each of 100 m 2surface area, which were all laid out on steep slopes.A total of 5691 trees and shrubs, belonging to 229 species, were found on the sampled area. Thirty-seven species comprised 90% of all sampled individuals. Cluster and ordination analysis showed variation of the species composition of secondary vegetation with age, altitude, geographic location, lithology and order of regrowth. Analysis of farmers' information on the relation between order of regrowth and species composition confirmed the results of sampling.Structural parameters, species composition, tree development and eco-unit development varied between orders of regrowth. Basal area, number of trees and crown area index were high in first- and second-order regrowths, but fell sharply in subsequent regrowths. First-order regrowths were dominated by one or two species. In several second-order regrowths, Hedyosmum mexicanum was the single dominant. In other second-order and in later-order regrowths polydominance was observed. Analysis of height-diameter relations in frequent species also indicated a relation between the order of regrowth and the development of the trees of a certain species, demonstrating the flexibility of trees in responding to a changing environment. Whereas first- and second-order regrowths were composed of few eco-units, third- and fourth-order regrowths showed fragmentation of eco-units from early phases of development onwards. The results indicate that the number of consecutive eco-units per time unit diminishes with increasing order of regrowth.Changes in soils during one cropping season were studied by comparing soil parameters in samples obtained after slashing the vegetation (May), after burning (June) and at harvest (October-November). No significant differences in bases, pH, nitrogen and carbon were found between May- and June-samples on limestone-derived soils. Between burning and harvest, pH and the sum of exchangeable bases increased slightly. In the area of 'selva alta perennifolia de montaña' pH and exchangeable bases increased significantly between May and June. During the cropping season (June to October-November), the sum of exchangeable bases declined slightly. No relation of these changes with the use-history of fields was found, possibly due to the small number of sampled fields and burns being partial and heterogenous in the year of sampling (1993).Sampling of soils in a chronosequence of fields in the area of 'selva alta perennifolia de montaña' gave strong indications of an increase of pH and exchangeable bases in the course of several decades, from the cutting of primary or old secondary vegetation onwards. The strongest increase was observed in the quantity of exchangeable calcium. Correlations between use-history parameters and carbon, nitrogen and phosphorus were not significant. A mechanism of soil change based on a combination of physical and biological processes is proposed, wherein an initial increase in pH through the addition of bases triggers of an increased biological activity resulting in a more hospitable soil.The performance of maize crops in a chronosequence of fields was studied in 1994 by determining several parameters referring to the crops (Chapter 7). Crop performance varied strongly between fields, both in the limestone area and in the area of 'selva alta perennifolia de montaña'. In the limestone area, yield per square meter sloping surface diminished with increasing number of burns; there was no relation between yield and any of the measured soil parameters. In the area of 'selva alta perennifolia de montaña', yields were not significantly correlated with any of the parameters applied to characterize the use-history of fields. However, yields per square meter sloping surface were correlated with several soil parameters: CEC-BaCl 2 , exchangeable calcium, total phosphorus and the C/N-ratio. At values smaller than 3.9 also pH-KCl was positively correlated with yields. In fertilization experiments, the combined application of nitrogen and phosphorus improved yield on a field where without fertilization a low yield was obtained; fertilization had no effect where high yields were obtained without fertilization.The development of secondary vegetation, soils and crop performance in indigenous shifting cultivation in two villages in the Chinantla, Mexico, illustrates the interactive and iterative character of this form of agriculture. This character should be taken as the point of departure for its redesign in such a way that the production of a variety of goods is combined with the production of a variety of services in a complex mosaic of eco-units.Treemail Publishersall rights reserved - ISBN 90-804443-4-0for information on all Treebooks visithttp://www.treemail.nl</p

Two-laser dynamic nuclear polarization with semiconductor electrons:Feedback, suppressed fluctuations, and bistability near two-photon resonance

Feedback control is a powerful tool to stabilize systems for which precision control is difficult to impose directly, such as the environment of an open quantum system. Reduction of noise from the environment is a major challenge on the road to harnessing delicate quantum effects such as superposition and entanglement. In particular, spin states of defects and quantum dots in semiconductors display promising coherence properties for future applications, often being limited by disturbance from disordered nuclear spins in their environment. Here we show how optical coherent population trapping (CPT) of the spin of localized semiconductor electrons stabilizes the surrounding nuclear spins via feedback control. We find distinct control regimes for different signs of laser detuning and examine the transition from an unpolarized, narrowed state to a polarized state possessing a bistability. The narrowing of the state protects the electron spin against dephasing and yields self-improving CPT. Our analysis is relevant for a variety of solid-state systems where hyperfine-induced dephasing is a limitation for using electron spin coherence