336 research outputs found
Magnetic and transport properties of the spin-state disordered oxide La0.8Sr0.2Co_{1-x}Rh_xO_{3-\delta}
We report measurements and analysis of magnetization, resistivity and
thermopower of polycrystalline samples of the perovskite-type Co/Rh oxide
LaSrCoRhO. This system constitutes a
solid solution for a full range of ,in which the crystal structure changes
from rhombohedral to orthorhombic symmetry with increasing Rh content . The
magnetization data reveal that the magnetic ground state immediately changes
upon Rh substitution from ferromagnetic to paramagnetic with increasing
near 0.25, which is close to the structural phase boundary. We find that one
substituted Rh ion diminishes the saturation moment by 9 , which implies
that one Rh ion makes a few magnetic Co ions nonmagnetic (the low
spin state), and causes disorder in the spin state and the highest occupied
orbital. In this disordered composition (), we find that
the thermopower is anomalously enhanced below 50 K. In particular, the
thermopower of =0.5 is larger by a factor of 10 than those of =0 and 1,
and the temperature coefficient reaches 4 V/K which is as large as
that of heavy-fermion materials such as CeRuSi.Comment: 8 pages, 6 figures, accepted to Phys. Rev.
Crystallographic and superconducting properties of the fully-gapped noncentrosymmetric 5d-electron superconductors CaMSi3 (M=Ir, Pt)
We report crystallographic, specific heat, transport, and magnetic properties
of the recently discovered noncentrosymmetric 5d-electron superconductors
CaIrSi3 (Tc = 3.6 K) and CaPtSi3 (Tc = 2.3 K). The specific heat suggests that
these superconductors are fully gapped. The upper critical fields are less than
1 T, consistent with limitation by conventional orbital depairing. High,
non-Pauli-limited {\mu}0 Hc2 values, often taken as a key signature of novel
noncentrosymmetric physics, are not observed in these materials because the
high carrier masses required to suppress orbital depairing and reveal the
violated Pauli limit are not present.Comment: 8 pages, 8 figure
Synthesis and photoemission study of as-grown superconducting MgB2 thin films
As-grown superconducting thin films of MgB2 were prepared by molecular beam
epitaxy (MBE), and studied by X-ray and ultraviolet photoelectron spectroscopy
(XPS and UPS). Only films prepared at temperatures between 150 and 320 deg.
showed superconductivity. A best TC onset of 36 K with a sharp transition width
of -1 K was obtained although the film crystallinity was poor. The in-situ
photoelectron spectra obtained on the surfaces of the MBE grown MgB2 films were
free from dirt peaks. XPS revealed that the binding energy of the Mg 2p levels
in MgB2 is close to that of metallic Mg, and the binding energy of B 1s is
close to that of transition-metal diborides. The valence UP spectra showed a
clear Fermi edge although the density of states (DOS) at EF is low and the
major components of the valence band are located between 5 and 11 eV.Comment: ISS 2001 proceedin
Superconductivity at 38 K in Iron-Based Compound with Platinum-Arsenide Layers Ca10(Pt4As8)(Fe2-xPtxAs2)5
We report superconductivity in novel iron-based compounds
Ca10(PtnAs8)(Fe2-xPtxAs2)5 with n = 3 and 4. Both compounds crystallize in
triclinic structures (space group P-1), in which Fe2As2 layers alternate with
PtnAs8 spacer layers. Superconductivity with a transition temperature of 38 K
is observed in the n = 4 compound with a Pt content of x ~ 0.36 in the Fe2As2
layers. The compound with n = 3 exhibits superconductivity at 13 K.Comment: OPEN SELECT article, 11 pages, 5 figures, 2 table
Validation of Stratospheric and Mesospheric Ozone Observed by SMILES from International Space Station
We observed ozone O3 in the vertical region between 250 and 0.0005 hPa (~ 12-96 km) using the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the Japanese Experiment Module (JEM) of the International Space Station (ISS) between 12 October 2009 and 21 April 2010. The new 4K superconducting heterodyne receiver technology of SMILES allowed us to obtain a one order of magnitude better signal-to-noise ratio for the O3 line observation compared to past spaceborne microwave instruments. The non-sun-synchronous orbit of the ISS allowed us to observe O3 at various local times. We assessed the quality of the vertical profiles of O3 in the 100-0.001 hPa (~ 16-90 km) region for the SMILES NICT Level 2 product version 2.1.5. The evaluation is based on four components: error analysis; internal comparisons of observations targeting three different instrumental setups for the same O3 625.371 GHz transition; internal comparisons of two different retrieval algorithms; and external comparisons for various local times with ozonesonde, satellite and balloon observations (ENVISAT/MIPAS, SCISAT/ACE-FTS, Odin/OSIRIS, Odin/SMR, Aura/MLS, TELIS). SMILES O3 data have an estimated absolute accuracy of better than 0.3 ppmv (3%) with a vertical resolution of 3-4 km over the 60 to 8 hPa range. The random error for a single measurement is better than the estimated systematic error, being less than 1, 2, and 7%, in the 40-1, 80-0.1, and 100-0.004 hPa pressure regions, respectively. SMILES O-3 abundance was 10-20% lower than all other satellite measurements at 8-0.1 hPa due to an error arising from uncertainties of the tangent point information and the gain calibration for the intensity of the spectrum. SMILES O3 from observation frequency Band-B had better accuracy than that from Band-A. A two month period is required to accumulate measurements covering 24 h in local time of O3 profile. However such a dataset can also contain variation due to dynamical, seasonal, and latitudinal effects
Electronic transport, structure, and energetics of endohedral Gd@C82 metallofullerenes
Electronic structure and transport properties of the fullerene C and
the metallofullerene Gd@C are investigated with density functional
theory and the Landauer-Buttiker formalism. The ground state structure of
Gd@C is found to have the Gd atom below the C-C bond on the C
molecular axis of C. Insertion of Gd into C deforms the carbon
chain in the vicinity of the Gd atoms. Significant overlap of the electron
distribution is found between Gd and the C cage, with the transferred Gd
electron density localized mainly on the nearest carbon atoms. This charge
localization reduces some of the conducting channels for the transport, causing
a reduction in the conductivity of the Gd@C species relative to the
empty C molecule. The electron transport across the metallofullerene is
found to be insensitive to the spin state of the Gd atom.Comment: 13 pages, 7 figures, submitted Nano Let
Electronic Structure of B-2p State in AlB2 Single Crystal: Direct Observation ofp\sigma and p\pi Density of States
X-ray emission (XES) and absorption (XAS) spectra near the B- edge were
measured on single-crystalline AlB compound which is an isostructural
diboride of superconducting MgB. The partial density of states (PDOS) of
B-2 and orbitals were derived from the polarization dependence
of XES and XAS spectra. There are considerable amounts of PDOS near the Fermi
energy in AlB similarly to that in MgB, but there are almost no PDOS in
orbitals of AlB near the Fermi energy, i.e., a pseudo-gap in
state and a broad metallic state in state are observed. The
present result indirectly supports scenarios that the holes play an
important role in the occurrence of superconductivity in MgB. The overall
features of PDOS were found to be in good agreement with the result of band
calculation of AlB, but a small discrepancy in the Fermi energy is
observed, which is attributed to the Al vacancy in the compounds, i.e., the
estimated concentration is AlB.Comment: LaTeX files and 4 eps figures, to be published in J. Phys. Soc. Jp
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