(Photo)Electrocatalytic CO2 Reduction at the Defective Anatase TiO2 (101) Surface

Excessive carbon dioxide (CO2) emissions by combustion of fossil fuels are linked to global warming and rapid climate change. One promising route to lowering the concentration of CO2 in the atmosphere is to reduce it to useful small molecules via photoelectrocatalytic hydrogenation, which would enable solar energy storage with a zero-carbon emission cycle and perform a more efficient separation of the photogenerated electron and hole pair than pure photocatalysis. Indeed, photoelectrocatalytic CO2 reduction has been an intense focus of research. Using the density functional theory (DFT), we studied the CO2 reduction reaction on the defective anatase TiO2 (101) surface, at both the solvent/catalyst and the electrolyte/catalyst interfaces. The analysis of the electronic structure of the surface shows a contrast between the solvent/catalyst and the electrolyte/catalyst interfaces, which results in the two corresponding catalytic cycles being distinct. Our study explains at the electronic and mechanistic levels why methanol is the main product in the presence of the electrolyte and why the overpotential is not only controlled by the reaction process but also by the diffusion process

Phonon density of states and compression behavior in iron sulfide under pressure

We report the partial phonon densities of states (DOS) of iron sulfide, a possible component of the rocky planet's core, measured by the Fe-57 nuclear resonant inelastic x-ray scattering and calculate the total phonon DOS under pressure. From the phonon DOS, we drive thermodynamic parameters. A comparison of the observed and estimated compressibilities makes it clear that there is a large pure electronic contribution in the observed compressibility in the metallic state. Our results present the observation of thermodynamic parameters of iron sulfide with the low-spin state of an Fe2+ ion at the high density, which is similar to the condition of the Martian core

Review article: the global emergence of Helicobacter pylori antibiotic resistance.

BackgroundHelicobacter pylori is one of the most prevalent global pathogens and can lead to gastrointestinal disease including peptic ulcers, gastric marginal zone lymphoma and gastric carcinoma.AimTo review recent trends in H. pylori antibiotic resistance rates, and to discuss diagnostics and treatment paradigms.MethodsA PubMed literature search using the following keywords: Helicobacter pylori, antibiotic resistance, clarithromycin, levofloxacin, metronidazole, prevalence, susceptibility testing.ResultsThe prevalence of bacterial antibiotic resistance is regionally variable and appears to be markedly increasing with time in many countries. Concordantly, the antimicrobial eradication rate of H. pylori has been declining globally. In particular, clarithromycin resistance has been rapidly increasing in many countries over the past decade, with rates as high as approximately 30% in Japan and Italy, 50% in China and 40% in Turkey; whereas resistance rates are much lower in Sweden and Taiwan, at approximately 15%; there are limited data in the USA. Other antibiotics show similar trends, although less pronounced.ConclusionsSince the choice of empiric therapies should be predicated on accurate information regarding antibiotic resistance rates, there is a critical need for determination of current rates at a local scale, and perhaps in individual patients. Such information would not only guide selection of appropriate empiric antibiotic therapy but also inform the development of better methods to identify H. pylori antibiotic resistance at diagnosis. Patient-specific tailoring of effective antibiotic treatment strategies may lead to reduced treatment failures and less antibiotic resistance

Experimental Analysis of Algorithms for Coflow Scheduling

Modern data centers face new scheduling challenges in optimizing job-level performance objectives, where a significant challenge is the scheduling of highly parallel data flows with a common performance goal (e.g., the shuffle operations in MapReduce applications). Chowdhury and Stoica introduced the coflow abstraction to capture these parallel communication patterns, and Chowdhury et al. proposed effective heuristics to schedule coflows efficiently. In our previous paper, we considered the strongly NP-hard problem of minimizing the total weighted completion time of coflows with release dates, and developed the first polynomial-time scheduling algorithms with O(1)-approximation ratios. In this paper, we carry out a comprehensive experimental analysis on a Facebook trace and extensive simulated instances to evaluate the practical performance of several algorithms for coflow scheduling, including the approximation algorithms developed in our previous paper. Our experiments suggest that simple algorithms provide effective approximations of the optimal, and that the performance of our approximation algorithms is relatively robust, near optimal, and always among the best compared with the other algorithms, in both the offline and online settings.Comment: 29 pages, 8 figures, 11 table

Nitride mediated epitaxy of CoSi2 through self-interlayer-formation of plasma-enhanced atomic layer deposition Co

The silicide formation by annealing plasma-enhanced atomic layer deposition (PE-ALD) Co and physical vapor deposition (PVD) Co was comparatively studied. Very pure Co films were deposited by PE-ALD with CoCp2 and NH3 plasma. However, various analyses have shown that amorphous SiNx interlayer was formed between PE-ALD Co and Si due to the NH3 plasma exposure in contrast with PVD Co. Due to the nitride interlayer, CoSi2 was epitaxially grown from PE-ALD Co by rapid thermal annealing through nitride mediated epitaxy. This process scheme is expected to provide a simple route for contact formation in future nanoscale devices. (c) 2007 American Institute of Physics.open112221sciescopu

Twenty years of technology and strategic roadmapping research: A school of thought perspective

© 2020 Two decades ago the thirtieth-anniversary special issue of Technological Forecasting and Social Change correctly anticipated the widespread adoption of technology and strategic roadmapping at firm, sectoral and national levels. In this article, we explore the evolution of roadmapping studies since that time. Drawing on a mixed-methods approach (i.e. topic modelling, genealogical analysis, content analysis and interviews), we reveal the development of seven distinctive ‘schools of thought’: the Cambridge practical school, the Seoul school, the Portland and Bangkok schools, the Cambridge phenomenological school, the Beijing school and the Moscow school. We show that the schools differ in terms of (a) the research orientation, whether it be solution- or theory-oriented; (b) the research methods and data sources being used; and (c) the nature of contributions that each school seeks to achieve. The different areas of emphasis associated with each school are not competing but complementary, and together they develop the eclectic body of knowledge on roadmapping

On the elliptical flow in asymmetric collisions and nuclear equation of state

We here present the results of elliptical flow for the collision of different asymmetric nuclei (10Ne20 +13 Al27, 18Ar40 +21 Sc45, 30Zn64 +28 Ni58, 36Kr86 +41 Nb93) by using the Quantum Molecular Dynamics (QMD) model. General features of elliptical flow are investigated with the help of theoretical simulations. The simulations are performed at different beam energies between 40 and 105 MeV/nucleon. A significant change can be seen from in-plane to out-of-plane elliptical flow of different fragments with incident energy. A comparison with experimental data is also made. Further, we predict, for the first time that, elliptical flow for different kind of fragments follow power law dependence ? C(Atot)? for asymmetric systems

A simple method for estimating the convectiondispersion equation parameters of solute transport in agricultural ecosystem

The convection-dispersion equation (CDE) is the classical approach for modeling solute transport in porous media. So, estimating parameters became a key problem in CDE. For statistical method, some problems such as parameter uniqueness are still unsolved because of more factors. Due to the advantage of clear physical concept and unique parameter values, the simple deterministic method became very useful alternatives. In this paper, a simple method was proposed to estimate both D and R, and the validity was verified by experiment, which can be applied in agriculture and environmental fields for predicting soil quality property.Key words: Convection-dispersion equation (CDE), parameters estimation, agricultural system