620 research outputs found
Інвестиційне кредитування переробних підприємств АПК банківськими установами
Метою статті є аналіз динаміки інвестиційного кредитування банківськими установами переробних підприємств агропромислового комплексу. Під час проведення дослідження були використані аналітичний, статистико – економічний, графічний, порівняльний методи та метод системного аналізу
Raman and fluorescence contributions to resonant inelastic soft x-ray scattering on LaAlO/SrTiO heterostructures
We present a detailed study of the Ti 3 carriers at the interface of
LaAlO/SrTiO heterostructures by high-resolution resonant inelastic soft
x-ray scattering (RIXS), with special focus on the roles of overlayer thickness
and oxygen vacancies. Our measurements show the existence of interfacial Ti
3 electrons already below the critical thickness for conductivity and an
increase of the total interface charge up to a LaAlO overlayer thickness of
6 unit cells before it levels out. By comparing stoichiometric and oxygen
deficient samples we observe strong Ti 3 charge carrier doping by oxygen
vacancies. The RIXS data combined with photoelectron spectroscopy and transport
measurements indicate the simultaneous presence of localized and itinerant
charge carriers. However, it is demonstrated that the relative amount of
localized and itinerant Ti electrons in the ground state cannot be deduced
from the relative intensities of the Raman and fluorescence peaks in excitation
energy dependent RIXS measurements, in contrast to previous interpretations.
Rather, we attribute the observation of either the Raman or the fluorescence
signal to the spatial extension of the intermediate state reached in the RIXS
excitation process.Comment: 9 pages, 6 figure
Cell line-specific oxidative stress in cellular toxicity: A toxicogenomics-based comparison between liver and colon cell models
High-energy photoemission on Fe3O4: Small polaron physics and the Verwey transition
We have studied the electronic structure and charge ordering (Verwey)
transition of magnetite (Fe3O4) by soft x-ray photoemission. Due to the
enhanced probing depth and the use of different surface preparations we are
able to distinguish surface and volume effects in the spectra. The pseudogap
behavior of the intrinsic spectra and its temperature dependence give evidence
for the existence of strongly bound small polarons consistent with both dc and
optical conductivity. Together with other recent structural and theoretical
results our findings support a picture in which the Verwey transition contains
elements of a cooperative Jahn-Teller effect, stabilized by local Coulomb
interaction
Surface characterization and surface electronic structure of organic quasi-one-dimensional charge transfer salts
We have thoroughly characterized the surfaces of the organic charge-transfer
salts TTF-TCNQ and (TMTSF)2PF6 which are generally acknowledged as prototypical
examples of one-dimensional conductors. In particular x-ray induced
photoemission spectroscopy turns out to be a valuable non-destructive
diagnostic tool. We show that the observation of generic one-dimensional
signatures in photoemission spectra of the valence band close to the Fermi
level can be strongly affected by surface effects. Especially, great care must
be exercised taking evidence for an unusual one-dimensional many-body state
exclusively from the observation of a pseudogap.Comment: 11 pages, 12 figures, v2: minor changes in text and figure labellin
Circular dichroism and bilayer splitting in the normal state of underdoped (Pb,Bi)Sr(CaY)CuO and overdoped (Pb,Bi)SrCaCuO
We report an ARPES investigation of the circular dichroism in the first
Brillouin zone (BZ) of under- and overdoped Pb-Bi2212 samples. We show that the
dichroism has opposite signs for bonding and antibonding components of the
bilayer-split CuO-band and is antisymmetric with respect to reflections in both
mirror planes parallel to the c-axis. Using this property of the energy and
momentum intensity distributions we prove the existence of the bilayer
splitting in the normal state of the underdoped compound and compare its value
with the splitting in overdoped sample. In agreement with previous studies the
magnitude of the interlayer coupling does not depend significantly on doping.
We also discuss possible origins of the observed dichroism.Comment: 4 RevTex pages, 4 EPS figure
Generalized Spectral Signatures of Electron Fractionalization in Quasi-One and -Two Dimensional Molybdenum Bronzes and Superconducting Cuprates
We establish the quasi-one-dimensional Li purple bronze as a photoemission
paradigm of Luttinger liquid behavior. We also show that generalized signatures
of electron fractionalization are present in the angle resolved photoemission
spectra for quasi-two-dimensional purple bronzes and certain cuprates. An
important component of our analysis for the quasi-two-dimensional systems is
the proposal of a ``melted holon'' scenario for the k-independent background
that accompanies but does not interact with the peaks that disperse to define
the Fermi surface.Comment: 7 pages, 8 figure
Electronic structure of the quasi-one-dimensional organic conductor TTF-TCNQ
We study the electronic structure of the quasi-one-dimensional organic
conductor TTF-TCNQ by means of density-functional band theory, Hubbard model
calculations, and angle-resolved photoelectron spectroscopy (ARPES). The
experimental spectra reveal significant quantitative and qualitative
discrepancies to band theory. We demonstrate that the dispersive behavior as
well as the temperature-dependence of the spectra can be consistently explained
by the finite-energy physics of the one-dimensional Hubbard model at metallic
doping. The model description can even be made quantitative, if one accounts
for an enhanced hopping integral at the surface, most likely caused by a
relaxation of the topmost molecular layer. Within this interpretation the ARPES
data provide spectroscopic evidence for the existence of spin-charge separation
on an energy scale of the conduction band width. The failure of the
one-dimensional Hubbard model for the {\it low-energy} spectral behavior is
attributed to interchain coupling and the additional effect of electron-phonon
interaction.Comment: 18 pages, 9 figure
Direct k-space mapping of the electronic structure in an oxide-oxide interface
The interface between LaAlO3 and SrTiO3 hosts a two-dimensional electron
system of itinerant carriers, although both oxides are band insulators.
Interface ferromagnetism coexisting with superconductivity has been found and
attributed to local moments. Experimentally, it has been established that Ti 3d
electrons are confined to the interface. Using soft x-ray angle-resolved
resonant photoelectron spectroscopy we have directly mapped the interface
states in k-space. Our data demonstrate a charge dichotomy. A mobile fraction
contributes to Fermi surface sheets, whereas a localized portion at higher
binding energies is tentatively attributed to electrons trapped by O-vacancies
in the SrTiO3. While photovoltage effects in the polar LaAlO3 layers cannot be
excluded, the apparent absence of surface-related Fermi surface sheets could
also be fully reconciled in a recently proposed electronic reconstruction
picture where the built-in potential in the LaAlO3 is compensated by surface
O-vacancies serving also as charge reservoir.Comment: 8 pages, 6 figures, incl. Supplemental Informatio
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