771 research outputs found
Failure analysis of a 3.5 inch, 50 ampere-hour nickel-hydrogen cell
The 3.5 inch, 50 ampere-hour nickel-hydrogen cell was on a Low Earth Orbit (LEO) test regime and was being cycled at 10 C and 60 percent depth of discharge. At cycle number 511 the Automatic Control and Data Acquisition System (ACDAS) terminated the test when the end of discharge voltage dropped below the 1.00 volt cutoff. Upon removal of the stack assembly from the pressure vessel, portions of the zircar separator were found to be completely missing. Upon further examination portions of both the positive and negative plates were found to be missing from its substrate and several gas screens were damaged due to excessive heat which caused fusing. The postulated cause of failure is free electrolyte in the cell which caused oxygen channelization resulting in localized recombination which degraded the stack components
Non-substitutional single-atom defects in the Ge_(1-x)Sn_x alloy
Ge_(1-x)Sn_x alloys have proved difficult to form at large x, contrary to
what happens with other group IV semiconductor combinations. However, at low x
they are typical examples of well-behaved substitutional compounds, which is
desirable for harnessing the electronic properties of narrow band
semiconductors. In this paper, we propose the appearance of another kind of
single-site defect (), consisting of a single Sn atom in the center
of a Ge divacancy, that may account for these facts. Accordingly, we examine
the electronic and structural properties of these alloys by performing
extensive numerical ab-initio calculations around local defects. The results
show that the environment of the defect relaxes towards a cubic
octahedral configuration, facilitating the nucleation of metallic white tin and
its segregation, as found in amorphous samples. Using the information stemming
from these local defect calculations, we built a simple statistical model to
investigate at which concentration these defects can be formed in
thermal equilibrium. These results agree remarkably well with experimental
findings, concerning the critical concentration above which the homogeneous
alloys cannot be formed at room temperature. Our model also predicts the
observed fact that at lower temperature the critical concentration increases.
We also performed single site effective-field calculations of the electronic
structure, which further support our hypothesis.Comment: 12 pages, 1 table, 16 figure
Electrokinetic behavior of two touching inhomogeneous biological cells and colloidal particles: Effects of multipolar interactions
We present a theory to investigate electro-kinetic behavior, namely,
electrorotation and dielectrophoresis under alternating current (AC) applied
fields for a pair of touching inhomogeneous colloidal particles and biological
cells. These inhomogeneous particles are treated as graded ones with physically
motivated model dielectric and conductivity profiles. The mutual polarization
interaction between the particles yields a change in their respective dipole
moments, and hence in the AC electrokinetic spectra. The multipolar
interactions between polarized particles are accurately captured by the
multiple images method. In the point-dipole limit, our theory reproduces the
known results. We find that the multipolar interactions as well as the spatial
fluctuations inside the particles can affect the AC electrokinetic spectra
significantly.Comment: Revised version with minor changes: References added and discussion
extende
The effect of Coulomb interaction at ferromagnetic-paramagnetic metallic perovskite junctions
We study the effect of Coulomb interactions in transition metal oxides
junctions. In this paper we analyze charge transfer at the interface of a three
layer ferromagnetic-paramagnetic-ferromagnetic metallic oxide system. We choose
a charge model considering a few atomic planes within each layer and obtain
results for the magnetic coupling between the ferromagnetic layers. For large
number of planes in the paramagnetic spacer we find that the coupling
oscillates with the same period as in RKKY but the amplitude is sensitive to
the Coulomb energy. At small spacer thickness however, large differences may
appear as function of : the number of electrons per atom in the ferromagnetics
and paramagnetics materials, the dielectric constant at each component, and the
charge defects at the interface plane emphasizing the effects of charge
transfer.Comment: tex file and 7 figure
Particle entrapment as a feedback effect
We consider a suspension of polarizable particles under the action of
traveling wave dielectrophoresis (DEP) and focus on particle induced effects.
In a situation where the particles are driven by the DEP force, but no external
forces are exerted on the fluid, the joint motion of the particles can induce a
steady fluid flow, which leads to particle entrapment. This feedback effect is
proven to be non-negligible even for small volume concentration of particles.Comment: 4 pages, 4 figures, submitte
Keck Hires Observations of the QSO First J104459.6+365605: Evidence for a Large Scale Outflow
This paper presents an analysis of a Keck HIRES spectrum of the QSO FIRST
J104459.6+365605. The line of sight towards the QSO contains two clusters of
outflowing clouds that give rise to broad blue shifted absorption lines. The
outflow velocities of the clouds range from -200 to -1200 km/s and from -3400
to -5200 km/s, respectively. The width of the individual absorption lines
ranges from 50 to more than 1000 km/s. The most prominent absorption lines are
those of Mg II, Mg I, and Fe II. The low ionization absorption lines occur at
the same velocities as the most saturated Mg II lines, showing that the Fe II,
Mg I and Mg II line forming regions must be closely associated. Many absorption
lines from excited states of Fe II are present, allowing a determination of the
population of several low lying energy levels. From this we determine an
electron density in the Fe II line forming regions of 4000 per cubic cm.
Modelling the ionization state of the absorbing gas with this value of the
electron density as a constraint, we find that the distance between the Fe II
and Mg I line forming region and the continuum source is of order 700 parsec.
From the correspondence in velocity between the Fe II, Mg I and Mg II lines
we infer that the Mg II lines must be formed at the same distance. The Mg II
absorption fulfills the criteria for Broad Absorption Lines defined by Weymann
et al. (1991). This large distance is surprising, since BALs are generally
thought to be formed in outflows at a much smaller distance from the nucleus.Comment: 34 pages, 11 figures. Accepted by The Astrophysical Journa
First-Principles Approach to Electrorotation Assay
We have presented a theoretical study of electrorotation assay based on the
spectral representation theory. We consider unshelled and shelled spheroidal
particles as an extension to spherical ones. From the theoretical analysis, we
find that the coating can change the characteristic frequency at which the
maximum rotational angular velocity occurs. The shift in the characteristic
frequency is attributed to a change in the dielectric properties of the
bead-coating complex with respect to those of the uncoated particles. By
adjusting the dielectric properties and the thickness of the coating, it is
possible to obtain good agreement between our theoretical predictions and the
assay data.Comment: 17 pages, 4 eps figures; minor revisions, accepted for publications
by J. Phys.: Condens. Matte
Central Stars of Planetary Nebulae in the Large Magellanic Cloud: A Far-UV Spectroscopic Analysis
We observed seven central stars of planetary nebulae (CSPN) in the Large
Magellanic Cloud (LMC) with the Far Ultraviolet Spectroscopic Explorer (FUSE),
and performed a model-based analysis of these spectra in conjunction with
Hubble Space Telescope (HST) spectra in the UV and optical range to determine
the stellar and nebular parameters. Most of the objects show wind features, and
they have effective temperatures ranging from 38 to 60 kK with mass-loss rates
of ~= 5x10^-8 Msun/yr. Five of the objects have typical LMC abundances. One
object (SMP LMC 61) is a [WC4] star, and we fit its spectra with He/C/O-rich
abundances typical of the [WC] class, and find its atmosphere to be
iron-deficient. Most objects have very hot (T ~> 2000 K) molecular hydrogen in
their nebulae, which may indicate a shocked environment. One of these (SMP LMC
62) also displays OVI 1032-38 nebular emission lines, rarely observed in PN.Comment: 53 pages, 15 figures (11 color). Accepted for publication in Ap
Synthesis of silyl iron dinitrogen complexes for activation of dihydrogen and catalytic silylation of dinitrogen
Electrorotation of a pair of spherical particles
We present a theoretical study of electrorotation (ER) of two spherical
particles under the action of a rotating electric field. When the two particles
approach and finally touch, the mutual polarization interaction between the
particles leads to a change in the dipole moment of the individual particle and
hence the ER spectrum, as compared to that of the well-separated particles. The
mutual polarization effects are captured by the method of multiple images. From
the theoretical analysis, we find that the mutual polarization effects can
change the characteristic frequency at which the maximum angular velocity of
electrorotation occurs. The numerical results can be understood in the spectral
representation theory.Comment: Minor revisions; accepted by Phys. Rev.
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