Measuring air movement in small spaces: understanding air movement in historic bookshelves

The National Trust has tested ventilation holes in bookshelves to encourage air movement behind books as a possible strategy to improve the environment in these microclimates. This could be used as a preventive measure for mould development. Air movement was measured in historic bookshelves to understand what causes air movement and the impact of ventilation holes on the shelves behind books. Three libraries in National Trust properties were used as case studies. It was found that pressure differential and stack effect are two mechanisms contributing to the air velocities measured. However, several variables are believed to influence air movement in these small spaces, and further research is needed to understand its influence on mould development

Electronic Structure and Stability of Ligated Superatoms and Bimetallic Clusters

Quantum confinement in small metal clusters leads to a bunching of states into electronic shells reminiscent of shells in atoms. The addition of ligands can tune the valence electron count and electron distribution in metal clusters. A combined experimental and theoretical study of the reactivity of methanol with AlnIm− clusters reveals that ligands can enhance the stability of clusters. In some cases the electronegative ligand may perturb the charge density of the metallic core generating active sites that can lead to the etching of the cluster. Also, an investigation is conducted to understand how the bonding scheme of a magnetic dopant evolves as the electronic structure of the host material is varied. By considering VCun+, VAgn+, and VAun+ clusters, we find that the electronic and atomic structure of the cluster plays a major role in determining how an impurity will couple to its surroundings

Predicting Inter-Species Cross-Talk in Two-Component Signalling Systems

Phosphosignalling pathways are an attractive option for the synthetic biologist looking for a wide repertoire of modular components from which to build. We demonstrate that two-component systems can be used in synthetic biology. However, their potential is limited by the fact that host cells contain many of their own phosphosignalling pathways and these may interact with, and cross-talk to, the introduced synthetic components. In this paper we also demonstrate a simple bioinformatic tool that can help predict whether interspecies cross-talk between introduced and native two-component signalling pathways will occur and show both in vitro and in vivo that the predicted interactions do take place. The ability to predict potential cross-talk prior to designing and constructing novel pathways or choosing a host organism is essential for the promise that phosphosignalling components hold for synthetic biology to be realised

Evolution of the Spin Magnetic Moments and Atomic Valence of Vanadium in VCux+, VAgx+, and VAux+ Clusters (x = 3–14)

The atomic structures, bonding characteristics, spin magnetic moments, and stability of VCUx+, VAgx+, and VAux+ (x = 3-14) clusters were examined using density functional theory. Our studies indicate that the effective valence of vanadium is size-dependent and that at small sizes some of the valence electrons of vanadium are localized on vanadium, while at larger sizes the 3d orbitals of the vanadium participate in metallic bonding eventually quenching the spin magnetic moment. The electronic stability of the clusters may be understood through a split-shell model that partitions the valence electrons in either a delocalized shell or localized on the vanadium atom. A molecular orbital analysis reveals that in planar clusters the delocalizatibn of the 3d orbital of vanadium is enhanced when surrounded by gold due to enhanced 6s-5d hybridization. Once the clusters become three-dimensional, this hybridization is reduced, and copper most readily delocalizes the vanadium\u27s valence electrons. By understanding these unique features, greater insight is offered into the role of a host material\u27s electronic structure in determining the bonding characteristics and stability of localized spin magnetic moments in quantum confined systems

Hubble Space Telescope Images of Magellanic Cloud Planetary Nebulae: Data and Correlations across Morphological Classes

The morphology of planetary nebulae (PNe) provides an essential tool for understanding their origin and evolution, as it reflects both the dynamics of the gas ejected during the TP-AGB phase, and the central star energetics. Here we study the morphology of 27 Magellanic Cloud planetary nebulae (MCPNe) and present an analysis of their physical characteristics across morphological classes. Similar studies have been successfully carried out for galactic PNe, but were compromised by the uncertainty of individual PN distances. We present our own HST/FOC images of 15 Magellanic Cloud PNe (MCPNe) acquired through a narrow-band lambda 5007 [O III] filter. We use the Richardson-Lucy deconvolution technique on these pre-COSTAR images to achieve post-COSTAR quality. Three PNe imaged before and after COSTAR confirm the high reliability of our deconvolution procedure. We derive morphological classes, dimensions, and surface photometry for all these PNe. We have combined this sample with HST/PC1 images of 15 MCPNe, three of which are in common with the FOC set, acquired by Dopita et al. (1996), to obtain the largest MCPN sample ever examined from the morphological viewpoint. By using the whole database, supplemented with published data from the literature, we have analyzed the properties of the MCPNe and compared them to a typical, complete galactic sample. Morphology of the MCPNe is then correlated with PN density, chemistry, and evolution.Comment: text file lstanghe_mcpn.tex (LaTex); Figures 2 through 10, Figure 5 is in 3 parts (a,b,c); Figure 1 available by regular mail only; ApJ, in press, November 10, 199

The Gemini Deep Deep Survey: II. Metals in Star-Forming Galaxies at Redshift 1.3<z<2

The goal of the Gemini Deep Deep Survey (GDDS) is to study an unbiased sample of K<20.6 galaxies in the redshift range 0.8<z<2.0. Here we determine the statistical properties of the heavy element enrichment in the interstellar medium (ISM) of a subsample of 13 galaxies with 1.34<z<1.97 and UV absolute magnitude M_2000 < -19.65. The sample contains 38% of the total number of identified galaxies in the first two fields of the survey with z>1.3. The selected objects have colors typical of irregular and Sbc galaxies. Strong [OII] emission indicates high star formation activity in the HII regions (SFR~13-106 M_sun/yr). The high S/N composite spectrum shows strong ISM MgII and FeII absorption, together with weak MnII and MgI lines. The FeII column density, derived using the curve of growth analysis, is logN_FeII = 15.54^{+0.23}_{-0.13}. This is considerably larger than typical values found in damped Ly-alpha systems (DLAs) along QSO sight lines, where only 10 out of 87 (~11%) have logN_FeII > 15.2. High FeII column densities are observed in the z=2.72 Lyman break galaxy cB58 (logN_FeII ~ 15.25) and in gamma-ray burst host galaxies (logN_FeII ~ 14.8-15.9). Given our measured FeII column density and assuming a moderate iron dust depletion (delta_Fe ~ 1 dex), we derive an optical dust extinction A_V ~ 0.6. If the HI column density is log N(HI)<21.7 (as in 98% of DLAs), then the mean metallicity is Z/Z_sun > 0.2. The high completeness of the GDDS sample implies that these results are typical of star-forming galaxies in the 1<z<2 redshift range, an epoch which has heretofore been particularly challenging for observational programs.Comment: ApJ in press, corrected HI column density estimat

Search for Interstellar Water in the Translucent Molecular Cloud toward HD 154368

We report an upper limit of 9 x 10^{12} cm-2 on the column density of water in the translucent cloud along the line of sight toward HD 154368. This result is based upon a search for the C-X band of water near 1240 \AA carried out using the Goddard High Resolution Spectrograph of the Hubble Space Telescope. Our observational limit on the water abundance together with detailed chemical models of translucent clouds and previous measurements of OH along the line of sight constrain the branching ratio in the dissociative recombination of H_3O+ to form water. We find at the $3\sigma$ level that no more than 30% of dissociative recombinations of H_3O+ can lead to H_2O. The observed spectrum also yielded high-resolution observations of the Mg II doublet at 1239.9 \AA and 1240.4 \AA, allowing the velocity structure of the dominant ionization state of magnesium to be studied along the line of sight. The Mg II spectrum is consistent with GHRS observations at lower spectral resolution that were obtained previously but allow an additional velocity component to be identified.Comment: Accepted by ApJ, uses aasp

Description of routes in people with intellectual disability

The ability to describe routes was assessed in participants with intellectual disability (ID) and participants without ID matched on chronological age (CA) or on mental age (MA). In two experiments, participants learned a route through a virtual environment until they reached a learning criterion. Then, they were asked to externalise their spatial knowledge in a verbal description task, a landmark recognition task or a map completion task. Results revealed that participants with ID mainly described the route as a succession of actions (“turn left”) while participants in the CA group prescribed actions referring to a landmark (“turn left at the swing”). Yet, results from the other tasks showed that individuals with ID had good landmark knowledge of the environment